Infrared Studies of the Symmetry Changes of the ²⁸SiH₄ Molecule in Low-Temperature Matrixes. Fundamental, Combination, and Overtone Transitions

Infrared spectra of ²⁸SiH₄ in argon and nitrogen matrixes at low temperature 6.5–20 K in the region of overtone and combination transitions were recorded for the first time. Additionally, the high-resolution spectra were obtained in the fundamental region. The frequencies and the relative intensities of all bands were determined. The set of experimental data suggests that the symmetry of molecules studied in the matrixes is different from the symmetry of the free molecules because of an interaction with the environment. The symmetry of ²⁸SiH₄ changes from <i>T</i>_<i>d</i> to <i>C</i>_3<i>v</i> on transition from the gas phase to a nitrogen matrix and to <i>D</i>_2<i>d</i> on transition to an argon matrix. A modeling of SiH₄ molecule force fields explains the experimental data as a change of a force constant of the selected SiH bond in the case of SiH₄ in the nitrogen matrix or force constants of two opposite angles in the case of SiH₄ in the argon matrix. In spite of small values of these changes, they result in noticeable spectroscopic effects: the band splitting and appearance of new bands in matrix spectra compared with spectra of free SiH₄. The interpretation of transitions in the fundamental and combination regions was performed

Integral Intensities of Absorption Bands of Silicon Tetrafluoride in the Gas Phase and Cryogenic Solutions: Experiment and Calculation

The spectral characteristics of the SiF4 molecule in the range 3100700 cm1, including the absorption range of the band 3, are studied in the gas phase at P = 0.47 bar and in solutions in liquefied Ar and Kr. In the cryogenic solutions, the relative intensities of the vibrational bands, including the bands of the isotopically substituted molecules, are determined. The absorption coefficients of the combination bands 23, 3 + 1, 3 + 4, and 34 are measured in the solution in Kr. In the gas phase of the one-component system at an elevated pressure of SiF4, the integrated absorption coefficient of the absorption band 3 of the 28SiF4 molecule was measured to be A(3) = 700 ± 30 km/mol. Within the limits of experimental error, this absorption coefficient is consistent with estimates obtained from independent measurements and virtually coincides with the coefficient A(3) = 691 km/mol calculated in this study by the quantum-chemical method MP2(full) with the basis set cc-pVQZ. ©2005 Pleiades Publishing, Inc