Bridge Deck Runoff: Water Quality Analysis and BMP Effectiveness

INE/AUTC 10.0

Photochemical modeling of the Antarctic stratosphere: Observational constraints from the airborne Antarctic ozone experiment and implications for ozone behavior

The rapid decrease in O3 column densities observed during Antarctic spring has been attributed to several chemical mechanisms involving nitrogen, bromine, or chlorine species, to dynamical mechanisms, or to a combination of the above. Chlorine-related theories, in particular, predict greatly elevated concentrations of ClO and OClO and suppressed abundances of NO2 below 22 km. The heterogeneous reactions and phase transitions proposed by these theories could also impact the concentrations of HCl, ClNO3 and HNO3 in this region. Observations of the above species have been carried out from the ground by the National Ozone Expedition (NOZE-I, 1986, and NOZE-II, 1987), and from aircrafts by the Airborne Antarctic Ozone Experiment (AAOE) during the austral spring of 1987. Observations of aerosol concentrations, size distribution and backscattering ratio from AAOE, and of aerosol extinction coefficients from the SAM-II satellite can also be used to deduce the altitude and temporal behavior of surfaces which catalyze heterogeneous mechanisms. All these observations provide important constraints on the photochemical processes suggested for the spring Antarctic stratosphere. Results are presented for the concentrations and time development of key trace gases in the Antarctic stratosphere, utilizing the AER photochemical model. This model includes complete gas-phase photochemistry, as well as heterogeneous reactions. Heterogeneous chemistry is parameterized in terms of surface concentrations of aerosols, collision frequencies between gas molecules and aerosol surfaces, concentrations of HCl/H2O in the frozen particles, and probability of reaction per collision (gamma). Values of gamma are taken from the latest laboratory measurements. The heterogeneous chemistry and phase transitions are assumed to occur between 12 and 22 km. The behavior of trace species at higher altitudes is calculated by the AER 2-D model without heterogeneous chemistry. Calculations are performed for solar illumination conditions typical of 60, 70, and 80 S, from July 15 to October 31

Scalable secure multi-party network vulnerability analysis via symbolic optimization

Threat propagation analysis is a valuable tool in improving the cyber resilience of enterprise networks. As these networks are interconnected and threats can propagate not only within but also across networks, a holistic view of the entire network can reveal threat propagation trajectories unobservable from within a single enterprise. However, companies are reluctant to share internal vulnerability measurement data as it is highly sensitive and (if leaked) possibly damaging. Secure Multi-Party Computation (MPC) addresses this concern. MPC is a cryptographic technique that allows distrusting parties to compute analytics over their joint data while protecting its confidentiality. In this work we apply MPC to threat propagation analysis on large, federated networks. To address the prohibitively high performance cost of general-purpose MPC we develop two novel applications of optimizations that can be leveraged to execute many relevant graph algorithms under MPC more efficiently: (1) dividing the computation into separate stages such that the first stage is executed privately by each party without MPC and the second stage is an MPC computation dealing with a much smaller shared network, and (2) optimizing the second stage by treating the execution of the analysis algorithm as a symbolic expression that can be optimized to reduce the number of costly operations and subsequently executed under MPC.We evaluate the scalability of this technique by analyzing the potential for threat propagation on examples of network graphs and propose several directions along which this work can be expanded

From usability to secure computing and back again

Secure multi-party computation (MPC) allows multiple parties to jointly compute the output of a function while preserving the privacy of any individual party’s inputs to that function. As MPC protocols transition from research prototypes to realworld applications, the usability of MPC-enabled applications is increasingly critical to their successful deployment and widespread adoption. Our Web-MPC platform, designed with a focus on usability, has been deployed for privacy-preserving data aggregation initiatives with the City of Boston and the Greater Boston Chamber of Commerce. After building and deploying an initial version of the platform, we conducted a heuristic evaluation to identify usability improvements and implemented corresponding application enhancements. However, it is difficult to gauge the effectiveness of these changes within the context of real-world deployments using traditional web analytics tools without compromising the security guarantees of the platform. This work consists of two contributions that address this challenge: (1) the Web-MPC platform has been extended with the capability to collect web analytics using existing MPC protocols, and (2) as a test of this feature and a way to inform future work, this capability has been leveraged to conduct a usability study comparing the two versions ofWeb-MPC. While many efforts have focused on ways to enhance the usability of privacy-preserving technologies, this study serves as a model for using a privacy-preserving data-driven approach to evaluate and enhance the usability of privacy-preserving websites and applications deployed in realworld scenarios. Data collected in this study yields insights into the relationship between usability and security; these can help inform future implementations of MPC solutions.Published versio

Effects of engine emissions from high-speed civil transport aircraft: A two-dimensional modeling study, part 1

The AER two-dimensional chemistry-transport model is used to study the effect on stratospheric ozone (O3) from operations of supersonic and subsonic aircraft. The study is based on six emission scenarios provided to AER. The study showed that: (1) the O3 response is dominated by the portion of the emitted nitrogen compounds that is entrained in the stratosphere; (2) the entrainment is a sensitive function of the altitude at which the material is injected; (3) the O3 removal efficiency of the emitted material depends on the concentrations of trace gases in the background atmosphere; and (4) evaluation of the impact of fleet operations in the future atmosphere must take into account the expected changes in trace gas concentrations from other activities. Areas for model improvements in future studies are also discussed

Photochemistry of the Venus Atmosphere

Carbon monoxide, produced in the Venus atmosphere by photolysis of CO_2, is removed mainly by reaction with OH. The radical OH is formed in part by photolysis of H_2O_2, in part by reaction of O with HO_2. Photolysis of HCl provides a major source of H radicals near the visible clouds of Venus and plays a major role in the overall photochemistry. The mixing ratio of O_2 is estimated to be approximately 10^(−7), about a factor of 10 less than a recent observational upper limit reported by Traub and Carleton. A detailed model, which accounts for the photochemical stability of Venus CO_2, is presented and discussed

Antarctic ozone decrease: Possible impact on the seasonal and latitudinal distribution of total ozone as simulated by a 2-D model

Satellite borne instruments, the Total Ozone Mapping Spectrometer (TOMS) and the Solar Backscatter Ultraviolet spectrometer (SBUV), show that total column ozone has decreased by more than 5 percent in the neighborhood of 60 S at all seasons since 1979. This is considerably larger than the decrease calculated by 2-D models which take into account solar flux variation and increases of trace gas concentrations over the same period. The meteorological conditions (warmer temperature and the apparent lack of polar stratospheric clouds) at these latitudes do not seem to favor heterogeneous chemistry as the direct cause for the observed ozone reduction. A mechanism involving the seasonal transport of ozone-poor air mass from within the polar vortex to lower latitudes (the so-called dilution effect) is proposed as a possible explanation for the observed year-round ozone reduction in regions away from the vortex