Defect tolerance in as-deposited selenium-alloyed cadmium telluride solar cells

The efficiency of cadmium telluride (CdTe) solar cells is limited primarily by voltage, which is known to depend on the carrier concentration and carrier lifetimes within the absorber layer of the cell. Here, cathodoluminescence measurements are made on an as-deposited CdSeTe/CdTe solar cell that show that selenium alloyed CdTe material luminesces much more strongly than non-alloyed CdTe. This reduction in non-radiative recombination in the CdSeTe suggests that the selenium gives it a certain defect tolerance. This has implications for carrier lifetimes and voltages in cadmium telluride solar cells

Effects of oxygen-related damage on dwell-fatigue crack propagation in a P/M Ni-based superalloy : from 2D to 3D assessment

Effects of oxygen-related damage (i.e. oxidation and dynamic embrittlement) on fatigue crack propagation behavior in an advanced disc alloy have been assessed in air and vacuum under dwell-fatigue conditions at 725 oC. The enhanced fatigue crack propagation is closely related to oxygen-related damage at/ahead of the crack tip, which is determined by the testing environment, the dwell period and the crack propagation rate itself based on two dimensional (2D) observation of the crack tip in an optical microscope and scanning electron microscope. X-ray computed tomography has also been employed to examine the differences between three dimension (3D) crack morphology in air and vacuum conditions, and the crack features have been quantified in terms of crack opening displacements, secondary cracks and uncracked bridging ligaments. The results show that the fatigue crack propagation rate is related to the amount of secondary cracks, and the crack length increment in a loading cycle is related to the breaking/cracking of the uncracked bridging ligaments within the discontinuous cracking zone ahead of the crack tip as oxygen-related damage preferentially occurs in these highly deformed regions. By combination of 3D X-ray computed tomography and traditional 2D observation, a deeper understanding is provided of the mechanisms of oxygen-enhanced fatigue crack propagation behavior

Role of oxygen in enhanced fatigue cracking in a PM Ni-based superalloy : stress assisted grain boundary oxidation or dynamic embrittlment?

The role of oxygen in enhanced fatigue cracking in an advanced Ni-based superalloy for turbine disc application has been evaluated in fatigue crack initiation and propagation stages along with static oxidation tests. It is found that the grain boundary oxide intrusion has a layered structure. The microstructure- and deformation-dependent grain boundary oxidation dominates the fatigue crack initiation and early propagation processes. As the crack propagates, this contribution arising from oxidation damage may gradually be overtaken by dynamic embrittlement processes until the mechanical damage outstrips the oxygen-related damage, resulting in a transition from intergranular to transgranular crack propagation

Low cycle fatigue of a directionally solidified nickel-based superalloy: Testing, characterisation and modelling

Low cycle fatigue (LCF) of a low-carbon (LC) directionally-solidified (DS) nickel-base superalloy, CM247 LC DS, was investigated using both experimental and computational methods. Strain-controlled LCF tests were conducted at 850°C, with a loading direction either parallel or perpendicular to the solidification direction. Trapezoidal loading-waveforms with 2 s and 200 s dwell times imposed at the minimum and the maximum strains were adopted for the testing. A constant strain range of 2% was maintained throughout the fully-reversed loading conditions (strain ratio R = −1). The observed fatigue life was shorter when the loading direction was perpendicular to the solidification one, indicating an anisotropic material response. It was found that the stress amplitude remained almost constant until final fracture, suggesting limited cyclic hardening/softening. Also, stress relaxation was clearly observed during the dwell period. Scanning Electron Microscopy fractographic analyses showed evidence of similar failure modes in all the specimens. To understand deformation at grain level, crystal plasticity finite element modelling was carried out based on grain textures measured with EBSD. The model simulated the full history of cyclic stress-strain responses. It was particularly revealed that the misorientations between columnar grains resulted in heterogeneous deformation and localised stress concentrations, which became more severe when the loading direction was normal to a solidification direction, explaining the shorter fatigue life observed

Effects of oxygen-related damage on dwell-fatigue crack propagation in a P/M Ni-based superalloy: From 2D to 3D assessment

Effects of oxygen-related damage (i.e. oxidation and dynamic embrittlement) on fatigue crack propagation behavior in an advanced disc alloy have been assessed in air and vacuum under dwell-fatigue conditions at 725 °C. The enhanced fatigue crack propagation is closely related to oxygen-related damage at/ahead of the crack tip, which is determined by the testing environment, the dwell period and the crack propagation rate itself based on two dimensional (2D) observation of the crack tip in an optical microscope and scanning electron microscope. X-ray computed tomography has also been employed to examine the differences between three dimension (3D) crack morphology in air and vacuum conditions, and the crack features have been quantified in terms of crack opening displacements, secondary cracks and uncracked bridging ligaments. The results show that the fatigue crack propagation rate is related to the amount of secondary cracks, and the crack length increment in a loading cycle is related to the breaking/cracking of the uncracked bridging ligaments within the discontinuous cracking zone ahead of the crack tip as oxygen-related damage preferentially occurs in these highly deformed regions. By combination of 3D X-ray computed tomography and traditional 2D observation, a deeper understanding is provided of the mechanisms of oxygen-enhanced fatigue crack propagation behavior

Effects of oxygen-related damage on dwell-fatigue crack propagation in a P/M Ni-based superalloy: from 2D to 3D assessment

This dataset includes the data presented in the journal paper, Effects of oxygen-related damage on dwell-fatigue crack propagation in a P/M Ni-based superalloy: From 2D to 3D assessment published in the International Journal of Fatigue, Volume 99, Part 1, June 2017, Pages 175&ndash;186, http://dx.doi.org/10.1016/j.ijfatigue.2017.03.003 </span

Realistic microstructure-based modelling of cyclic deformation and crack growth using crystal plasticity

Using crystal plasticity, finite element analyses were carried out to model cyclic deformation for a low solvus high refractory (LSHR) nickel superalloy at elevated temperature. The analyses were implemented using a representative volume element (RVE), consisting of realistic microstructure obtained from SEM images of the material. Monotonic, stress-relaxation and cyclic test data at 725 °C were used to determine the model parameters from a fitting process and their sensitivity to RVE size and random grain orientation. In combination with extended finite element method (XFEM), the crystal plasticity model was further applied to predict surface crack growth, for which accumulated plastic strain was used as a fracture criterion. Again, realistic microstructure, taken from the cracking site on the surface of a plain fatigue specimen, was used to create the finite element model for crack growth analyses. The prediction was conducted for a pseudo-3D geometrical model, resembling the plane stress condition at specimen surface. The loading level at the cracking site was determined from a viscoplasticity finite element analysis of the fatigue specimen. The proposed model is capable of predicting the variation in growth rate in grains with different orientation