Thermionic-enhanced near-field thermophotovoltaics

Solid-state heat-to-electrical power converters are thermodynamic engines that use fundamental particles, such as electrons or photons, as working fluids. Virtually all commercially available devices are thermoelectric generators, in which electrons flow through a solid driven by a temperature difference. Thermophotovoltaics and thermionics are highly efficient alternatives relying on the direct emission of photons and electrons. However, the low energy flux carried by the emitted particles significantly limits their generated electrical power density potential. Creating nanoscale vacuum gaps between the emitter and the receiver in thermionic and thermophotovoltaic devices enables a significant enhancement of the electron and photon energy fluxes, respectively, which in turn results in an increase of the generated electrical power density. Here we propose a thermionic-enhanced near-field thermophotovoltaic device that exploits the simultaneous emission of photons and electrons through nanoscale vacuum gaps. We present the theoretical analysis of a device in which photons and electrons travel from a hot LaB6-coated tungsten emitter to a closely spaced BaF2-coated InGaAs photovoltaic cell. Photon tunnelling and space charge removal across the nanoscale vacuum gap produce a drastic increase in flux of electrons and photons, and subsequently, of the generated electrical power density. We show that conversion efficiencies and electrical power densities of 30% and 70W/cm2 are achievable at 2000K for a practicable gap distance of 100nm, and thus greatly enhance the performances of stand-alone near-field thermophotovoltaic devices (10% and 10W/cm2). A key practical advantage of this nanoscale energy conversion device is the use of grid-less cell designs, eliminating the issue of series resistance and shadowing losses, which are unavoidable in conventional near-field thermophotovoltaic devices.Comment: Nano Energy (2019

Optimum semiconductor bandgaps in single junction and multijunction thermophotovoltaic converters

The choice of the optimum semiconductor for manufacturing thermophotovoltaic (TPV) cells is not straightforward. In contrast to conventional solar photovoltaics (PV) where the optimum semiconductor bandgap is determined solely by the spectrum (and eventually the irradiance) of the incident solar light, in a TPV converter it depends on the emitter temperature and on the spectral control elements determining the net spectral power flux between the TPV cell and the emitter. Additionally, in TPV converters there is a tradeoff between power density and conversion efficiency that does not exist in conventional solar PV systems. Thus, the choice of the proper semiconductor compound in TPV converters requires a thorough analysis that has not been presented so far. This paper presents the optimum semiconductor bandgaps leading to the maximum efficiency and power density in TPV converters using both single junction and multijunction TPV cells. These results were obtained within the framework of the detailed balance theory and assuming only radiative recombination. Optimal bandgaps are provided as a function of the emitter and cell temperature, as well as the degree of spectral control. I show that multijunction TPV cells are excellent candidates to maximize both the efficiency and the power density simultaneously, eliminating the historical tradeoff between efficiency and power density of TPV converters. Finally, multijunction TPV cells are less sensitive to photon recycling losses, which suggest that they can be combined with relatively simple cut-off spectral control systems to provide practically-viable high performing TPV devices

Thermophotovoltaic conversion efficiency measurement at high view factors

A standardized method for measuring thermophotovoltaic (TPV) efficiency has not been yet established, which makes the reported results difficult to compare. Besides, most of the TPV efficiencies reported to date have been obtained using small view factors, i.e., large cell-to-emitter distances, so the impact of the series resistance is usually underestimated, and the optical cavity effects, i.e., the multiple reflections taking place between the emitter and the cell, are not accounted for experimentally. In this work, we present an experimental setup able to measure the TPV efficiency under high view factors (up to 0.98), by using small emitter-to-cell distances (< 1 mm). This allows a more accurate direct measurement of the TPV efficiency at higher power densities than previous works. As a result, a TPV efficiency of 26.4+-0.1 % and a power density of 4.3+-0.8 W/cm2 have been obtained for an InGaAs TPV cell with a back surface reflector irradiated by a graphite thermal emitter at 1592 C

Detailed balance analysis of solar thermophotovoltaic systems made up of single junction photovoltaic cells and broadband thermal emitters

This paper presents a detailed balance analysis of a solar thermophotovoltaic system comprising an optical concentrator, a cut-off broad band absorber and emitter, and single junction photovoltaic cells working at the radiative limit with an integrated back-side reflector in a configuration in which the cells enclose the emitter to form an optical cavity. The analysis includes the effect of multiple variables on the system performance (efficiency and electrical power density), such as the concentration factor, the emitter-to-absorber area ratio, the absorber and emitter cut-off energies, the semiconductor band-gap energy and the voltage of the cells. Furthermore, the effect of optical losses within the cavity such as those attributed to a back-side reflector with reflectivity lower than one or to a semi-open optical cavity is also included. One of our main conclusions is that for a planar system configuration (the emitter, the cells and the absorber have the same area) the combination of low concentration and a spectrally selective absorber provides the highest system efficiencies. The efficiency limit of this kind of systems is 45.3%, which exceeds the Shockley–Queisser limit of 40.8% (obtained for a single junction solar cell, directly illuminated by the sun, working under maximum concentration and with an optimized band-gap). This system also has the great benefit of requiring a very low concentration factor of 4.4 suns

Global optimization of solar thermophotovoltaic systems

n this paper, we present a theoretical model based on the detailed balance theory of solar thermophotovoltaic systems comprising multijunction photovoltaic cells, a sunlight concentrator and spectrally selective surfaces. The full system has been defined by means of 2n + 8 variables (being n the number of sub-cells of the multijunction cell). These variables are as follows: the sunlight concentration factor, the absorber cut-off energy, the emitter-to-absorber area ratio, the emitter cut-off energy, the band-gap energy(ies) and voltage(s) of the sub-cells, the reflectivity of the cells' back-side reflector, the emitter-to-cell and cell-to-cell view factors and the emitter-to-cell area ratio. We have used this model for carrying out a multi-variable system optimization by means of a multidimensional direct-search algorithm. This analysis allows to find the set of system variables whose combined effects results in the maximum overall system efficiency. From this analysis, we have seen that multijunction cells are excellent candidates to enhance the system efficiency and the electrical power density. Particularly, multijunction cells report great benefits for systems with a notable presence of optical losses, which are unavoidable in practical systems. Also, we have seen that the use of spectrally selective absorbers, rather than black-body absorbers, allows to achieve higher system efficiencies for both lower concentration and lower emitter-to-absorber area ratio. Finally, we have seen that sun-to-electricity conversion efficiencies above 30% and electrical power densities above 50 W/cm2 are achievable for this kind of systems

Development and experimental evaluation of a complete solar thermophotovoltaic system

We present a practical implementation of a solar thermophotovoltaic (TPV) system. The system presented in this paper comprises a sunlight concentrator system, a cylindrical cup-shaped absorber/emitter (made of tungsten coated with HfO2), and an hexagonal-shaped water-cooled TPV generator comprising 24 germanium TPV cells, which is surrounding the cylindrical absorber/emitter. This paper focuses on the development of shingled TPV cell arrays, the characterization of the sunlight concentrator system, the estimation of the temperature achieved by the cylindrical emitters operated under concentrated sunlight, and the evaluation of the full system performance under real outdoor irradiance conditions. From the system characterization, we have measured short-circuit current densities up to 0.95 A/cm2, electric power densities of 67 mW/cm2, and a global conversion efficiency of about 0.8%. To our knowledge, this is the first overall solar-to-electricity efficiency reported for a complete solar thermophotovoltaic system. The very low efficiency is mainly due to the overheating of the cells (up to 120 °C) and to the high optical concentrator losses, which prevent the achievement of the optimum emitter temperature. The loss analysis shows that by improving both aspects, efficiencies above 5% could be achievable in the very short term and efficiencies above 10% could be achieved with further improvements

Solar photovoltaic power-to-heat-to-power energy storage

This article summarizes part of the work developed, and already published, in the context of the AMADEUS project (www.amadeusproject. eu), a FET-OPEN project funded by the European Commission to research a new generation of materials and solid state devices for ultra-high temperature energy storage and conversion. New silicon-based alloys as new phase change materials (PCMs) are explored, achieving latent heat in the range of 1000-2000 kWh/m3, which means an order of magnitude greater than that of typical saltbased PCMs used in concentrated solar power (CSP). In addition, silicon-based PCMs lead to storage temperatures well beyond 1000 ºC, and so this project aims at breaking the mark of ~ 600 ºC rarely exceeded by current state of the art thermal energy storage (TES). Furthermore, this article presents the most significant outcomes of work developed to assesses whether it is profitable to store solar photovoltaic (PV) electricity in the form of heat and convert it back to electricity on demand in the residential sector

Energía Solar Termofotovoltaica

La energía solar fotovoltaica es una de las alternativas renovables más interesantes para afrontar el futuro energético del planeta desde el punto de vista de la sostenibilidad. Sin embargo, actualmente los sistemas fotovoltaicos comerciales son poco eficientes –aprovechan sólo el 10% de la radiación incidente– y económicamente menos atractivos que las fuentes de energía convencionales. En este trabajo se analizan las principales causas que limitan la eficiencia de conversión de radiación en electricidad y, tras ello, se presenta una novedosa línea de investigación basada en la utilización de sistemas termofotovoltaicos conjuntamente con concentradores solares, estrategia que permite incrementar la eficiencia de conversión hasta alcanzar valores por encima del 30%, algo fundamental para aumentar la competitividad de las técnicas fotovoltaicas. Por último se presenta el prototipo de Sistema Solar Termofotovoltaico que se está construyendo en el Instituto de Energía Solar en colaboración con los principales laboratorios de investigación europeos en la materia

Ultra-dense energy storage utilizing high melting point metallic alloys and photovoltaic cells

A novel concept for energy storage utilizing high melting point metallic alloys and photovoltaic cells is presented. In the proposed system, the energy is stored in the form of latent heat of metallic alloys and converted to electricity upon demand by infrared sensitive photovoltaic cells. Silicon is considered in this paper due to its extremely high latent heat (1800 J/g), melting point (1410°C), low cost (�$1.7/kg) and abundance on earth. The proposed solution enables an enormous energy storage density of � 500 Wh/kg and � 1 MWh/m3, which is 12 times higher than that of lead-acid batteries, 4 times than that of Li-ion batteries and 10 to 20 times than that of the molten salts utilized in CSP systems