8 research outputs found
Coexistence of Intermetallic Complexions and Bulk Particles in Grain Boundaries in the ZEK100 Alloy
Magnesium-based alloys are highly sought after in the industry due to their lightweight and reliable strength. However, the hexagonal crystal structure of magnesium results in the mechanical propertiesâ anisotropy. This anisotropy is effectively addressed by alloying magnesium with elements like zirconium, zinc, and rare earth metals (REM). The addition of these elements promotes rapid seed formation, yielding small grains with a uniform orientation distribution, thereby reducing anisotropy. Despite these benefits, the formation of intermetallic phases (IP) containing Zn, Zr, and REM within the microstructure can be a concern. Some of these IP phases can be exceedingly hard and brittle, thus weakening the material by providing easy pathways for crack propagation along grain boundaries (GBs). This issue becomes particularly significant if intermetallic phases form continuous layers along the entire GB between two neighboring GB triple junctions, a phenomenon known as complete GB wetting. To mitigate the risks associated with complete GB wetting and prevent the weakening of the alloyâs structure, understanding the potential occurrence of a GB wetting phase transition and how to control continuous GB layers of IP phases becomes crucial. In the investigation of a commercial magnesium alloy, ZEK100, the GB wetting phase transition (i.e., between complete and partial GB wetting) was successfully studied and confirmed. Notably, complete GB wetting was observed at temperatures near the liquidus point of the alloy. However, at lower temperatures, a coexistence of a nano-scaled precipitate film and bulk particles with nonzero contact angles within the same GB was observed. This insight into the wetting transition characteristics holds potential to expand the range of applications for the present alloy in the industry. By understanding and controlling GB wetting phenomena, the alloyâs mechanical properties and structural integrity can be enhanced, paving the way for its wider utilization in various industrial applications
Influence of Heat Treatment and High-Pressure Torsion on Phase Transformations in TiZrHfMoCr High-Entropy Alloy
This research was funded by the Russian Ministry of Science and Higher Education (contract no. 075-15-2021-945 grant no. 13.2251.21.0013).The study focused on a 21.99 at.%Tiâ22.49 at.%Zrâ20.35 at.%Hfâ17.45 at.%Moâ17.73 at.%Cr). Analytical techniques such as X-ray diffraction, scanning electron microscopy as well as X-ray absorption spectroscopy were employed to investigate the alloyâs structure, phase transformations, and properties. The alloy in the as-cast state contained three phases, namely the body-centred cubic (A2) phase, hexagonal Laves phase (C14), and cubic Laves phase (C15). The alloy has been annealed for a long time at different temperatures. It led to the disappearance of the hexagonal Laves phase, leaving behind two primary phases, namely the cubic Laves phase (C15) and the body-centered cubic phase (A2). At 1200 °C, the A2 phase almost disappeared, resulting in a practically single-phase sample. After a high-pressure torsion (HPT) treatment, the hexagonal Laves phase disappeared entirely, while the A2 and C15 phases remained. The grain size of the A2 and C15 phases was refined after HPT and grains were elongated, and their configuration resembled a layered structure. The high hardness of the A2 and C15 + C14 phases accounted for this behavior. The lattice parameters in the A2 and C15 phases after HPT treatment approached those observed after prolonged annealing at 1000 °C, indicating that the composition of these phases after short-term high-pressure torsion at ambient temperature is equivalent to the composition of these phases after long tempering at 1000 °C. The rate of diffusion-like mass transfer during severe plastic deformation was estimated to be many orders of magnitude higher than that for conventional bulk diffusion at the HPT treatment temperature and similar to that at elevated temperatures above 1000 °C. X-ray absorption spectroscopy results obtained at K-edges of Ti, Cr, Zr, and Mo as well as at the L3-edge of Hf indicated that the local environment around metal atoms before HPT was similar to that after HPT. However, the static disorder increased after HPT, which could be attributed to an increased specific amount of metal atoms in the disordered grain boundary layers after HPT-driven grain refinement. --//-- This is an open access article Gornakova, A.; Straumal, B.; Kuzmin, A.; Tyurin, A.; Chernyaeva, E.; Druzhinin, A.; Afonikova, N.; Davdian, G. Influence of Heat Treatment and High-Pressure Torsion on Phase Transformations in TiZrHfMoCr High-Entropy Alloy. Metals 2023, 13, 1030. https://doi.org/10.3390/met13061030 published under the CC BY 4.0 licence.Russian Ministry of Science and Higher Education (contract no. 075-15-2021-945 grant no. 13.2251.21.0013). The Institute of Solid State Physics, University of Latvia at the Center of Excellence has received funding from the European Unionâs Horizon 2020 Framework Programme H2020-WIDESPREAD-01-2016-2017-TeamingPhase2 under grant agreement No. 739508, project CAMART2
Grain Boundary Wetting Transition in the Mg-Based ZEK 100 Alloy
Modern magnesium-based alloys are broadly used in various industries as well as for biodegradable medical implants due to their exceptional combination of light weight, strength, and plasticity. The studied ZEK100 alloy had a nominal composition of 1 wt.% zinc, 0.1 wt.% zirconium, and 0.1 wt.% rare earth metals (REMs) such as Y, Ce, Nd, and La, with the remainder being Mg. It has been observed that between the solidus (Ts = 529.5 ± 0.5 °C) and liquidus temperature (Tl = 645 ± 5 °C), the Mg/Mg grain boundaries can contain either the droplets of a melt (incomplete or partial wetting) or the continuous liquid layers separating the abutting Mg grains (complete wetting). With the temperature increasing from Ts to Tl, the transformation proceeds from incomplete to complete grain boundary wetting. Below 565 °C, all grain boundaries are partially wetted by the melt. Above 565 °C, the completely wetted Mg/Mg grain boundaries appear. Their portion grows quickly with an increasing temperature until reaching 100% at 622 °C. Above 622 °C, all the solid Mg grains are completely surrounded by the melt. After rapid solidification, the REM-rich melt forms brittle intermetallic compounds. The compression strength as well as the compression yield strength parameter Ï02 strongly depend on the morphology of the grain boundary layers. If the hard and brittle intermetallic phase has the shape of separated particles (partial wetting), the overall compression strength is about 341 MPa and Ï02 = 101 MPa. If the polycrystal contains the continous intergarnular layers of the brittle intermetallic phase (complete wetting), the overall compression strength drops to 247 Mpa and Ï02 to 40 Mpa. We for the first time observed, therefore, that the grain boundary wetting phenomena can strongly influence the mechanical properties of a polycrystal. Therefore, grain boundary wetting can be used for tailoring the behavior of materials
Coexistence of Intermetallic Complexions and Bulk Particles in Grain Boundaries in the ZEK100 Alloy
Magnesium-based alloys are highly sought after in the industry due to their lightweight and reliable strength. However, the hexagonal crystal structure of magnesium results in the mechanical propertiesâ anisotropy. This anisotropy is effectively addressed by alloying magnesium with elements like zirconium, zinc, and rare earth metals (REM). The addition of these elements promotes rapid seed formation, yielding small grains with a uniform orientation distribution, thereby reducing anisotropy. Despite these benefits, the formation of intermetallic phases (IP) containing Zn, Zr, and REM within the microstructure can be a concern. Some of these IP phases can be exceedingly hard and brittle, thus weakening the material by providing easy pathways for crack propagation along grain boundaries (GBs). This issue becomes particularly significant if intermetallic phases form continuous layers along the entire GB between two neighboring GB triple junctions, a phenomenon known as complete GB wetting. To mitigate the risks associated with complete GB wetting and prevent the weakening of the alloyâs structure, understanding the potential occurrence of a GB wetting phase transition and how to control continuous GB layers of IP phases becomes crucial. In the investigation of a commercial magnesium alloy, ZEK100, the GB wetting phase transition (i.e., between complete and partial GB wetting) was successfully studied and confirmed. Notably, complete GB wetting was observed at temperatures near the liquidus point of the alloy. However, at lower temperatures, a coexistence of a nano-scaled precipitate film and bulk particles with nonzero contact angles within the same GB was observed. This insight into the wetting transition characteristics holds potential to expand the range of applications for the present alloy in the industry. By understanding and controlling GB wetting phenomena, the alloyâs mechanical properties and structural integrity can be enhanced, paving the way for its wider utilization in various industrial applications
Effect of High-Pressure Torsion on Phase Formation and Mechanical Properties of a High-Entropy TiZrHfMoCrCo Alloy
This research was funded by the Russian Ministry of Science and Higher Education (contract no. 075-15-2021-945; grant no. 13.2251.21.0013). We acknowledge DESY (Hamburg, Germany), a member of the Helmholtz Association HGF, for the provision of experimental facilities. Parts of this research were carried out at the PETRA III P65 beamline.This investigation delved into the alterations in the mechanical properties of a TiZrHfMoCrCo high-entropy alloy due to phase transformations induced by high-pressure torsion (HPT). The alloyâs genesis involved levitation melting within an argon atmosphere, presenting two distinct states for analysis: the initial, post-manufacturing state and the state subsequent to HPT treatment. The original alloy featured a composition comprising a singular A2 phase with a bcc lattice and two Laves phases, C15 and C14. The HPT process triggered significant phase modifications: a retention of one C15 Laves phase and decomposition of the bcc phase into two distinct phases exhibiting different bcc lattice parameters. The HPT-induced effect prominently manifests as strong grain refinement. However, scanning electron microscopy (SEM) observations unveiled persistent inhomogeneities at a micron scale both before and after HPT treatment. Thus, grain refinement occurs separately within each of the bcc and Laves phases, visible in the light, dark, and gray areas in SEM images, while mixing does not occur on the scale of several microns. The examination of Ti, Cr, Co, Zr, Mo, and Hf via X-ray absorption spectroscopy (EXAFS) at specific K-edges and L3-edge revealed that the HPT treatment conserves the local atomic environment of metal atoms, albeit with a slight elevation in static disorder. Assessments through microhardness and three-point bending tests demonstrated the materialâs inherent hardness and brittleness. The microhardness, standing at a substantial value of 600 HV, displayed negligible augmentation post-HPT. However, the microhardness of individual phases exhibited a notable alteration, nearly doubling in magnitude. © 2023 by the authors. --//-- This is an open-access article: Gornakova, A.S.; Kabirova, D.B.; Korneva, A.; Straumal, B.; Imayev, M.F.; Kuzmin, A.; Czaja, P.; Afonikova, N.S.; Orlov, V.I.; Nekrasov, A.N.; et al. Effect of High-Pressure Torsion on Phase Formation and Mechanical Properties of a High-Entropy TiZrHfMoCrCo Alloy. Materials 2023, 16, 7558. https://doi.org/10.3390/ma16247558 published under the CC BY 4.0 licence.Russian Ministry of Science and Higher Education (contract no. 075-15-2021-945; grant no. 13.2251.21.0013); The Institute of Solid State Physics, University of Latvia at the Center of Excellence has received funding from the European Unionâs Horizon 2020 Framework Programme H2020-WIDESPREAD-01-2016-2017-TeamingPhase2 under grant agreement No. 739508, project CAMART2
Phase Transformations Caused by Heat Treatment and High-Pressure Torsion in TiZrHfMoCrCo Alloy
In this work the high-entropy alloy studied contained six components, Ti/Zr/Hf/Mo/Cr/Co, and three phases, namely one phase with body-centered cubic lattice (BCC) and two Laves phases C14 and C15. A series of annealings in the temperature range from 600 to 1000 °C demonstrated not only a change in the microstructure of the TiZrHfMoCrCo alloy, but also the modification of phase composition. After annealing at 1000 °C the BCC phase almost fully disappeared. The annealing at 600 and 800 °C leads to the formation of new Laves phases. After high-pressure torsion (HPT) of the as-cast TiZrHfMoCrCo alloy, the grains become very small, the BCC phase prevails, and C14 Laves phase completely disappears. This state is similar to the state after annealing at high effective temperature Teff. The additional annealing at 1000 °C after HPT returns the phase composition back to the state similar to that of the as-cast alloy after annealing at 1000 °C. At 1000 °C the BCC phase completely wets the C15/C15 grain boundaries (GBs). At 600 and 800 °C the GB wetting is incomplete. The big spread of nanohardness and Youngâs modulus for the BCC phase and (C15 + C14) Laves phases is observed
Influence of the Phase Composition of Titanium Alloys on Cell Adhesion and Surface Colonization
The pivotal role of metal implants within the hostâs body following reconstructive surgery hinges primarily on the initial phase of the process: the adhesion of host cells to the implantâs surface and the subsequent colonization by these cells. Notably, titanium alloys represent a significant class of materials used for crafting metal implants. This study, however, marks the first investigation into how the phase composition of titanium alloys, encompassing the volume fractions of the α, ÎČ, and Ï phases, influences cell adhesion to the implantâs surface. Moreover, the research delves into the examination of induced hemolysis and cytotoxicity. To manipulate the phase composition of titanium alloys, various parameters were altered, including the chemical composition of titanium alloys with iron and niobium, annealing temperature, and high-pressure torsion parameters. By systematically adjusting these experimental parameters, we were able to discern the distinct impact of phase composition. As a result, the study unveiled that the colonization of the surfaces of the examined TiâNb and TiâFe alloys by human multipotent mesenchymal stromal cells exhibits an upward trend with the increasing proportion of the Ï phase, concurrently accompanied by a decrease in the α and ÎČ phases. These findings signify a new avenue for advancing Ti-based alloys for both permanent implants and temporary fixtures, capitalizing on the ability to regulate the volume fractions of the α, ÎČ, and Ï phases. Furthermore, the promising characteristics of the Ï phase suggest the potential emergence of a third generation of biocompatible Ti alloys, the Ï-based materials, following the first-generation α-Ti alloys and second-generation ÎČ alloys
Severe plastic deformation for producing Superfunctional ultrafine-grained and heterostructured materials: An interdisciplinary review
Ultrafine-grained and heterostructured materials are currently of high interest due to their superior mechanical and functional properties. Severe plastic deformation (SPD) is one of the most effective methods to produce such materials with unique microstructure-property relationships. In this review paper, after summarizing the recent progress in developing various SPD methods for processing bulk, surface and powder of materials, the main structural and microstructural features of SPD-processed materials are explained including lattice defects, grain boundaries and phase transformations. The properties and potential applications of SPD-processed materials are then reviewed in detail including tensile properties, creep, superplasticity, hydrogen embrittlement resistance, electrical conductivity, magnetic properties, optical properties, solar energy harvesting, photocatalysis, electrocatalysis, hydrolysis, hydrogen storage, hydrogen production, CO2 conversion, corrosion resistance and biocompatibility. It is shown that achieving such properties is not currently limited to pure metals and conventional metallic alloys, and a wide range of materials are processed by SPD, including high-entropy alloys, glasses, semiconductors, ceramics and polymers. It is particularly emphasized that SPD has moved from a simple metal processing tool to a powerful means for the discovery and synthesis of new superfunctional metallic and nonmetallic materials. The article ends by declaring that the borders of SPD have been extended from materials science and it has become an interdisciplinary tool to address scientific questions such as the mechanism of geological and astronomical phenomena and the origin of life