24 research outputs found
Recommended from our members
Asymmetric gold-catalyzed lactonizations in water at room temperature
No full textAsymmetric gold-catalyzed hydrocarboxylations are reported that show broad substrate scope. The hydrophobic effect associated with in situ-formed aqueous nanomicelles gives good to excellent ee's of product lactones. In-flask product isolation, along with the recycling of the catalyst and the reaction medium, are combined to arrive at an especially environmentally friendly process. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
Recommended from our members
Asymmetric gold-catalyzed lactonizations in water at room temperature
No full textAsymmetric gold-catalyzed hydrocarboxylations are reported that show broad substrate scope. The hydrophobic effect associated with in situ-formed aqueous nanomicelles gives good to excellent ee's of product lactones. In-flask product isolation, along with the recycling of the catalyst and the reaction medium, are combined to arrive at an especially environmentally friendly process. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
Paradigms and paradoxes: revisiting the relation of oxidation state and acidity of polyhydride cations
No full text
The immunodominant site of a synthetic immunogen has a conformational preference in water for a type-II reverse turn
No full text
Calculated bond dissociation energies and enthalpy of formation of α-amino acid radicals
No full text
