Retrodictive states and two-photon quantum imaging

We use retrodictive quantum theory to analyse two-photon quantum imaging systems. The formalism is particularly suitable for calculating conditional probability distributions.Comment: 5 pages, 3 figure

The fundamental cycle of concept construction underlying various theoretical frameworks

In this paper, the development of mathematical concepts over time is considered. Particular reference is given to the shifting of attention from step-by-step procedures that are performed in time, to symbolism that can be manipulated as mental entities on paper and in the mind. The development is analysed using different theoretical perspectives, including the SOLO model and various theories of concept construction to reveal a fundamental cycle underlying the building of concepts that features widely in different ways of thinking that occurs throughout mathematical learning

Retrodiction with two-level atoms: atomic previvals

In the Jaynes-Cummings model a two-level atom interacts with a single-mode electromagnetic field. Quantum mechanics predicts collapses and revivals in the probability that a measurement will show the atom to be excited at various times after the initial preparation of the atom and field. In retrodictive quantum mechanics we seek the probability that the atom was prepared in a particular state given the initial state of the field and the outcome of a later measurement on the atom. Although this is not simply the time reverse of the usual predictive problem, we demonstrate in this paper that retrodictive collapses and revivals also exist. We highlight the differences between predictive and retrodictive evolutions and describe an interesting situation where the prepared state is essentially unretrodictable.Comment: 15 pages, 3 (5) figure

Retrodiction as a tool for micromaser field measurements

We use retrodictive quantum theory to describe cavity field measurements by successive atomic detections in the micromaser. We calculate the state of the micromaser cavity field prior to detection of sequences of atoms in either the excited or ground state, for atoms that are initially prepared in the excited state. This provides the POM elements, which describe such sequences of measurements.Comment: 20 pages, 4(8) figure

Photodetachment study of the 1s3s4s ^4S resonance in He^-

A Feshbach resonance associated with the 1s3s4s ^{4}S state of He^{-} has been observed in the He(1s2s ^{3}S) + e^- (\epsilon s) partial photodetachment cross section. The residual He(1s2s ^{3}S) atoms were resonantly ionized and the resulting He^+ ions were detected in the presence of a small background. A collinear laser-ion beam apparatus was used to attain both high resolution and sensitivity. We measured a resonance energy E_r = 2.959 255(7) eV and a width \Gamma = 0.19(3) meV, in agreement with a recent calculation.Comment: LaTeX article, 4 pages, 3 figures, 21 reference

Electron affinity of Li: A state-selective measurement

We have investigated the threshold of photodetachment of Li^- leading to the formation of the residual Li atom in the $2p ^2P$ state. The excited residual atom was selectively photoionized via an intermediate Rydberg state and the resulting Li^+ ion was detected. A collinear laser-ion beam geometry enabled both high resolution and sensitivity to be attained. We have demonstrated the potential of this state selective photodetachment spectroscopic method by improving the accuracy of Li electron affinity measurements an order of magnitude. From a fit to the Wigner law in the threshold region, we obtained a Li electron affinity of 0.618 049(20) eV.Comment: 5 pages,6 figures,22 reference

Master Equation for Retrodiction of Quantum Communication Signals

We derive the master equation that governs the evolution of the measured state backwards in time in an open system. This allows us to determine probabilities for a given set of preparation events from the results of subsequent measurements, which has particular relevance to quantum communication.Comment: 14 pages, no figure

Toy Model for a Relational Formulation of Quantum Theory

In the absence of an external frame of reference physical degrees of freedom must describe relations between systems. Using a simple model, we investigate how such a relational quantum theory naturally arises by promoting reference systems to the status of dynamical entities. Our goal is to demonstrate using elementary quantum theory how any quantum mechanical experiment admits a purely relational description at a fundamental level, from which the original "non-relational" theory emerges in a semi-classical limit. According to this thesis, the non-relational theory is therefore an approximation of the fundamental relational theory. We propose four simple rules that can be used to translate an "orthodox" quantum mechanical description into a relational description, independent of an external spacial reference frame or clock. The techniques used to construct these relational theories are motivated by a Bayesian approach to quantum mechanics, and rely on the noiseless subsystem method of quantum information science used to protect quantum states against undesired noise. The relational theory naturally predicts a fundamental decoherence mechanism, so an arrow of time emerges from a time-symmetric theory. Moreover, there is no need for a "collapse of the wave packet" in our model: the probability interpretation is only applied to diagonal density operators. Finally, the physical states of the relational theory can be described in terms of "spin networks" introduced by Penrose as a combinatorial description of geometry, and widely studied in the loop formulation of quantum gravity. Thus, our simple bottom-up approach (starting from the semi-classical limit to derive the fully relational quantum theory) may offer interesting insights on the low energy limit of quantum gravity.Comment: References added, extended discussio

Massively parallel quantum chemistry: PFAS on over 1 million cloud vCPUs

Accurate solutions to the electronic Schr\"odinger equation can provide valuable insight for electron interactions within molecular systems, accelerating the molecular design and discovery processes in many different applications. However, the availability of such accurate solutions are limited to small molecular systems due to both the extremely high computational complexity and the challenge of operating and executing these workloads on high-performance compute clusters. This work presents a massively scalable cloud-based quantum chemistry platform by implementing a highly parallelizable quantum chemistry method that provides a polynomial-scaling approximation to full configuration interaction (FCI). Our platform orchestrates more than one million virtual CPUs on the cloud to analyze the bond-breaking behaviour of carbon-fluoride bonds of per- and polyfluoroalkyl substances (PFAS) with near-exact accuracy within the chosen basis set. This is the first quantum chemistry calculation utilizing more than one million virtual CPUs on the cloud and is the most accurate electronic structure computation of PFAS bond breaking to date