Equilibrium ultrastable glasses produced by random pinning

Ultrastable glasses have risen to prominence due to their potentially useful material properties and the tantalizing possibility of a general method of preparation via vapor deposition. Despite the importance of this novel class of amorphous materials, numerical studies have been scarce because achieving ultrastability in atomistic simulations is an enormous challenge. Here we bypass this difficulty and establish that randomly pinning the position of a small fraction of particles inside an equilibrated supercooled liquid generates ultrastable configurations at essentially no numerical cost, while avoiding undesired structural changes due to the preparation protocol. Building on the analogy with vapor-deposited ultrastable glasses, we study the melting kinetics of these configurations following a sudden temperature jump into the liquid phase. In homogeneous geometries, we find that enhanced kinetic stability is accompanied by large scale dynamic heterogeneity, while a competition between homogeneous and heterogeneous melting is observed when a liquid boundary invades the glass at constant velocity. Our work demonstrates the feasibility of large-scale, atomistically resolved, and experimentally relevant simulations of the kinetics of ultrastable glasses.Comment: 9 pages, 5 figure

Sheer shear: weak lensing with one mode

3D data compression techniques can be used to determine the natural basis of radial eigenmodes that encode the maximum amount of information in a tomographic large-scale structure survey. We explore the potential of the Karhunen-Lo\`eve decomposition in reducing the dimensionality of the data vector for cosmic shear measurements, and apply it to the final data from the \cfh survey. We find that practically all of the cosmological information can be encoded in one single radial eigenmode, from which we are able to reproduce compatible constraints with those found in the fiducial tomographic analysis (done with 7 redshift bins) with a factor of ~30 fewer datapoints. This simplifies the problem of computing the two-point function covariance matrix from mock catalogues by the same factor, or by a factor of ~800 for an analytical covariance. The resulting set of radial eigenfunctions is close to ell-independent, and therefore they can be used as redshift-dependent galaxy weights. This simplifies the application of the Karhunen-Lo\`eve decomposition to real-space and Fourier-space data, and allows one to explore the effective radial window function of the principal eigenmodes as well as the associated shear maps in order to identify potential systematics. We also apply the method to extended parameter spaces and verify that additional information may be gained by including a second mode to break parameter degeneracies. The data and analysis code are publicly available at https://github.com/emiliobellini/kl_sample.Comment: 15 pages, 16 figures. Accepted version on OJ

Duality for pathwise superhedging in continuous time

We provide a model-free pricing-hedging duality in continuous time. For a frictionless market consisting of $d$ risky assets with continuous price trajectories, we show that the purely analytic problem of finding the minimal superhedging price of a path dependent European option has the same value as the purely probabilistic problem of finding the supremum of the expectations of the option over all martingale measures. The superhedging problem is formulated with simple trading strategies, the claim is the limit inferior of continuous functions, which allows for upper and lower semi-continuous claims, and superhedging is required in the pathwise sense on a $\sigma$-compact sample space of price trajectories. If the sample space is stable under stopping, the probabilistic problem reduces to finding the supremum over all martingale measures with compact support. As an application of the general results we deduce dualities for Vovk's outer measure and semi-static superhedging with finitely many securities

Crossovers in the dynamics of supercooled liquids probed by an amorphous wall

We study the relaxation dynamics of a binary Lennard-Jones liquid in the presence of an amorphous wall generated from equilibrium particle configurations. In qualitative agreement with the results presented in Nature Phys. {\bf 8}, 164 (2012) for a liquid of harmonic spheres, we find that our binary mixture shows a saturation of the dynamical length scale close to the mode-coupling temperature $T_c$. Furthermore we show that, due to the broken symmetry imposed by the wall, signatures of an additional change in dynamics become apparent at a temperature well above $T_c$. We provide evidence that this modification in the relaxation dynamics occurs at a recently proposed dynamical crossover temperature $T_s > T_c$, which is related to the breakdown of the Stokes-Einstein relation. We find that this dynamical crossover at $T_s$ is also observed for a system of harmonic spheres as well as a WCA liquid, showing that it may be a general feature of glass-forming systems.Comment: 10 pages, 8 figure

Mass transfer and hydrodynamic characteristics of new carbon carbon packing: Application to CO2 post-combustion capture

A novel structured packing, the 4D packing, has been characterized in terms of hydrodynamics, effective area and gas side mass transfer coefficient. The increase of the 4D opening fraction allows to reduce pressure drop and to get a better capacity than Mellapak 500Y and 750Y, for which the geometric areas are similar. The 50% open 4D packing, 4D-50%, leads to effective areas which are higher than Mellapak 500Y ones, and doubled compared with Mellapak Plus 252Y ones. Effective areas for the 4D do not decrease when the opening fraction increases from 30 to 50%, this indicates that a non-negligible amount of droplets is generated at 50%. Gas side mass transfer coefficient had been measured with an original experimental method: water evaporation. Corresponding results seem to be in agreement with the literature, and with the fact that a large amount of droplets is generated. Correlations are proposed for both effective area and gas side mass transfer coefficient for the 4D-50%.The 4D-50% packing could be very interesting for post-combustion CO2 capture since it generates low pressure drop and a very high interfacial area. This will be further confirmed by an economic study for which the absorber plant will be designed with a rate based model

Modern computational studies of the glass transition

The physics of the glass transition and amorphous materials continues to attract the attention of a wide research community after decades of effort. Supercooled liquids and glasses have been studied numerically since the advent of molecular dynamics and Monte Carlo simulations in the last century. Computer studies have greatly enhanced both experimental discoveries and theoretical developments and constitute an active and continually expanding research field. Our goal in this review is to provide a modern perspective on this area. We describe the need to go beyond canonical methods to attack a problem that is notoriously difficult in terms of time scales, length scales, and physical observables. We first summarise recent algorithmic developments to achieve enhanced sampling and faster equilibration using replica exchange methods, cluster and swap Monte Carlo algorithms, and other techniques. We then review some major recent advances afforded by these novel tools regarding the statistical mechanical description of the liquid-to-glass transition as well as the mechanical, vibrational and thermal properties of the glassy solid. We finally describe some important challenges for future research

Experimental tracking of limit-point bifurcations and backbone curves using control-based continuation

Control-based continuation (CBC) is a means of applying numerical continuation directly to a physical experiment for bifurcation analysis without the use of a mathematical model. CBC enables the detection and tracking of bifurcations directly, without the need for a post-processing stage as is often the case for more traditional experimental approaches. In this paper, we use CBC to directly locate limit-point bifurcations of a periodically forced oscillator and track them as forcing parameters are varied. Backbone curves, which capture the overall frequency-amplitude dependence of the system’s forced response, are also traced out directly. The proposed method is demonstrated on a single-degree-of-freedom mechanical system with a nonlinear stiffness characteristic. Results are presented for two configurations of the nonlinearity — one where it exhibits a hardening stiffness characteristic and one where it exhibits softening-hardening. </jats:p

HYDRODYNAMIC MEASUREMENTS AROUND MOVING PROFILES: FLAPPING FLIGHT, WATER TURBINE, AND OSCILLATING PROFILE

In the field of the fluid mechanics, the team HYDEE (Hydrodynamics and Environmental flow section) of the institute Pprime is involved in the understanding of flows around moving profiles for environmental applications, the maritime transport, the renewable energy production, The research interests cover fundamental aspects of unsteady flows with moving structures, turbulent free-surface flows, environmental flows and mixing through different national and European programs. Fundamental contributions to optical flow measurements include PIV stereoscopy PIV measurement techniques and recently free surface measurement and volumetric measurement techniques have been obtained

SYNCHRONIZATION OF A SLIDE PRESENTATION AND PRESENTATION VIDEO RECORDING

A technique is proposed for assisting a user with presenting and recording a slide based presentation on a cloud-content based platform. A document application provided by the cloud-content based platform receives a request to record a video of a slide presentation. During the slide presentation, the document application generates a set of timestamp bookmarks, where each timestamp bookmark corresponds with a slide of the slide presentation document. At the end of the presentation, the video recording terminates and the slide presentation and the recorded presentation video is made available for consumption by one or more viewers. During consumption, the viewer is able to select a slide of interest and, based on the user selection, the application will present the viewer with the portion of the video recording that has the time stamp associated with the selected slide

Charge separation by photoexcitation in semicrystalline polymeric semiconductors: An intrinsic or extrinsic mechanism?

We probe charge photogeneration and subsequent recombination dynamics in neat regioregular poly(3-hexylthiophene) films over six decades in time by means of time-resolved photoluminescence spectroscopy. Exciton dissociation at 10K occurs extrinsically at interfaces between molecularly ordered and disordered domains. Polaron pairs thus produced recombine by tunnelling with distributed rates governed by the distribution of electron-hole radii. Quantum-chemical calculations suggest that hot-exciton dissociation at such interfaces results from a high charge-transfer character.Comment: 10 pages, 3 figure