2 research outputs found
Direct Growth of Graphene Films on 3D Grating Structural Quartz Substrates for High-Performance Pressure-Sensitive Sensors
Conformal graphene
films have directly been synthesized on the
surface of grating microstructured quartz substrates by a simple chemical
vapor deposition process. The wonderful conformality and relatively
high quality of the as-prepared graphene on the three-dimensional
substrate have been verified by scanning electron microscopy and Raman
spectra. This conformal graphene film possesses excellent electrical
and optical properties with a sheet resistance of <2000 Ω·sq<sup>–1</sup> and a transmittance of >80% (at 550 nm), which
can
be attached with a flat graphene film on a polyÂ(dimethylsiloxane)
substrate, and then could work as a pressure-sensitive sensor. This
device possesses a high-pressure sensitivity of −6.524 kPa<sup>–1</sup> in a low-pressure range of 0–200 Pa. Meanwhile,
this pressure-sensitive sensor exhibits super-reliability (≥5000
cycles) and an ultrafast response time (≤4 ms). Owing to these
features, this pressure-sensitive sensor based on 3D conformal graphene
is adequately introduced to test wind pressure, expressing higher
accuracy and a lower background noise level than a market anemometer
Solvent-Free Process to Produce Three Dimensional Graphene Network with High Electrochemical Stability
Three-dimensional
(3D) graphene has attracted increasing attention
in electrochemical devices. However, the existing preparation technologies
usually involve a solvent process, which introduces defects and functional
groups into the 3D network. Here, we find the defects and functional
groups influence the electrochemical stability of graphene. After
an electrochemical process, the current decreases by more than 1 order
of magnitude, indicating remarkable etching of graphene. To improve
the electrochemical stability, we develop a solvent-free preparation
process to produce 3D graphene for the first time. After growth on
a 3D microporous copper by chemical vapor deposition (CVD), the copper
template is removed by a high temperature evaporation process, resulting
in 3D graphene network without any solvent process involved. The samples
exhibit remarkably improved stability with durable time 2 times, compared
with normal CVD samples, and 55 times, compared with reduced graphite
oxide, and no obvious etching is observed at 1.6 V versus saturated
calomel electrode, showing great potential for application in future
3D graphene-based high stable electrochemical devices