9 research outputs found
The Potts Fully Frustrated model: Thermodynamics, percolation and dynamics in 2 dimensions
We consider a Potts model diluted by fully frustrated Ising spins. The model
corresponds to a fully frustrated Potts model with variables having an integer
absolute value and a sign. This model presents precursor phenomena of a glass
transition in the high-temperature region. We show that the onset of these
phenomena can be related to a thermodynamic transition. Furthermore this
transition can be mapped onto a percolation transition. We numerically study
the phase diagram in 2 dimensions (2D) for this model with frustration and {\em
without} disorder and we compare it to the phase diagram of the model with
frustration {\em and} disorder and of the ferromagnetic model.
Introducing a parameter that connects the three models, we generalize the exact
expression of the ferromagnetic Potts transition temperature in 2D to the other
cases. Finally, we estimate the dynamic critical exponents related to the Potts
order parameter and to the energy.Comment: 10 pages, 10 figures, new result
Nanocomposites of magnetic cobalt nanoparticles and cellulose
Polymeric matrices with stabilized metallic nanoparticles constitute an important class of
nanostructured materials, because polymer technology allows fabrication of components
with various electronic, magnetic and mechanical properties. The porous cellulose matrix has been shown to be a useful support material for platinum, palladium, silver, copper and nickel nanoparticles.
In the present study, nanosized cobalt particles with enhanced magnetic properties were made by chemical reduction within a microcrystalline cellulose (MCC) matrix. Two different chemical reducers, NaBH4 and NaH2PO2, were used, and the so-formed nanoparticles were characterized with X-ray absorption spectroscopy, X-ray diffraction, scanning electron microscopy and transmission electron microscopy. These experimental techniques were used to gain insight into the effect of different synthesis routes on structural properties of the nanoparticles. Magnetic properties of the nanoparticles were studied using a vibrating sample magnetometer. Particles made via the NaBH4 reduction were amorphous Co–B or Co oxide composites with diminished ferromagnetic behaviour and particles made via the NaH2PO2 reduction were well-ordered ferromagnetic hcp cobalt nanocrystals