Point-contact spectroscopy of the borocarbide superconductor YNi2B2C

Point-contact (PC) spectroscopy measurements on YNi2B2C single crystals in the normal and superconducting (SC) state (T_c=15.4K) for the main crystallographic directions are reported. The PC study reveals the electron-phonon interaction (EPI) function with a dominant maximum around 12meV and a further weak structure (kink or shallow broad maximum) at higher energy at about 50meV. Other phonon maxima at 20, 24 and 32meV specified in the phonon DOS of YNi2B2C by neutron measurements [PRB, V.55, 9058 (1997)] are not resolved in the PC spectra pointing out to the main role of the low energy phonon modes in EPI. Directional study of the SC gap results in \Delta_[100]=1.5meV for the a- direction and \Delta_[001]=2.4meV along the c-axis which may point to anisotropic and/or multiband behavior. Noteworthy, the critical temperature T_c in all cases corresponds to that of bulk samples. The value 2\Delta_[001]/kT_c=3.6 is close to the BCS one of 3.52, and the temperature dependence \Delta(T) is BCS-like, while for the a-direction \Delta(T) deviates from mean-field BCS behavior above T_c/2. The directional variation in \Delta can be attributed to the multiband nature of the SC state in YNi2B2C predicted 10 years ago (PRL, V.80, 1730 (1998)).Comment: 3 figs, 2 pages, presented on M2S-HTSC Conference, July 9-14, 2006, Dresde

Point-contact investigations of challenging superconductors: two-band MgB2, antiferromagnetic HoNi2B2C, heavy fermion UPd2Al3, paramagnetic MgCNi3

An overview on recent efforts in point-contact (PC) spectroscopy of title superconductors is given. Distinct phonon features and crystalline-electric-field effects are observed in PC spectra of HoNi2B2C. Results of study of superconducting (SC) gap and excess current versus temperature and magnetic field reflecting specific multi-band electronic structure in MgB2 are presented. The nature of the extremely nonlinear I(V) curves in the antiferromagnetic (AF) and SC state are elucidated for UPd2Al3 break-junctions and MgCNi3 point contacts.Comment: 2 pages, 4 figs., presented on SCES`04 (26-30 July, Karlsruhe, Germany), accepted for publicatio

Point-contact spectroscopy of the nickel borocarbide superconductor YNi2B2C in the normal and superconducting state

Point-contact (PC) spectroscopy measurements of YNi2B2C single crystals in the normal and superconducting (SC) state (T_c=15.4K) for the main crystallographic directions are reported. The PC study reveals the electron-phonon interaction (EPI) spectral function with dominant phonon maximum around 12 meV and further weak structures (hump or kink) at higher energy at about 50 meV. No "soft" modes below 12 meV are resolved in the normal state. The PC EPI spectra are qualitatively similar for the different directions. Contrary, directional study of the SC gap results in \Delta_[100]=1.5 meV for the a direction and \Delta_[001]=2.3 meV along the c axis; however the critical temperature T_c in PC in all cases is near to that in the bulk sample. The value 2\Delta_[001]/kT_c=3.6 is close to the BCS value of 3.52, and the temperature dependence \Delta_[001](T) is BCS-like, while the for small gap \Delta_[100](T) is below BCS behavior at T>T_c/2 similarly as in the two-gap superconductor MgB2. It is supposed that the directional variation \Delta can be attributed to a multiband nature of the SC state in YNi2B2C.Comment: 9 pages, 10 figures, to be published in a special issue of J. Low Temp. Phys. in honour of Prof. H. von Loehneyse

Suppression of ferromagnetism in CeSi_1.81 under temperature and pressure

We have studied the pressure dependence of the magnetization of single crystalline CeSi_1.81. At ambient pressure ferromagnetism develops below T_C = 9.5 Below ~ 5 K an additional shoulder in low-field hysteresis loops and a metamagnetic crossover around 4 T suggest the appearance of an additional magnetic modulation to the ferromagnetic state. The suppression of the magnetic order in CeSi_1.81 as function of temperature at ambient pressure and as function of pressure at low temperature are in remarkable qualitative agreement. The continuous suppression of the ordered moment at p ~ 13.1 kbar suggests the existence of a ferromagnetic quantum critical point in this material.Comment: 9 pages, 9 figures, to be published in Physical Review

Born Effective Charges and Infrared Response of LiBC

Calculations of the zone center optical mode frequencies (including LO-TO splitting), Born effective charges Z$^*_{\alpha\alpha}$ for each atom, dielectric constants $\epsilon_{0}$ and $\epsilon_{\infty}$, and the dielectric response in the infrared, using density functional linear response theory, are reported. Calculated Raman modes are in excellent agreement with experimental values (170 cm$^{-1}$ and 1170 cm$^{-1}$), while it will require better experimental data to clarify the infrared active mode frequencies. The Born effective charges Z$^*_{\alpha \alpha}$ (i) have surprisingly different values for B and C, and (ii) show considerable anisotropy. Relationships between the effective charges and LO-TO splitting are discussed, and the predicted reflectivity in the range 0 -- 1400 cm$^{-1}$ is presented. These results hold possible implications for Li removal in LiBC, and C substition for B in MgB$_2$.Comment: 6 pages, 3 figure

Electronic and Structural Properties of a 4d-Perovskite: Cubic Phase of SrZrO3_3

First-principles density functional calculations are performed within the local density approximation to study the electronic properties of SrZrO$_3$, an insulating 4d-perovskite, in its high-temperature cubic phase, above 1400 K, as well as the generic 3d-perovskite SrTiO$_3$, which is also a d^0-insulator and cubic above 105 K, for comparison reasons. The energy bands, density of states and charge density distributions are obtained and a detailed comparison between their band structures is presented. The results are discussed also in terms of the existing data in the literature for both oxides.Comment: 5 pages, 2 figure

Point-contact spectroscopy of the antiferromagnetic superconductor HoNi2B2C in the normal and superconducting state

Point-contact (PC) spectroscopy measurements on antiferromagnetic (AF) (T_N=5.2K) HoNi2B2C single crystals in the normal and two different superconducting (SC) states (T_c=8.5K and $T_c^*=5.6K) are reported. The PC study of the electron-boson(phonon) interaction (EB(P)I) spectral function reveals pronounced phonon maxima at 16, 22 and 34meV. For the first time the high energy maxima at about 50meV and 100meV are resolved. Additionally, an admixture of a crystalline-electric-field (CEF) excitations with a maximum near 10meV and a `magnetic` peak near 3meV are observed. The contribution of the 10-meV peak in PC EPI constant \lambda_PC is evaluated as 20-30contribution of the high energy modes at 50 and 100meV amounts about 10each maxima, so the superconductivity might be affected by CEF excitations. The SC gap in HoNi2B2C exhibits a standard single-band BCS-like dependence, but vanishes at$T_c^*=5.6K<T_c, with 2\Delta/kT_c^*=3.9. The strong coupling Eliashberg analysis of the low-temperature SC phase with T_c^*=5.6K =T_N, coexisting with the commensurate AF structure, suggests a sizable value of the EPI constant \lambda_s=0.93. We also provide strong support for the recently proposed by us ''Fermi surface (FS) separation'' scenario for the coexistence of magnetism and superconductivity in magnetic borocarbides, namely, that the superconductivity in the commensurate AF phase survives at a special (nearly isotropic) FS sheet without an admixture of Ho 5d states. Above T_c^* the SC features in the PC characteristics are strongly suppressed pointing to a specific weakened SC state between T_c* and T_c.Comment: 11 pages, 8 figs, to be published in PRB, Vol.75, Iss.2