1 research outputs found
A Versatile and Efficient Strategy to Discrete Conjugated Oligomers
An
efficient and scalable strategy to prepare libraries of discrete
conjugated oligomers (<i><i>Đ</i></i> =
1.0) using the combination of controlled polymerization and automated
flash chromatography is reported. From this two-step process, a series
of discrete conjugated materials from dimers to tetradecamers could
be isolated in high yield with excellent structural control. Facile
and scalable access to monodisperse libraries of different conjugated
oligomers opens pathways to designer mixtures with precise composition
and monomer sequence, allowing exquisite control over their physical,
optical, and electronic properties