Metalliferous sediments and the scavenging residence time of Nd near hydrothermal vents

Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/94674/1/grl5993.pd

Carbonate Assimilation at Merapi Volcano, Java, Indonesia: Insights from Crystal Isotope Stratigraphy

Recent basaltic andesite lavas from Merapi volcano contain abundant, complexly zoned, plagioclase phenocrysts, analysed here for their petrographic textures, major element composition and Sr isotope composition. Anorthite (An) content in individual crystals can vary by as much as 55 mol% (An40-95) across internal resorption surfaces with a negative correlation between high An mol% (>70), MgO wt% and FeO wt%. In situ Sr isotope analyses of zoned plagioclase phenocrysts show that the 87Sr/86Sr ratios of individual zones range from 0·70568 to 0·70627. The upper end of this range is notably more radiogenic than the host basaltic andesite whole-rocks (< 0·70574). Crystal zones with the highest An content have the highest 87Sr/86Sr values, requiring a source or melt with elevated radiogenic Sr, rich in Ca and with lower Mg and Fe. Recent Merapi eruptive rocks contain abundant xenoliths, including metamorphosed volcanoclastic sediment and carbonate country rock (calc-silicate skarns) analysed here for petrographic textures, mineralogy, major element composition and Sr isotope composition. The xenoliths contain extremely calcic plagioclase (up to An100) and have whole-rock 87Sr/86Sr ratios of 0·70584 to 0·70786. The presence of these xenoliths and their mineralogy and geochemistry, coupled with the 87Sr/86Sr ratios observed in different zones of individual phenocrysts, indicate that magma-crust interaction at Merapi is potentially more significant than previously thought, as numerous crystal cores in the phenocrysts appear to be inherited from a metamorphosed sedimentary crustal source. This has potentially significant consequences for geochemical mass-balance calculations, volatile saturation and flux and eruptive behaviour at Merapi and similar island arc volcanic systems elsewher

Modelling the petrogenesis of high Rb/Sr silicic magmas

Rhyolites can be highly evolved with Sr contents as low as 0.1 ppm and Rb/Sr &gt; 2,000. In contrast, granite batholiths are commonly comprised of rocks with Rb/Sr 100. Mass-balance modelling of source compositions, differentiation and contamination using the trace-element geochemistry of granites are therefore commonly in error because of the failure to account for evolved differentiates that may have been erupted from the system. Rhyolitic magmas with very low Sr concentrations ([les]1 ppm) cannot be explained by any partial melting models involving typical crustal source compositions. The only plausible mechanism for the production of such rhyolites is Rayleigh fractional crystallization involving substantial volumes of cumulates. A variety of methods for modelling the differentiation of magmas with extremely high Rb/Sr is discussed. In each case it is concluded that the bulk partition coefficients for Sr have to be large. In the simplest models, the bulk DSr of the most evolved types is modelled as &gt; 50. Evidence from phenocryst/glass/whole-rock concentrations supports high Sr partition coefficients in feldspars from high silica rhyolites. However, the low modal abundance of plagioclase commonly observed in such rocks is difficult to reconcile with such simple fractionation models of the observed trace-element trends. In certain cases, this may be because the apparent trace-element trend defined by the suite of cognetic rhyolites is the product of different batches of magma with separate differentiation histories accumulating in the magma chamber roof zone.Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/29127/1/0000166.pd

Small-Scale Disequilibrium in a Magmatic Inclusion and its More Silicic Host

Basaltic andesite inclusions and their host dacite from the Purico-Chascon complex in northern Chile are isotopically distinct. Textural characteristics of the inclusions are typical of those resulting from magma mingling. Serial sectioning across the interface of an inclusion and its host dacite, complemented by microdrill sampling and detailed microprobe work, has enabled us to examine the scale of mixing and chemical (isotopic and trace element) disequilibrium. The results of this work show that (1) the composition of the inclusion is relatively homogeneous; (2) the dacite host is generally higher in ⁸⁷Sr/⁸⁶Sr and lower in ¹⁴³Nd/¹⁴⁴Nd than the enclave, but it is heterogeneous on a small scale, and probably a “hybrid”; (3) the isotopic composition in the marginal zone, apparently on both host and inclusion sides of the weakly chilled interface, actually shows the highest ⁸⁷Sr/⁸⁶Sr and lowest ¹⁴³Nd/¹⁴⁴Nd; (4) large plagioclase crystals in the inclusions and host are xenocrystic, with higher ⁸⁷Sr/⁸⁶Sr than any of the other samples. These observations are reconciled with a model of magma evolution in a crustal magma chamber. In such a scenario the mafic magma is overlain by a cap of rhyolite - a partial melt of the dacitic ignimbrites which now underlie the Purico-Chascon complex. Overturn of such a magma system gives rise to a hybrid dacite containing discrete mafic inclusions

Observations of bedforms on a dissipative macrotidal beach

NERC NE/H004262/1 and NE/H02543X/1 DRIB

Digital music libraries - Research and development

A report on the progress of several major research and development projects in digital music libraries is presented. Digital music libraries provide enhanced access and functionality that facilitates scholarly research and education. The issue of integrating digital music library collections with interactive instructional applications is addressed

Gender-dependent differences in plasma matrix metalloproteinase-8 elevated in pulmonary tuberculosis.

Tuberculosis (TB) remains a global health pandemic and greater understanding of underlying pathogenesis is required to develop novel therapeutic and diagnostic approaches. Matrix metalloproteinases (MMPs) are emerging as key effectors of tissue destruction in TB but have not been comprehensively studied in plasma, nor have gender differences been investigated. We measured the plasma concentrations of MMPs in a carefully characterised, prospectively recruited clinical cohort of 380 individuals. The collagenases, MMP-1 and MMP-8, were elevated in plasma of patients with pulmonary TB relative to healthy controls, and MMP-7 (matrilysin) and MMP-9 (gelatinase B) were also increased. MMP-8 was TB-specific (p<0.001), not being elevated in symptomatic controls (symptoms suspicious of TB but active disease excluded). Plasma MMP-8 concentrations inversely correlated with body mass index. Plasma MMP-8 concentration was 1.51-fold higher in males than females with TB (p<0.05) and this difference was not due to greater disease severity in men. Gender-specific analysis of MMPs demonstrated consistent increase in MMP-1 and -8 in TB, but MMP-8 was a better discriminator for TB in men. Plasma collagenases are elevated in pulmonary TB and differ between men and women. Gender must be considered in investigation of TB immunopathology and development of novel diagnostic markers