Time-resolved resonance Raman spectroscopy and density functional theory investigation of the CH2I-I isomer and CH2I2⋯I molecular complex products produced from ultraviolet photolysis of CH2I2 in the solution phase

The CH2I-I isomer and CH2I2···I molecular complex products produced from ultraviolet photolysis of CH2I2 in the solution phase was analyzed by using time-resolved resonance Raman spectroscopy. The structure and properties of the CH2I-I species and the CH2I2···I molecular complex and their reaction towards ethylene were compared. The results showed that the CH2I-I isomer reacts with ethylene to produce a cyclopropane product and I2 leaving group via a single step and low barrier to reaction.published_or_final_versio

SEARCHING FOR DEBRIS DISKS AROUND SEVEN RADIO PULSARS

We report on our searches for debris disks around seven relatively nearby radio pulsars, which are isolated sources that were carefully selected as targets on the basis of our deep Ks-band imaging survey. The Ks images obtained with the 6.5m Baade Magellan Telescope at Las Campanas Observatory are analyzed together with the Spitzer/IRAC images at 4.5 and 8.0μm and the WISE images at 3.4, 4.6, 12, and 22μm. No infrared counterparts of these pulsars are found, with flux upper limits of ∼μJy at near-infrared (λ < 10μm) and ∼10–1000μJy at mid-infrared wavelengths (λ > 10 μm). The results of this search are discussed in terms of the efficiency of converting the pulsar spin-down energy to thermal energy and X-ray heating of debris disks, with a comparison made of the two magnetars 4U 0142+61 and 1E 2259+586, which are suggested to harbor a debris disk.published_or_final_versio

Ethics of Artificial Intelligence Demarcations

In this paper we present a set of key demarcations, particularly important when discussing ethical and societal issues of current AI research and applications. Properly distinguishing issues and concerns related to Artificial General Intelligence and weak AI, between symbolic and connectionist AI, AI methods, data and applications are prerequisites for an informed debate. Such demarcations would not only facilitate much-needed discussions on ethics on current AI technologies and research. In addition sufficiently establishing such demarcations would also enhance knowledge-sharing and support rigor in interdisciplinary research between technical and social sciences.Comment: Proceedings of the Norwegian AI Symposium 2019 (NAIS 2019), Trondheim, Norwa

Evaluating performance of multiple RRTs

This paper presents experimental results evaluating the performance of a new multiple Rapidly-exploring Random Tree (RRT) algorithm. RRTs are randomised planners especially adept at solving difficult, high-dimensional path planning problems. However, environments with low-connectivity due to the presence of obstacles can severely affect convergence. Multiple RRTs have been proposed as a means of addressing this issue, however, this approach can adversely affect computational efficiency. This paper introduces a new and simple method which takes advantage of the benefits of multiple trees, whilst ensuring the computational burden of maintaining them is minimised. Results indicate that multiple RRTs are able to reduce the logarithmic complexity of the search, most notably in environments with high obstacle densities. © 2008 IEEE

STUDY ON THE RELATIONSHIP BETWEEN PHYSICAL STRUCTURAL INTEGRALITY AND ECOSYSTEM SERVICES VALUE IN THE RIPARIAN ZONE

Riparian zone is crucial to the health of streams and their surrounding environment. A healthy riparian zone can provide food, habitats, protecting water quality and many other ecological functions and environmental benefits. Evaluating riparian quality is essential to achieve and maintain good stream health, as well as to guarantee the ecological functions that riparian areas provide. In this study, we addressed the consistency of characterizing integrality of ecosystem of a riparian zone in Northeast China with physical structural integrality (PSI) and ecosystem service value (ESV), and explored the relationship between the PSI and ESV. The procedures included (1) evaluation of PSI of the riparian zone based on remote sensing; (2) calculation of the riparian ESV based on basic evaluation units (BEUs); (3) exploration of statistical relationships between the PSI and the ESV by the performance of linear regression. The study concluded that the trend of PSI was the same as the ESV, and they were consistent in describing the quantitative trend of the riparian zone’s ecosystem integrity. There was statistically significant correlation (R = 0.66, P \u3c 0.01 level) between PSI and ESV

Effects of hydrogen bond and solvent polarity on the C=O strectching of bis(2-thienyl)ketone in solution

The optimized structural parameters, the absorption and the resonance Raman spectra have been investigated for the bis(2-thienyl)ketone in gas phase, in cyclohexane, methanol, and acetonitrile solvents by means of time dependent density functional theory calculations, the solvent electronic polarization effect on the solvation shift is examined and in well accordance with the calculation. The effect of increasing the polarity of the solvent is well represented by the polarizable continuum model, both for the absorption spectra and resonance Raman intensities. The Raman spectra of the C=O stretching mode, which is sensitive to the intermolecular interaction for bis(2-thienyl)ketone dissolved in solvents, were systematically studied. It was found that the hydrogen bond effect plays an important role in reducing the carbonyl stretching wavenumbers. The results of Raman shifts were interpreted through the dilution effect, solvation effects, and hydrogen bond-forming effects. Furthermore, the excitation profiles of several important Raman bands of bis(2-thienyl)ketone molecule in different solvents have been critically analyzed. The solvent effects on structural and symmetry properties of the molecule in S2 electronic state as well as the short-time photo relaxation dynamics have been discussed.published_or_final_versio

Winner-take-all selection in a neural system with delayed feedback

We consider the effects of temporal delay in a neural feedback system with excitation and inhibition. The topology of our model system reflects the anatomy of the avian isthmic circuitry, a feedback structure found in all classes of vertebrates. We show that the system is capable of performing a `winner-take-all' selection rule for certain combinations of excitatory and inhibitory feedback. In particular, we show that when the time delays are sufficiently large a system with local inhibition and global excitation can function as a `winner-take-all' network and exhibit oscillatory dynamics. We demonstrate how the origin of the oscillations can be attributed to the finite delays through a linear stability analysis.Comment: 8 pages, 6 figure

Excitonic quantum confinement modified optical conductivity of monolayer and few-layered MoS2

2016-2017 > Academic research: refereed > Publication in refereed journal201804_a bcmaVersion of RecordPublishe

Electron transport and band structure in phosphorus-doped polycrystalline silicon films

We study transport mechanisms, effective mass, and band structure by measuring the resistivity, Hall, and Seebeck and Nernst coefficients in heavily phosphorus-doped polycrystalline silicon films made by thermal crystallization of amorphous silicon. We observe a change in transport mechanism which results in an increase in electron mobility from 10% to 80% of the single-crystal silicon mobility as the carrier concentration increases from 1019 to 1020 cm-3. Our measurements of effective mass at the Fermi level indicate that as the carrier concentration increases, there is a shift from impurity-band transport to conduction-band transport, and that the electron effective mass is lower in the impurity band than in the conduction band of Si. The shift to conduction-band transport improves electron mobility with carrier density by improving intragrain carrier mean free path lengths and relaxation times. © 2009 American Institute of Physics.published_or_final_versio