Non-additivity of pair interactions in charged colloids

It is general wisdom that the pair potential of charged colloids in a liquid may be closely approximated by a Yukawa interaction, as predicted by the classical Derjaguin-Landau-Verwey-Overbeek (DLVO) theory. We experimentally determine the effective forces in a binary mixture of like-charged particles, of species 1 and 2, with blinking optical tweezers. The measured forces are consistent with a Yukawa pair potential but the (12) cross-interaction is not equal to the geometric mean of the (11) and (22) like-interactions, as expected from DLVO. The deviation is a function of the electrostatic screening length and the size ratio, with the cross-interaction measured being consistently weaker than DLVO predictions. The corresponding non-additivity parameter is negative and grows in magnitude with increased size asymmetry.Comment: Final versio

Development and validation of detailed building, plant and controller modelling to demonstrate interactive behaviour of system components

As plant modelling becomes capable of more complexity and detailed resolution, new opportunities arise for the virtual evaluation of discrete plant components such as flow control and energy conversion devices, and controllers. Such objects are conventionally developed and tested at the prototype stage in a laboratory environment. Designers now seek to use modelling technology to extend their understanding from limited laboratory test results to full building and plant system analysis. This paper describes the development of a modelling system, using ESP-r, for typical United Kingdom domestic house types with hydronic gas or oil fired central heating including radiator and underfloor heating systems, and with a variety of conventional or advanced control types. It demonstrates the ability of detailed building and plant modelling to reveal unexpected insights into how real control systems perform in combination with other plant items and in different building types, including estimation of their influence on annual energy consumption. Comparisons with measurements taken in test rooms confirm that the observed behaviour of controls is realised in practice. The authors conclude that the complex dynamic interactions that take place between the various elements that make up a real building energy system have an important influence on its overall energy performance, revealing causes of variance that cannot be identified by laboratory testing alone, or by simplistic energy assessment tools

Capacity building for improved performance of water and sanitation NGOS/CBOS in Uganda

This paper highlights the 5 year capacity building programme for more than 94 NGOs/CBOs in the Ugandan water and sanitation sector. Capacity building activity implementation aimed at developing an effective civil society which can complement and inform government towards achievement of sustainable access to water & sanitation takes place at regional level, and is being co-coordinated by 8 regional coordinator in 8 different parts of the country. The 1st year implementation built capacity of NGOs/CBOs in areas of practical skills, report writing and records management using training methods such as workshops, apprenticeship, coaching and internship. By the end of the 1st implementation year, there was visible improvement of co-ordination, knowledge and experience sharing among beneficiary NGOs/CBOs. All of them streamlined their legal status, and service provision/operational focus as well

Processing circuitry for single channel radiation detector

Processing circuitry is provided for a high voltage operated radiation detector. An event detector utilizes a comparator configured to produce an event signal based on a leading edge threshold value. A preferred event detector does not produce another event signal until a trailing edge threshold value is satisfied. The event signal can be utilized for counting the number of particle hits and also for controlling data collection operation for a peak detect circuit and timer. The leading edge threshold value is programmable such that it can be reprogrammed by a remote computer. A digital high voltage control is preferably operable to monitor and adjust high voltage for the detector

Distance dependence of excitation energy transfer between spacer-separated conjugated polymer films

We report a systematic study of the scaling with distance of electronic energy transfer between thin films of conjugated polymers separated by a silica spacer. The energy-transfer kinetics were obtained directly from time-resolved photoluminescence measurements and show a 1/ z3 distance dependence of the transfer rate between the excited donor and the acceptor film for z≥8 nm. This is consistent with Förster theory; but at shorter separations the energy transfer is slower than predicted and can be explained by the breakdown of the point-dipole approximation at z∼5 nm. The results are relevant for organic photovoltaics and light-emitting devices, where energy transfer can provide a means of increasing performance

Oxygen Compatibility of Brass-Filled PTFE Compared to Commonly Used Fluorinated Polymers for Oxygen Systems

Safe and reliable seal materials for high-pressure oxygen systems sometimes appear to be extinct species when sought out by oxygen systems designers. Materials that seal well are easy to find, but these materials are typically incompatible with oxygen, especially in cryogenic liquid form. This incompatibility can result in seals that leak, or much worse, seals that easily ignite and burn during use. Materials that are compatible with oxygen are easy to find, such as the long list of compatible metals, but these metallic materials are limiting as seal materials. A material that seals well and is oxygen compatible has been the big game in the designer's safari. Scientists at the Materials Combustion Research Facility (MCRF), part of NASA/Marshall Space Flight Center (MSFC), are constantly searching for better materials and processes to improve the safety of oxygen systems. One focus of this effort is improving the characteristics of polymers used in the presence of an oxygen enriched environment. Very few systems can be built which contain no polymeric materials; therefore, materials which have good impact resistance, low heat of combustion, high auto-ignition temperature and that maintain good mechanical properties are essential. The scientists and engineers at the Materials Combustion Research Facility, in cooperation with seal suppliers, are currently testing a new formulation of polytetrafluoroethylene (PTFE) with Brass filler. This Brass-filled PTFE is showing great promise as a seal and seat material for high pressure oxygen systems. Early research has demonstrated very encouraging results, which could rank this material as one of the best fluorinated polymers ever tested. This paper will compare the data obtained for Brass-filled PTFE with other fluorinated polymers, such as TFE-Teflon (PTFE) , Kel-F 81, Viton A, Viton A-500, Fluorel , and Algoflon . A similar metal filled fluorinated polymer, Salox-M , was tested in comparison to Brass-filled PTFE to demonstrate the importance of the metal chosen and relative percentage of filler. General conclusions on the oxygen compatibility of this formulation are drawn, with an emphasis on comparing and contrasting the materials performance to the performance of the current state-of-the-art oxygen compatible polymers

An Exact Test of Fit for the Gaussian Linear Model using Optimal Nonbipartite Matching

Fisher tested the fit of Gaussian linear models using replicated observations. We refine this method by (1) constructing near-replicates using an optimal nonbipartite matching and (2) defining a distance that focuses on predictors important to the model’s predictions. Near-replicates may not exist unless the predictor set is low-dimensional; the test addresses dimensionality by betting that model failures involve a subset of predictors important in the old fit. Despite using the old fit to pair observations, the test has exactly its stated level under the null hypothesis. Simulations show the test has reasonable power even when many spurious predictors are present