Numerical Study of Heterogeneous Reactions in an SOFC Anode with Oxygen Addition

Previous experimental studies have shown that addition of small amounts of oxygen to a hydrocarbon fuel stream can control coking in the anode, while relatively large amounts of oxygen are present in the fuel stream in single-chamber solid oxide fuel cells (SOFCs). In order to rationally design an anode for such use, it is important to understand the coupled catalytic oxidation/reforming chemistry and diffusion within the anode under SOFC operating conditions. In this study, the heterogeneous catalytic reactions in the anode of an anode-supported SOFC running on methane fuel with added oxygen are numerically investigated using a model that accounts for catalytic chemistry, porous media transport, and electrochemistry at the anode/electrolyte interface. Using an experimentally validated heterogeneous reaction mechanism for methane partial oxidation and reforming on nickel, we identify three distinct reaction zones at different depths within the anode: a thin outer layer in which oxygen is nearly fully consumed in oxidizing methane and hydrogen, followed by a reforming region, and then a water–gas shift region deep within the anode. Both single-chamber and dual-chamber SOFC anodes are explored

Advance Production Duopolies and Posted Prices or Market-Clearing Prices

The paper reports the results of 39 laboratory duopoly markets for which pricing institution and participant experience are treatments. Duopolies in which producers with complete information about market demand make advance-production output decisions and sell their output at a clearing price (Cournot markets) are contrasted with comparable duopolies who post prices for sale through an efficient rationing mechanism (Kreps-Scheinkman or KS markets). Inexperienced participants in KS markets have much more difficulty selecting capacities consistent with the theoretical predictions than do those in Cournot markets. With experience, the differences disappear. If trading sessions last sufficiently long, it is likely that differences will disappear with inexperienced participants.

Quantity Precommitment with Price Competition versus Quantity Precommitment with Market Clearing Prices in the Laboratory

The paper reports the results of 39 laboratory duopoly markets for which pricing institution and participant experience are treatments. Cournot (C) duopolies (quantity precommitment and a price determined to clear the market) are contrasted with Kreps-Scheinkman (KS) duopolies (quantity precommitment and posted prices). Inexperienced participants in KS markets have much more difficulty selecting capacities consistent with the theoretical predictions than do those in C markets. With experience, the differences disappear.Duopoly; Laboratory experiment; Quantity precommitment; Posted prices; Price competition; Market-clearing prices; Experience

Diamond growth in premixed propylene-oxygen flames

Diamond film growth in low-pressure premixed propylene/oxygen flames is demonstrated. Well-faceted films are grown at a pressure of 180 Torr and a fuel/oxygen ratio of 0.47. Using propylene as the fuel may greatly improve the economics of flame synthesis of diamond, since propylene is an order of magnitude cheaper than acetylene

A Two-Dimensional Model of a Single-Chamber SOFC with Hydrocarbon Fuels

The single chamber fuel cell (SCFC) is a novel simplification of the conventional solid oxide fuel cell (SOFC) into which a premixed fuel/air mixture is introduced. It relies on the selectivity of the anode and cathode catalysts to generate a chemical potential gradient across the cell. For SCFC running on hydrocarbon fuels, the anode catalyst promotes in-situ internal reforming of the hydrocarbon and electrochemical oxidation of the syngas, while the cathode catalyst reduces oxygen simultaneously. Laboratory tests of small designs of such fuel cells have demonstrated excellent electrical performance (1, 2)

Wither the Creative City? Art, Cities, and Justice

Maloney Library lecture series, Behind the Bookhttps://ir.lawnet.fordham.edu/behindthebookposters/1004/thumbnail.jp

Characterization of highly-oriented ferroelectric Pb_xBa_(1-x)TiO_3

Pb_xBa_(1-x)TiO_3 (0.2 ≾ x ≾ 1) thin films were deposited on single-crystal MgO as well as amorphous Si_3N_4/Si substrates using biaxially textured MgO buffer templates, grown by ion beam-assisted deposition (IBAD). The ferroelectric films were stoichiometric and highly oriented, with only (001) and (100) orientations evident in x-ray diffraction (XRD) scans. Films on biaxially textured templates had smaller grains (60 nm average) than those deposited on single-crystal MgO (300 nm average). Electron backscatter diffraction (EBSD) has been used to study the microtexture on both types of substrates and the results were consistent with x-ray pole figures and transmission electron microscopy (TEM) micrographs that indicated the presence of 90° domain boundaries, twins, in films deposited on single-crystal MgO substrates. In contrast, films on biaxially textured substrates consisted of small single-domain grains that were either c or a oriented. The surface-sensitive EBSD technique was used to measure the tetragonal tilt angle as well as in-plane and out-of-plane texture. High-temperature x-ray diffraction (HTXRD) of films with 90° domain walls indicated large changes, as much as 60%, in the c and a domain fractions with temperature, while such changes were not observed for Pb_xBa_(1-x)TiO_3 (PBT) films on biaxially textured MgO/Si_3N_4/Si substrates, which lacked 90° domain boundaries

Discs in misaligned binary systems

We perform SPH simulations to study precession and changes in alignment between the circumprimary disc and the binary orbit in misaligned binary systems. We find that the precession process can be described by the rigid-disc approximation, where the disc is considered as a rigid body interacting with the binary companion only gravitationally. Precession also causes change in alignment between the rotational axis of the disc and the spin axis of the primary star. This type of alignment is of great important for explaining the origin of spin-orbit misaligned planetary systems. However, we find that the rigid-disc approximation fails to describe changes in alignment between the disc and the binary orbit. This is because the alignment process is a consequence of interactions that involve the fluidity of the disc, such as the tidal interaction and the encounter interaction. Furthermore, simulation results show that there are not only alignment processes, which bring the components towards alignment, but also anti-alignment processes, which tend to misalign the components. The alignment process dominates in systems with misalignment angle near 90 degrees, while the anti-alignment process dominates in systems with the misalignment angle near 0 or 180 degrees. This means that highly misaligned systems will become more aligned but slightly misaligned systems will become more misaligned.Comment: 15 pages, 16 figures, 1 table, accepted for publication in MNRA

Growth Stimulation of Biological Cells and Tissue by Electromagnetic Fields and Uses Thereof

The present invention provides systems for growing two or three dimensional mammalian cells within a culture medium facilitated by an electromagnetic field, and preferably, a time varying electromagnetic field. The cells, and culture medium are contained within a fixed or rotating culture vessel, and the electromagnetic field is emitted from at least one electrode. In one embodiment, the electrode is spaced from the vessel. The invention further provides methods to promote neural tissue regeneration by means of culturing the neural cells in the claimed system. In one embodiment, neuronal cells are grown within longitudinally extending tissue strands extending axially along and within electrodes comprising electrically conductive channels or guides through which a time varying electrical current is conducted, the conductive channels being positioned within a culture medium