484 research outputs found
ARPES and NMTO Wannier Orbital Theory of LiMoO - Implications for Unusually Robust Quasi-One Dimensional Behavior
We present the results of a combined study by band theory and angle resolved
photoemission spectroscopy (ARPES) of the purple bronze,
LiMoO. Structural and electronic origins of its unusually
robust quasi-one dimensional (quasi-1D) behavior are investigated in detail.
The band structure, in a large energy window around the Fermi energy, is
basically 2D and formed by three Mo -like extended Wannier orbitals,
each one giving rise to a 1D band running at a 120 angle to the two
others. A structural "dimerization" from to gaps
the and bands while leaving the bands metallic in the gap, but
resonantly coupled to the gap edges and, hence, to the other directions. The
resulting complex shape of the quasi-1D Fermi surface (FS), verified by our
ARPES, thus depends strongly on the Fermi energy position in the gap, implying
a great sensitivity to Li stoichiometry of properties dependent on the FS, such
as FS nesting or superconductivity. The strong resonances prevent either a
two-band tight-binding model or a related real-space ladder picture from giving
a valid description of the low-energy electronic structure. We use our extended
knowledge of the electronic structure to newly advocate for framing
LiMoO as a weak-coupling material and in that framework can
rationalize both the robustness of its quasi-1D behavior and the rather large
value of its Luttinger liquid (LL) exponent . Down to a temperature of
6K we find no evidence for a theoretically expected downward
renormalization of perpendicular single particle hopping due to LL fluctuations
in the quasi-1D chains.Comment: 53 pages, 17 Figures, 6 year
Coexistence of Bloch electrons and glassy electrons in Ca10(Ir4As8)(Fe2_xIrxAs2)5 revealed by angle-resolved photoemission spectroscopy
Angle-resolved photoemission spectroscopy of Ca10(Ir4As8)(Fe2_xIrxAs2)5 shows
that the Fe 3d electrons in the FeAs layer form the hole-like Fermi pocket at
the zone center and the electron-like Fermi pockets at the zone corners as
commonly seen in various Fe-based superconductors. The FeAs layer is heavily
electron doped and has relatively good two dimensionality. On the other hand,
the Ir 5d electrons are metallic and glassy probably due to atomic disorder
related to the Ir 5d orbital instability. Ca10(Ir4As8)(Fe2_xIrxAs2)5 exhibits a
unique electronic state where the Bloch electrons in the FeAs layer coexist
with the glassy electrons in the Ir4As8 layer.Comment: 4 pages, 3 figure
Orbital Degeneracy and Peierls Instability in Triangular Lattice Superconductor IrPtTe
We have studied electronic structure of triangular lattice
IrPtTe superconductor using photoemission spectroscopy and
model calculations. Ir core-level photoemission spectra show that Ir
charge modulation established in the low temperature phase of IrTe
is suppressed by Pt doping. This observation indicates that the suppression of
charge modulation is related to the emergence of superconductivity.
Valence-band photoemission spectra of IrTe suggest that the Ir charge
modulation is accompanied by Ir orbital reconstruction. Based on the
photoemission results and model calculations, we argue that the
orbitally-induced Peierls effect governs the charge and orbital instability in
the IrPtTe.Comment: 5 pages,4 figure
Electronic structure reconstruction by orbital symmetry breaking in IrTe2
We report an angle-resolved photoemission spectroscopy (ARPES) study on IrTe2
which exhibits an interesting lattice distortion below 270 K and becomes
triangular lattice superconductors by suppressing the distortion via chemical
substitution or intercalation. ARPES results at 300 K show multi-band Fermi
surfaces with six-fold symmetry which are basically consistent with band
structure calculations. At 20 K in the distorted phase, whereas the flower
shape of the outermost Fermi surface does not change from that at 300 K,
topology of the inner Fermi surfaces is strongly modified by the lattice
distortion. The Fermi surface reconstruction by the distortion depends on the
orbital character of the Fermi surfaces, suggesting importance of Ir 5d and/or
Te 5p orbital symmetry breaking.Comment: 4pages, 4figure
Evidence for the Coexistence of Anisotropic Superconducting Gap and Nonlocal Effects in the Non-magnetic Superconductor LuNi2B2C
A study of the dependence of the heat capacity Cp(alpha) on field angle in
LuNi2B2C reveals an anomalous disorder effect. For pure samples, Cp(alpha)
exhibits a fourfold variation as the field H < Hc2 is rotated in the [001]
plane, with minima along (alpha = 0). A slightly disordered sample,
however, develops anomalous secondary minima along for H > 1 T, leading
to an 8-fold pattern. The anomalous pattern is discussed in terms of coexisting
superconducting gap anisotropy and non-local effects.Comment: 5 pages, 4 figure
Heat Conduction in the Vortex State of NbSe_2: Evidence for Multi-Band Superconductivity
The thermal conductivity kappa of the layered s-wave superconductor NbSe_2
was measured down to T_c/100 throughout the vortex state. With increasing
field, we identify two regimes: one with localized states at fields very near
H_c1 and one with highly delocalized quasiparticle excitations at higher
fields. The two associated length scales are naturally explained as multi-band
superconductivity, with distinct small and large superconducting gaps on
different sheets of the Fermi surface. This behavior is compared to that of the
multi-band superconductor MgB_2 and the conventional superconductor V_3Si.Comment: 5 pages, 4 figure
Effect of Pt substitution on the electronic structure of AuTe2
We report a photoemission and x-ray absorption study on Au1-xPtxTe2 (x = 0
and 0.35) triangular lattice in which superconductivity is induced by Pt
substitution for Au. Au 4f and Te 3d core-level spectra of AuTe2 suggests a
valence state of Au2+(Te2)2-, which is consistent with its distorted crystal
structure with Te-Te dimers and compressed AuTe6 otahedra. On the other hand,
valence-band photoemission spectra and pre-edge peaks of Te 3d absorption edge
indicate that Au 5d bands are almost fully occupied and that Te 5p holes govern
the transport properties and the lattice distortion. The two apparently
conflicting pictures can be reconciled by strong Au 5d/Au 6s-Te 5p
hybridization. Absence of a core-level energy shift with Pt substitution is
inconsistent with the simple rigid band picture for hole doping. The Au 4f
core-level spectrum gets slightly narrow with Pt substitution, indicating that
the small Au 5d charge modulation in distorted AuTe2 is partially suppressed.Comment: 13 pages, 4 figures, accepted by Physical Review
Te 5p orbitals bring three-dimensional electronic structure to two-dimensional Ir0.95Pt0.05Te2
We have studied the nature of the three-dimensional multi-band electronic
structure in the twodimensional triangular lattice Ir1-xPtxTe2 (x=0.05)
superconductor using angle-resolved photoemission spectroscopy (ARPES), x-ray
photoemission spectroscopy (XPS) and band structure calculation. ARPES results
clearly show a cylindrical (almost two-dimensional) Fermi surface around the
zone center. Near the zone boundary, the cylindrical Fermi surface is truncated
into several pieces in a complicated manner with strong three-dimensionality.
The XPS result and the band structure calculation indicate that the strong Te
5p-Te 5p hybridization between the IrTe2 triangular lattice layers is
responsible for the three-dimensionality of the Fermi surfaces and the
intervening of the Fermi surfaces observed by ARPES.Comment: 5 pages, 4 figure
Antiferromagnetic Order Induced by an Applied Magnetic Field in a High-Temperature Superconductor
One view of the cuprate high-transition temperature (high-Tc) superconductors
is that they are conventional superconductors where the pairing occurs between
weakly interacting quasiparticles, which stand in one-to-one correspondence
with the electrons in ordinary metals - although the theory has to be pushed to
its limit. An alternative view is that the electrons organize into collective
textures (e.g. charge and spin stripes) which cannot be mapped onto the
electrons in ordinary metals. The phase diagram, a complex function of various
parameters (temperature, doping and magnetic field), should then be approached
using quantum field theories of objects such as textures and strings, rather
than point-like electrons. In an external magnetic field, magnetic flux
penetrates type-II superconductors via vortices, each carrying one flux
quantum. The vortices form lattices of resistive material embedded in the
non-resistive superconductor and can reveal the nature of the ground state -
e.g. a conventional metal or an ordered, striped phase - which would have
appeared had superconductivity not intervened. Knowledge of this ground state
clearly provides the most appropriate starting point for a pairing theory. Here
we report that for one high-Tc superconductor, the applied field which imposes
the vortex lattice, also induces antiferromagnetic order. Ordinary
quasiparticle pictures cannot account for the nearly field-independent
antiferromagnetic transition temperature revealed by our measurements
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