Spin projection chromatography

We formulate the many-body spin dynamics at high temperature within the non-equilibrium Keldysh formalism. For the simplest XY interaction, analytical expressions in terms of the one particle solutions are obtained for linear and ring configurations. For small rings of even spin number, the group velocities of excitations depend on the parity of the total spin projection. This should enable a dynamical filtering of spin projections with a given parity i.e. a Spin projection chromatography.Comment: 13 pages, 3 figure

Decoherence as attenuation of mesoscopic echoes in a spin-chain channel

An initial local excitation in a confined quantum system evolves exploring the whole system, returning to the initial position as a mesoscopic echo at the Heisenberg time. We consider a two weakly coupled spin chains, a spin ladder, where one is a quantum channel while the other represents an environment. We quantify decoherence in the quantum channel through the attenuation of the mesoscopic echoes. We evaluate decoherence rates for different ratios between sources of amplitude fluctuation and dephasing in the inter-chain interaction Hamiltonian. The many-body dynamics is seen as a one-body evolution with a decoherence rate given by the Fermi golden rule.Comment: 12 pages, 7 figure

Quantum parallelism as a tool for ensemble spin dynamics calculations

Efficient simulations of quantum evolutions of spin-1/2 systems are relevant for ensemble quantum computation as well as in typical NMR experiments. We propose an efficient method to calculate the dynamics of an observable provided that the initial excitation is "local". It resorts a single entangled pure initial state built as a superposition, with random phases, of the pure elements that compose the mixture. This ensures self-averaging of any observable, drastically reducing the calculation time. The procedure is tested for two representative systems: a spin star (cluster with random long range interactions) and a spin ladder.Comment: 5 pages, 3 figures, improved version of the manuscrip

Quantum dynamics under coherent and incoherent effects of a spin bath in the Keldysh formalism: application to a spin swapping operation

We develop the Keldysh formalism for the polarization dynamics of an open spin system. We apply it to the swapping between two qubit states in a model describing an NMR cross-polarization experiment. The environment is a set of interacting spins. For fast fluctuations in the environment, the analytical solution shows effects missed by the secular approximation of the Quantum Master Equation for the density matrix: a frequency decrease depending on the system-environment escape rate and the quantum quadratic short time behavior. Considering full memory of the bath correlations yields a progressive change of the swapping frequency.Comment: 16 pages, 3 figures, final for

Perfect state transfers by selective quantum interferences within complex spin networks

We present a method that implement directional, perfect state transfers within a branched spin network by exploiting quantum interferences in the time-domain. That provides a tool to isolate subsystems from a large and complex one. Directionality is achieved by interrupting the spin-spin coupled evolution with periods of free Zeeman evolutions, whose timing is tuned to be commensurate with the relative phases accrued by specific spin pairs. This leads to a resonant transfer between the chosen qubits, and to a detuning of all remaining pathways in the network, using only global manipulations. As the transfer is perfect when the selected pathway is mediated by 2 or 3 spins, distant state transfers over complex networks can be achieved by successive recouplings among specific pairs/triads of spins. These effects are illustrated with a quantum simulator involving 13C NMR on Leucine's backbone; a six-spin network.Comment: 5 pages, 3 figure

Comparing Catalysts of the Direct Synthesis of Hydrogen Peroxide in Organic Solvent: is the Measure of the Product an Issue?

The direct synthesis of hydrogen peroxide has been for about 20 years a hot topic in \u201cgreen\u201d catalysis. Several methods, which are well established to measure the concentration of hydrogen peroxide in water are also applied to the analysis of reaction mixtures from the direct synthesis of H2O2. However, this step could not be always straightforward, because these mixtures contain almost invariably organic solvents and, sometimes, selectivity enhancers which can interfere in some, at the least, of the most popular titrimetric methods. This work presents a comparative investigation of iodometry, cerimetry, permanganometry (titrimetric methods) and spectrophotometric analysis of TiIV/H2O2 adduct, as applied to analysis of hydrogen peroxide produced by its direct synthesis. They account for more than 90 % of the competent literature since 2000. Their pros and cons are highlighted to provide a guideline for the choice of the best possible method of analysis and for the comparison of catalytic results assessed in different ways in the context of the direct synthesis of hydrogen peroxide

Time Reversal Mirror and Perfect Inverse Filter in a Microscopic Model for Sound Propagation

Time reversal of quantum dynamics can be achieved by a global change of the Hamiltonian sign (a hasty Loschmidt daemon), as in the Loschmidt Echo experiments in NMR, or by a local but persistent procedure (a stubborn daemon) as in the Time Reversal Mirror (TRM) used in ultrasound acoustics. While the first is limited by chaos and disorder, the last procedure seems to benefit from it. As a first step to quantify such stability we develop a procedure, the Perfect Inverse Filter (PIF), that accounts for memory effects, and we apply it to a system of coupled oscillators. In order to ensure a many-body dynamics numerically intrinsically reversible, we develop an algorithm, the pair partitioning, based on the Trotter strategy used for quantum dynamics. We analyze situations where the PIF gives substantial improvements over the TRM.Comment: Submitted to Physica

Environmentally induced Quantum Dynamical Phase Transition in the spin swapping operation

Quantum Information Processing relies on coherent quantum dynamics for a precise control of its basic operations. A swapping gate in a two-spin system exchanges the degenerate states |+,-> and |-,+>. In NMR, this is achieved turning on and off the spin-spin interaction b=\Delta E that splits the energy levels and induces an oscillation with a natural frequency \Delta E/\hbar. Interaction of strength \hbar/\tau_{SE}, with an environment of neighboring spins, degrades this oscillation within a decoherence time scale \tau_{\phi}. While the experimental frequency \omega and decoherence time \tau_{\phi} were expected to be roughly proportional to b/\hbar and \tau_{SE} respectively, we present here experiments that show drastic deviations in both \omega and \tau_{\phi}. By solving the many spin dynamics, we prove that the swapping regime is restricted to \Delta E \tau_{SE} > \hbar. Beyond a critical interaction with the environment the swapping freezes and the decoherence rate drops as 1/\tau_{\phi} \propto (b/\hbar)^2 \tau_{SE}. The transition between quantum dynamical phases occurs when \omega \propto \sqrt{(b/\hbar)^{2}-(k/\tau_{SE})^2} becomes imaginary, resembling an overdamped classical oscillator. Here, 0<k^2<1 depends only on the anisotropy of the system-environment interaction, being 0 for isotropic and 1 for XY interactions. This critical onset of a phase dominated by the Quantum Zeno effect opens up new opportunities for controlling quantum dynamics.Comment: Final version. One figure and some equations corrected, 10 pages, 4 figure

Decoherence under many-body system-environment interactions: a stroboscopic representation based on a fictitiously homogenized interaction rate

An environment interacting with portions of a system leads to multiexponential interaction rates. Within the Keldysh formalism, we fictitiously homogenize the system-environment interaction yielding a uniform decay rate facilitating the evaluation of the propagators. Through an injection procedure we neutralize the fictitious interactions. This technique justifies a stroboscopic representation of the system-environment interaction which is useful for numerical implementation and converges to the natural continuous process. We apply this procedure to a fermionic two-level system and use the Jordan-Wigner transformation to solve a two-spin swapping gate in the presence of a spin environment.Comment: 11 pages, 3 figures, title changed, some typos change