Purcell Enhancement of Parametric Luminescence: Bright and Broadband Nonlinear Light Emission in Metamaterials

Single-photon and correlated two-photon sources are important elements for optical information systems. Nonlinear downconversion light sources are robust and stable emitters of single photons and entangled photon pairs. However, the rate of downconverted light emission, dictated by the properties of low-symmetry nonlinear crystals, is typically very small, leading to significant constrains in device design and integration. In this paper, we show that the principles for spontaneous emission control (i.e. Purcell effect) of isolated emitters in nanoscale structures, such as metamaterials, can be generalized to describe the enhancement of nonlinear light generation processes such as parametric down conversion. We develop a novel theoretical framework for quantum nonlinear emission in a general anisotropic, dispersive and lossy media. We further find that spontaneous parametric downconversion in media with hyperbolic dispersion is broadband and phase-mismatch-free. We predict a 1000-fold enhancement of the downconverted emission rate with up to 105 photon pairs per second in experimentally realistic nanostructures. Our theoretical formalism and approach to Purcell enhancement of nonlinear optical processes, provides a framework for description of quantum nonlinear optical phenomena in complex nanophotonic structures.Comment: 29 pages, 10 figure

Van der Waals Materials for Atomically-Thin Photovoltaics: Promise and Outlook

Two-dimensional (2D) semiconductors provide a unique opportunity for optoelectronics due to their layered atomic structure, electronic and optical properties. To date, a majority of the application-oriented research in this field has been focused on field-effect electronics as well as photodetectors and light emitting diodes. Here we present a perspective on the use of 2D semiconductors for photovoltaic applications. We discuss photonic device designs that enable light trapping in nanometer-thickness absorber layers, and we also outline schemes for efficient carrier transport and collection. We further provide theoretical estimates of efficiency indicating that 2D semiconductors can indeed be competitive with and complementary to conventional photovoltaics, based on favorable energy bandgap, absorption, external radiative efficiency, along with recent experimental demonstrations. Photonic and electronic design of 2D semiconductor photovoltaics represents a new direction for realizing ultrathin, efficient solar cells with applications ranging from conventional power generation to portable and ultralight solar power.Comment: 4 figure

Plasmonic Bloch oscillations in chirped metal-dielectric structures

We study the propagation of plasmon polaritons in one-dimensional chirped metal-dielectric layered structures. We find an optical Wannier–Stark ladder in the mode spectrum and analyze Bloch oscillations associated with the coupling of surface plasmons localized at the metal-dielectric interfaces. For long structures, we find that the energy flow may dramatically change its direction, thus providing possibilities for the beam steering in the transmission band.The work has been supported by the Australian Research Council

High Photovoltaic Quantum Efficiency in Ultrathin van der Waals Heterostructures

We report experimental measurements for ultrathin (< 15 nm) van der Waals heterostructures exhibiting external quantum efficiencies exceeding 50%, and show that these structures can achieve experimental absorbance > 90%. By coupling electromagnetic simulations and experimental measurements, we show that pn WSe2/MoS2 heterojunctions with vertical carrier collection can have internal photocarrier collection efficiencies exceeding 70%.Comment: ACS Nano, 2017. Manuscript (25 pages, 7 figures) plus supporting information (7 pages, 4 figures

Near-Unity Absorption in van der Waals Semiconductors for Ultrathin Optoelectronics

We demonstrate near-unity, broadband absorbing optoelectronic devices using sub-15 nm thick transition metal dichalcogenides (TMDCs) of molybdenum and tungsten as van der Waals semiconductor active layers. Specifically, we report that near-unity light absorption is possible in extremely thin (<15 nm) van der Waals semiconductor structures by coupling to strongly damped optical modes of semiconductor/metal heterostructures. We further fabricate Schottky junction devices using these highly absorbing heterostructures and characterize their optoelectronic performance. Our work addresses one of the key criteria to enable TMDCs as potential candidates to achieve high optoelectronic efficiency

Near-unity light-matter interaction in mid-infrared van der Waals nanocavities

Accessing mid-infrared radiation is of great importance for a range of applications, including thermal imaging, sensing, and radiative cooling. Here, we study light interaction with hexagonal boron nitride nanocavities and reveal strong and tunable resonances across its hyperbolic transition. In addition to conventional phonon-polariton excitations, we demonstrate that the high refractive index of hexagonal boron nitride outside the Reststrahlen band allows enhanced light-matter interactions in deep subwavelength (<{\lambda}/15) nanostructures across a broad 7-8 {\mu}m range. Near-unity absorption and high quality (Q>80) resonance interaction in the vicinity of the transverse optical phonon is observed. Our study provides new avenues to design highly efficient and ultracompact structures for controlling mid-infrared radiation and accessing strong light-matter interaction.Comment: 14 pages, 4 figure

Optical Bloch oscillations in periodic structures with metamaterials

We predict that optical Bloch oscillations can be observed in layered structures with left-handed metamaterials and zero average refractive index where the layer thickness varies linearly across the structure. We demonstrate a new type of the Bloch oscillations associated with coupled surface waves excited at the interfaces between the layers with left-handed material and conventional dielectric.Comment: 3 pages, 5 postscript figure

Exciton Assisted Deeply Subwavelength Nano-Photonics

The wave nature of light sets a fundamental diffraction limit that challenges confinement and control of light in nanoscale structures with dimensions significantly smaller than the wavelength. Here, we demonstrate van der Waals MoS_2 nano-photonic devices with dimensions as small as ~ \lambda/16 (~60 nm at 1000 nm excitation wavelength). This deep subwavelength light confinement is achieved by exploiting the coupling between MoS_2 excitons and photons. We validate deep subwavelength light control via far- and near-field measurements. Our near-field measurements reveal detailed imaging of excitation, evolution, and guidance of fields in MoS_2 nanodevices, whereas our far-field study examines highly confined integrated photonics. Exciton-driven nano-photonics at a fraction of a wavelength demonstrated here could dramatically reduce the size of integrated photonic devices and opto-electronic circuits with potential applications in optical information science and engineering.Comment: 39 pages, 32 figure