Influences of operational parameters on phosphorus removal in batch and continuous electrocoagulation process performance

© 2017, Springer-Verlag GmbH Germany. Performance of an electrocoagulation (EC) process in batch and continuous operating modes was thoroughly investigated and evaluated for enhancing wastewater phosphorus removal under various operating conditions, individually or combined with initial phosphorus concentration, wastewater conductivity, current density, and electrolysis times. The results revealed excellent phosphorus removal (72.7–100%) for both processes within 3–6 min of electrolysis, with relatively low energy requirements, i.e., less than 0.5 kWh/m3 for treated wastewater. However, the removal efficiency of phosphorus in the continuous EC operation mode was better than that in batch mode within the scope of the study. Additionally, the rate and efficiency of phosphorus removal strongly depended on operational parameters, including wastewater conductivity, initial phosphorus concentration, current density, and electrolysis time. Based on experimental data, statistical model verification of the response surface methodology (RSM) (multiple factor optimization) was also established to provide further insights and accurately describe the interactive relationship between the process variables, thus optimizing the EC process performance. The EC process using iron electrodes is promising for improving wastewater phosphorus removal efficiency, and RSM can be a sustainable tool for predicting the performance of the EC process and explaining the influence of the process variables

Performance and membrane fouling of two types of laboratory-scale submerged membrane bioreactors for hospital wastewater treatment at low flux condition

© 2016 Elsevier B.V. All rights reserved. The performance and membrane fouling of a lab-scale submerged sponge-membrane bioreactor (Sponge-MBR) and a conventional MBR were investigated and compared for hospital wastewater treatment at low fluxes of 2-6 LMH. COD removal by the Sponge-MBR was similar to that of the MBR, while the Sponge-MBR achieved 9-16% removed more total nitrogen than the MBR. This was due to 60% of total biomass being entrapped in the sponges, which enhanced simultaneous nitrification denitrification. Additionally, the fouling rates of the Sponge-MBR were 11-, 6.2- and 3.8-times less than those of the MBR at flux rates of 2, 4 and 6 LMH, respectively. It indicates the addition of sponge media into a MBR could effectively reduce the fouling caused by cake formation and absorption of soluble substances in a low flux scenario

Enhanced efficiency for better wastewater sludge hydrolysis conversion through ultrasonic hydrolytic pretreatment

© 2016 Taiwan Institute of Chemical Engineers The major requirements for accelerating the process of anaerobic digestion and energy production are breaking the structure of waste activated sludge (WAS), and transforming it into a soluble form suitable for biodegradation. This work investigated and analysed a novel bench-scale ultrasonic system for WAS disruption and hydrolysis using ultrasonic homogenization. Different commercial sonoreactors were used at low frequencies under a variety of operating conditions (intensity, density, power, sonication time, and total suspended solids) to evaluate the effects of the equipment on sludge hydrolysis and to generate new insights into the empirical models and mechanisms applicable to the real-world processing of wastewater sludge. A relationship was established between the operating parameters and the experimental data. Results indicated an increase in sonication time or ultrasonic intensity correlated with improved sludge hydrolysis rates, sludge temperature, and reduction rate of volatile solids (33.51%). It also emerged that ultrasonication could effectively accelerate WAS hydrolysis to achieve disintegration within 5–10 min, depending on the ultrasonic intensity. This study also determined multiple alternative parameters to increase the efficiency of sludge treatment and organic matter reduction, and establish the practicality of applying ultrasonics to wastewater sludge pretreatment

Bioprocessing for elimination antibiotics and hormones from swine wastewater

© 2017 Elsevier B.V. Antibiotics and hormones in swine wastewater have become a critical concern worldwide due to the severe threats to human health and the eco-environment. Removal of most detectable antibiotics and hormones, such as sulfonamides (SAs), SMs, tetracyclines (TCs), macrolides, and estrogenic hormones from swine wastewater utilizing various biological processes were summarized and compared. In biological processes, biosorption and biodegradation are the two major removal mechanisms for antibiotics and hormones. The residuals in treated effluents and sludge of conventional activated sludge and anaerobic digestion processes can still pose risks to the surrounding environment, and the anaerobic processes’ removal efficiencies were inferior to those of aerobic processes. In contrast, membrane bioreactors (MBRs), constructed wetlands (CWs) and modified processes performed better because of their higher biodegradation of toxicants. Process modification on activated sludge, anaerobic digestion and conventional MBRs could also enhance the performance (e.g. removing up to 98% SMs, 88.9% TCs, and 99.6% hormones from wastewater). The hybrid process combining MBRs with biological or physical technology also led to better removal efficiency. As such, modified conventional biological processes, advanced biological technologies and MBR hybrid systems are considered as a promising technology for removing toxicants from swine wastewater

Sustainable enzymatic technologies in waste animal fat and protein management.

Waste animal fats and proteins (WAFP) are rich in various animal by-products from food industries. On one hand, increasing production of huge amounts of WAFP brings a great challenge to their appropriate disposal, and raises severe risks to environment and life health. On the other hand, the high fat and protein contents in these animal wastes are valuable resources which can be reutilized in an eco-friendly and renewable way. Sustainable enzymatic technologies are promising methods for WAFP management. This review discussed the application of various enzymes in the conversion of WSFP to value-added biodiesel and bioactivate hydrolysates. New biotechnologies to discover novel enzymes with robust properties were proposed as well. This paper also presented the bio-utilization strategy of animal fat and protein wastes as alternative nutrient media for microorganism growth activities to yield important industrial enzymes cost-effectively

Wastewater treatment and biomass growth of eight plants for shallow bed wetland roofs

© 2017 Elsevier Ltd Wetland roof (WR) could bring many advantages for tropical cities such as thermal benefits, flood control, green coverage and domestic wastewater treatment. This study investigates wastewater treatment and biomass growth of eight local plants in shallow bed WRs. Results showed that removal rates of WRs were 21–28 kg COD ha−1 day−1, 9–13 kg TN ha−1 day−1 and 0.5–0.9 kg TP ha−1 day−1, respectively. The plants generated more biomass at lower hydraulic loading rate (HLR). Dry biomass growth was 0.4–28.1 g day−1 for average HLR of 247–403 m3 ha−1 day−1. Green leaf area of the plants was ranging as high as 67–99 m2 leaves per m2 of WR. In general, the descent order of Kyllinga brevifoliaRottb (WR8), Cyperus javanicus Houtt (WR5) and Imperata cylindrical (WR4) was suggested as effective vegetations in WR conditions in terms of wastewater treatment, dry biomass growth and green coverage ratio

Abrasion resistance and compressive strength of unprocessed rice husk ash concrete

This paper investigates the effects of adding natural rice husk ash collected from uncontrolled burning and without previous grinding (NRHA) as cement replacement in concrete. To obtain an adequate particle size, NRHA was mixed with coarse aggregate for a convenient period of time before adding the other components. Compressive strength, water absorption, porosity, and abrasion resistance expressed as weight loss were examined. Test results show that decreasing the particle size through mixing with coarse aggregate improved the compressive strength, reduced the permeability, and increased the abrasion resistance of concrete. By mixing NRHA with aggregate for 8 min, abrasion resistance improved by 10.35 and 23.62% over the control concrete at 28 and 91 days, respectively. Incorporating NRHA in concrete by grinding with coarse aggregate during the mixing process could be suitable for making normal-strength concrete and for applications where abrasion resistance is an important parameter. In addition, using NRHA as a partial replacement cement contributes to the reduction of CO2 emissions due to the production of cement

Immunomodulation of murine collagen-induced arthritis by N, N-dimethylglycine and a preparation of Perna canaliculus

<p>Abstract</p> <p>Background</p> <p>Rheumatoid arthritis (RA) and its accepted animal model, murine collagen-induced arthritis (CIA), are classic autoimmune inflammatory diseases which require proinflammatory cytokine production for pathogenesis. We and others have previously used N, N-dimethylglycine (DMG) and extracts from the New Zealand green-lipped mussel <it>Perna canaliculus </it>(Perna) as potent immunomodulators to modify ongoing immune and/or inflammatory responses.</p> <p>Methods</p> <p>In our initial studies, we treated lipopolysaccahride (LPS) stimulated THP-1 monocytes <it>in vitro </it>with increasing concentrations of Perna extract or DMG. Additionally, we treated rat peripheral blood neutrophils with increasing concentrations of Perna extract and measured superoxide burst. In subsequent <it>in vivo </it>experiments, CIA was induced by administration of type II collagen; rats were prophylactically treated with either Perna or DMG, and then followed for disease severity. Finally, to test whether Perna and/or DMG could block or inhibit an ongoing pathologic disease process, we induced CIA in mice and treated them therapeutically with either of the two immunomodulators.</p> <p>Results</p> <p>Following LPS stimulation of THP-1 monocytes, we observed dose-dependent reductions in TNF-α and IL-12p40 production in Perna treated cultures. DMG treatment, however, showed significant increases in both of these cytokines in the range of 0.001–1 μM. We also demonstrate that <it>in vitro </it>neutrophil superoxide burst activity is dose-dependently reduced in the presence of Perna. Significant reductions in disease incidence, onset, and severity of CIA in rats were noted following prophylactic treatment with either of the two immunomodulators. More importantly, amelioration of mouse CIA was observed following therapeutic administration of Perna. In contrast, DMG appeared to have little effect in mice and may act in a species-specific manner.</p> <p>Conclusion</p> <p>These data suggest that Perna, and perhaps DMG, may be useful supplements to the treatment of RA in humans.</p