20 research outputs found
Kinetics of deoxidation of liquid copper by graphite particles during submerged injection
Investigation of a Two-Stage Aqueous Reactor Design for Carbon Dioxide Sequestration using Steelmaking Slag
Hydrous carbonate sequestration of carbon dioxide using steelmaking slag was studied using a METSIM process model to analyze experimental data and estimate the reactor operating results. Several scenarios of a two-stage system with water/slag contact in reactor 1 and leachate/carbon dioxide contact in reactor 2 were investigated. These scenarios included batch vs continuous processing and fresh water input vs water recirculation. The METSIM leaching and carbonation models were verified with results obtained from previous slag sequestration experiments. Fresh water additions to reactor 1 allowed the highest leaching efficiency and resulted in excellent carbonation in reactor 2, but a continuous system has a high water demand. Recirculation of the spent leachate minimizes the fresh water addition required, but inhibits the leaching process by producing a calcium carbonate product layer on the slag particles in reactor 1. Increasing the slag surface area, slag/solution ratio, or reactor residence time partially overcomes product layer blinding. Optimal residence times were defined for different process parameters and slag particle sizes
Investigation of a Two-Stage Aqueous Reactor Design for Carbon Dioxide Sequestration Using Steelmaking Slag
Freeze-Lining Formation of a Synthetic Lead Slag: Part I. Microstructure Formation
Recently, freeze linings have been selected more frequently to protect pyrometallurgical reactor walls, due to a number of advantages over conventional refractory lining such as a self-regenerating capability and the possibility of operating under high-intensity process conditions. A freeze lining is formed on a cooled reactor wall in a time-dependent temperature gradient. To model freeze-lining behavior, input data on several assumptions, such as the phase formation and the temperature at the bath-freeze-lining interface during freeze-lining formation, are needed. In order to provide experimental data, the freeze-lining formation of a synthetic lead slag system (PbO-FeO-Fe2O3-ZnO-CaO-SiO2) is investigated. A lab-scale freeze lining was produced by submerging an air-cooled probe into a liquid slag bath for 120 minutes. The temperature evolution during freeze-lining formation was estimated using the experimentally determined position and composition of the phases, the phase-temperature relations predicted with the thermodynamic computer package FactSage, and the results of reference experiments. For the studied slag system, it is concluded that heat transfer is much faster than mass transfer and crystallization. As a result, the liquid in front of the freeze lining undercools. The degree of undercooling depends on the solidification rate. It is concluded that the temperature at the bath-freeze-lining interface varies between the glass transition and liquidus temperatures of the slag bath during freeze-lining formation
Investigation of freeze linings in copper-containing slag systems: Part II. Mechanism of the deposit stabilization
A major industrial problem in high-temperature liquid reaction systems is the attack of furnace components by chemically aggressive molten reactants. Freeze-lining technologies involving the deliberate formation of controlled frozen deposits are increasingly being applied to extend the range of liquid bath compositions and process temperatures that can be used; this has resulted in significant increases in process performance and productivity. It has been widely assumed that the interface between the stationary frozen layer and the agitated molten bath at steady state consists of the primary phase, which stays in contact with the bulk liquid at the liquidus temperature, T . It has been shown in the current laboratory-based studies through the use of a cold finger technique that, at steady state and in selected ranges of process conditions and bath compositions, the phase assemblage present at the deposit/liquid interface is not that of the primary phase alone. The microstructural observations clearly demonstrate that the temperature of the deposit/liquid bath interface, T , can be lower than the liquidus temperature of the bulk liquid, T . These observations point to a significant change in the mechanism and behavior of the systems. To explain this phenomenon, it is proposed that the steady-state thickness of freeze linings is not the result of equilibrium freezing but rather represents a state of dynamic equilibrium that is critically dependent on the relative rates of crystallization, mass, and heat transfer processes, occurring close to and at the deposit interface. The mechanisms taking place in the boundary liquid layer involve both partial crystallization/remelting and continuous removal of solids. This finding has important implications for the design of the high-temperature industrial reactors and selection of ranges of melt chemistries and conditions that can be used. This finding means that temperatures below the liquidus can be selected for some processes, resulting potentially in significant savings of energy and increases in throughput of pyrometallurgical reactors. The findings are generic and are not limited to the specific chemical systems reported in the article