6 research outputs found
Analytical method for predicting the quasi-static buffeting response of transmission conductor under non-stationary winds
This paper was reviewed and accepted by the APCWE-IX Programme Committee for Presentation at the 9th Asia-Pacific Conference on Wind Engineering, University of Auckland, Auckland, New Zealand, held from 3-7 December 2017
Fe-Catalyzed Reductive Coupling of Unactivated Alkenes with β‑Nitroalkenes
An
Fe-catalyzed reductive coupling of unactivated alkenes with
β-nitroalkenes has been developed. The reaction proceeds through
a radical pathway, with β-nitroalkenes serving as the vinylating
reagents and the nitro group being cleaved in the process. Therefore,
this method provides a viable synthetic approach to valuable secondary-
and tertiary-alkylated styrene derivatives. Furthermore, control experiments
were conducted and a plausible mechanism is proposed
Facile Synthesis of Isoindolinones via Rh(III)-Catalyzed One-Pot Reaction of Benzamides, Ketones, and Hydrazines
A RhÂ(III)-catalyzed
one-pot reaction of benzamides, ketones, and
hydrazines for facile access to isoindolinones is reported. In this
method, various ketones are transformed into donor–donor diazo
compounds, which sequentially engage in insertion with benzamides
under RhÂ(III) catalysis to generate <i>N</i>-substituted
quaternary isoindolinones
Silver(I)-Mediated Phosphorylation/Cyclization Cascade of <i>N</i>‑Cyanamide Alkenes for Divergent Access to Quinazolinones and Dihydroisoquinolinones
A silverÂ(I)-mediated
phosphorylation/cyclization radical cascade
of <i>N</i>-cyanamide alkenes has been developed. The addition
of in situ generated phosphorus radical to <i>N</i>-cyanamide
alkenes triggers the cascade, resulting in late-stage cyclization
toward divergent access to 4-quinazolinones and dihydroisoquinolinones.
Both terminal and internal <i>N</i>-cyanamide alkenes are
applicable in this protocol, and the cyclizations are consistent with
Baldwin’s rule
Silver(I)-Mediated Phosphorylation/Cyclization Cascade of <i>N</i>‑Cyanamide Alkenes for Divergent Access to Quinazolinones and Dihydroisoquinolinones
A silverÂ(I)-mediated
phosphorylation/cyclization radical cascade
of <i>N</i>-cyanamide alkenes has been developed. The addition
of in situ generated phosphorus radical to <i>N</i>-cyanamide
alkenes triggers the cascade, resulting in late-stage cyclization
toward divergent access to 4-quinazolinones and dihydroisoquinolinones.
Both terminal and internal <i>N</i>-cyanamide alkenes are
applicable in this protocol, and the cyclizations are consistent with
Baldwin’s rule
Silver(I)-Mediated Phosphorylation/Cyclization Cascade of <i>N</i>‑Cyanamide Alkenes for Divergent Access to Quinazolinones and Dihydroisoquinolinones
A silverÂ(I)-mediated
phosphorylation/cyclization radical cascade
of <i>N</i>-cyanamide alkenes has been developed. The addition
of in situ generated phosphorus radical to <i>N</i>-cyanamide
alkenes triggers the cascade, resulting in late-stage cyclization
toward divergent access to 4-quinazolinones and dihydroisoquinolinones.
Both terminal and internal <i>N</i>-cyanamide alkenes are
applicable in this protocol, and the cyclizations are consistent with
Baldwin’s rule