Numerical Study of Heterogeneous Reactions in an SOFC Anode with Oxygen Addition

Previous experimental studies have shown that addition of small amounts of oxygen to a hydrocarbon fuel stream can control coking in the anode, while relatively large amounts of oxygen are present in the fuel stream in single-chamber solid oxide fuel cells (SOFCs). In order to rationally design an anode for such use, it is important to understand the coupled catalytic oxidation/reforming chemistry and diffusion within the anode under SOFC operating conditions. In this study, the heterogeneous catalytic reactions in the anode of an anode-supported SOFC running on methane fuel with added oxygen are numerically investigated using a model that accounts for catalytic chemistry, porous media transport, and electrochemistry at the anode/electrolyte interface. Using an experimentally validated heterogeneous reaction mechanism for methane partial oxidation and reforming on nickel, we identify three distinct reaction zones at different depths within the anode: a thin outer layer in which oxygen is nearly fully consumed in oxidizing methane and hydrogen, followed by a reforming region, and then a water–gas shift region deep within the anode. Both single-chamber and dual-chamber SOFC anodes are explored

Quantity Precommitment with Price Competition versus Quantity Precommitment with Market Clearing Prices in the Laboratory

The paper reports the results of 39 laboratory duopoly markets for which pricing institution and participant experience are treatments. Cournot (C) duopolies (quantity precommitment and a price determined to clear the market) are contrasted with Kreps-Scheinkman (KS) duopolies (quantity precommitment and posted prices). Inexperienced participants in KS markets have much more difficulty selecting capacities consistent with the theoretical predictions than do those in C markets. With experience, the differences disappear.Duopoly; Laboratory experiment; Quantity precommitment; Posted prices; Price competition; Market-clearing prices; Experience

Advance Production Duopolies and Posted Prices or Market-Clearing Prices

The paper reports the results of 39 laboratory duopoly markets for which pricing institution and participant experience are treatments. Duopolies in which producers with complete information about market demand make advance-production output decisions and sell their output at a clearing price (Cournot markets) are contrasted with comparable duopolies who post prices for sale through an efficient rationing mechanism (Kreps-Scheinkman or KS markets). Inexperienced participants in KS markets have much more difficulty selecting capacities consistent with the theoretical predictions than do those in Cournot markets. With experience, the differences disappear. If trading sessions last sufficiently long, it is likely that differences will disappear with inexperienced participants.

Diamond growth in premixed propylene-oxygen flames

Diamond film growth in low-pressure premixed propylene/oxygen flames is demonstrated. Well-faceted films are grown at a pressure of 180 Torr and a fuel/oxygen ratio of 0.47. Using propylene as the fuel may greatly improve the economics of flame synthesis of diamond, since propylene is an order of magnitude cheaper than acetylene

Characterization of highly-oriented ferroelectric Pb_xBa_(1-x)TiO_3

Pb_xBa_(1-x)TiO_3 (0.2 ≾ x ≾ 1) thin films were deposited on single-crystal MgO as well as amorphous Si_3N_4/Si substrates using biaxially textured MgO buffer templates, grown by ion beam-assisted deposition (IBAD). The ferroelectric films were stoichiometric and highly oriented, with only (001) and (100) orientations evident in x-ray diffraction (XRD) scans. Films on biaxially textured templates had smaller grains (60 nm average) than those deposited on single-crystal MgO (300 nm average). Electron backscatter diffraction (EBSD) has been used to study the microtexture on both types of substrates and the results were consistent with x-ray pole figures and transmission electron microscopy (TEM) micrographs that indicated the presence of 90° domain boundaries, twins, in films deposited on single-crystal MgO substrates. In contrast, films on biaxially textured substrates consisted of small single-domain grains that were either c or a oriented. The surface-sensitive EBSD technique was used to measure the tetragonal tilt angle as well as in-plane and out-of-plane texture. High-temperature x-ray diffraction (HTXRD) of films with 90° domain walls indicated large changes, as much as 60%, in the c and a domain fractions with temperature, while such changes were not observed for Pb_xBa_(1-x)TiO_3 (PBT) films on biaxially textured MgO/Si_3N_4/Si substrates, which lacked 90° domain boundaries

Diamond films from combustion of methyl acetylene and propadiene

To date diamond films grown with the combustion technique have used either acetylene or, rarely, ethylene as the fuel. However, there are barriers to large scale commercialization of the combustion technique using either fuel. For example, acetylene is relatively expensive and difficult to handle, while the use of ethylene gives relatively low growth rates. In this letter we propose replacing acetylene with MAPPTM gas, a commercial mixture of methyl acetylene and propadiene in liquefied petroleum gas (primarily propylene). MAPP gas is considerably cheaper, safer, and easier to handle than acetylene. Furthermore, the experiments described here suggest that MAPP gas flames are only slightly less efficient than acetylene flames at converting fuel carbon atoms into diamond

Effective transition rates for epitaxial growth using fast modulation

Thin-film deposition is an industrially important process that is highly dependent on the processing conditions. Most films are grown under constant conditions, but a few studies show that modified properties may be obtained with periodic inputs. However, assessing the effects of modulation experimentally becomes impractical with increasing material complexity. Here we consider periodic conditions in which the period is short relative to the time scales of growth. We analyze a stochastic model of thin-film growth, computing effective transition rates associated with rapid periodic process parameters. Combinations of effective rates may exist that are not attainable under steady conditions, potentially enabling new film properties. An algorithm is presented to construct the periodic input for a desired set of effective transition rates. These ideas are demonstrated in three simple examples using kinetic Monte Carlo simulations of epitaxial growth

Second order phase dispersion by optimised rotation pulses

We show that the duration of broadband universal control pulses can be halved by choosing control targets with a quadratic function of phase dispersion. This class of control pulses perform a broadband universal rotation around an axis, in the Bloch sphere representation of two-level systems, given by this phase dispersion function. We present an effective optimal control method to avoid the problem of convergence to local extrema traps.Comment: 8 pages, 4 figure

Graded ferroelectric capacitors with robust temperature characteristics

Ferroelectric thin films offer the possibility of engineering the dielectric response for tunable components in frequency-agile rf and microwave devices. However, this approach often leads to an undesired temperature sensitivity. Compositionally graded ferroelectric films have been explored as a means of redressing this sensitivity, but experimental observations vary depending on geometry and other details. In this paper, we present a continuum model to calculate the capacitive response of graded ferroelectric films with realistic electrode geometries by accurately accounting for the polarization distribution and long-range electrostatic interactions. We show that graded c-axis poled BaxSr_(1−xT)iO_3 BST parallel plate capacitors are ineffective while graded a-axis poled BST coplanar capacitors with interdigitated electrodes are extremely effective in obtaining high and temperature-stable dielectric properties