Spin-polarized low-energy positron beams and their applications

The production and use of low-energy (100 eV to 5 keV) high-intensity, spin-polarized positron beams is reviewed. Methods for obtaining beams with high polarization are discussed. Applications include studies of the moderation process, surface and bulk magnetism, optically active molecules, and the production of polarized anti-protons.Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/47033/1/339_2004_Article_BF00635183.pd

Beta decay and the origin of biological chirality: New experimental results

The proposed connection between the parity-violating handedness of beta particles in radioactive decay and the sign (L) of biological chirality (the Vester-Ulbricht [V-U] hypothesis) is being investigated by measuring the theoretically predicted asymmetry in the formation of triplet positronium in amino acid enantiomers by low energy positrons under reversal of the helicity of the positrons. We find the asymmetry in leucine to be (0.8±1.0)×10 −4 , i.e. consistent with the theoretical, prediction of 10 −6 to 10 −7 . The apparatus is now sensitive enough to test the predicted asymmetry in optically active molecules which have heavy atoms at their chiral centers. The connection between these results and asymmetry in radiolysis by beta-decay electrons is made, and the implications of our limits for the V-U hypothesis discussed. Although the above limits are 10 6 times lower than direct measurements of radiolysis, they are still not small enough to allow us to rule out the V-U hypothesis.Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/43347/1/11084_2004_Article_BF00933685.pd

Vitrification of thin polymer films: From linear chain to soft colloid-like behavior

We show that the vitrification of star-shaped polystyrene (PS), of functionality f and molecular weight per arm Mwarm, thin films supported by silicon oxide, SiOx, is strongly dependent on Mwarm and f. When f is small, the vitrification behavior is similar to that of linear-chain PS where the average glass transition, Tg, decreases with decreasing film thickness (ΔTg < 0). However, for sufficiently large f and small Mwarm, Tg becomes independent of film thickness (ΔTg ≈ 0). In this region, where ΔTg ≈ 0, the star-shaped macromolecules self-assemble into ordered, periodic structures, similar to that of soft spheres or colloids, as revealed by simulations and experiments. This is identified as the soft-colloidal region. The transition from the linear-chain-like to the soft-colloidal-like region occurs over an intermediate range of functionalities and arm lengths; throughout this transition range ΔTg > 0. We show that the overall vitrification behavior of these thin film star-shaped polymers is due to competing entropic interactions associated with changes in f and Mwarm. The vitrification behavior of thin star-shaped PS films on SiOx is summarized in terms of a "diagram of states". © 2015 American Chemical Society

Pore sealing by NH3 plasma treatment of porous low dielectric constant films

10.1149/1.2435625Journal of the Electrochemical Society1544G85-G94JESO