Point-contact spectroscopy of the borocarbide superconductor YNi2B2C

Point-contact (PC) spectroscopy measurements on YNi2B2C single crystals in the normal and superconducting (SC) state (T_c=15.4K) for the main crystallographic directions are reported. The PC study reveals the electron-phonon interaction (EPI) function with a dominant maximum around 12meV and a further weak structure (kink or shallow broad maximum) at higher energy at about 50meV. Other phonon maxima at 20, 24 and 32meV specified in the phonon DOS of YNi2B2C by neutron measurements [PRB, V.55, 9058 (1997)] are not resolved in the PC spectra pointing out to the main role of the low energy phonon modes in EPI. Directional study of the SC gap results in \Delta_[100]=1.5meV for the a- direction and \Delta_[001]=2.4meV along the c-axis which may point to anisotropic and/or multiband behavior. Noteworthy, the critical temperature T_c in all cases corresponds to that of bulk samples. The value 2\Delta_[001]/kT_c=3.6 is close to the BCS one of 3.52, and the temperature dependence \Delta(T) is BCS-like, while for the a-direction \Delta(T) deviates from mean-field BCS behavior above T_c/2. The directional variation in \Delta can be attributed to the multiband nature of the SC state in YNi2B2C predicted 10 years ago (PRL, V.80, 1730 (1998)).Comment: 3 figs, 2 pages, presented on M2S-HTSC Conference, July 9-14, 2006, Dresde

The superconducting gaps in FeSe studied by soft point-contact Andreev reflection spectroscopy

FeSe single crystals have been studied by soft point-contact Andreev-reflection spectroscopy. Superconducting gap features in the differential resistance dV/dI(V) of point contacts such as a characteristic Andreev-reflection double-minimum structure have been measured versus temperature and magnetic field. Analyzing dV/dI within the extended two-gap Blonder-Tinkham-Klapwijk model allows to extract both the temperature and magnetic field dependence of the superconducting gaps. The temperature dependence of both gaps is close to the standard BCS behavior. Remarkably, the magnitude of the double-minimum structure gradually vanishes in magnetic field, while the minima position only slightly shifts with field indicating a weak decrease of the superconducting gaps. Analyzing the dV/dI(V) spectra for 25 point contacts results in the averaged gap values = 1.8+/-0.4meV and =1.0+/-0.2 meV and reduced values 2/kTc=4.2+/-0.9 and 2/kTc=2.3+/-0.5 for the large (L) and small (S) gap, respectively. Additionally, the small gap contribution was found to be within tens of percent decreasing with both temperature and magnetic field. No signatures in the dV/dI spectra were observed testifying a gapless superconductivity or presence of even smaller gaps.Comment: 8 pages, 4 figs., 3 tables. Shortened version without fig.4 and Table 3 is accepted for publication in Phys. Rev.

Point-contact spectroscopy of the nickel borocarbide superconductor YNi2B2C in the normal and superconducting state

Point-contact (PC) spectroscopy measurements of YNi2B2C single crystals in the normal and superconducting (SC) state (T_c=15.4K) for the main crystallographic directions are reported. The PC study reveals the electron-phonon interaction (EPI) spectral function with dominant phonon maximum around 12 meV and further weak structures (hump or kink) at higher energy at about 50 meV. No "soft" modes below 12 meV are resolved in the normal state. The PC EPI spectra are qualitatively similar for the different directions. Contrary, directional study of the SC gap results in \Delta_[100]=1.5 meV for the a direction and \Delta_[001]=2.3 meV along the c axis; however the critical temperature T_c in PC in all cases is near to that in the bulk sample. The value 2\Delta_[001]/kT_c=3.6 is close to the BCS value of 3.52, and the temperature dependence \Delta_[001](T) is BCS-like, while the for small gap \Delta_[100](T) is below BCS behavior at T>T_c/2 similarly as in the two-gap superconductor MgB2. It is supposed that the directional variation \Delta can be attributed to a multiband nature of the SC state in YNi2B2C.Comment: 9 pages, 10 figures, to be published in a special issue of J. Low Temp. Phys. in honour of Prof. H. von Loehneyse

Peculiarities of electron transport and resistive switching in point contacts on TiSe2, TiSeS and CuxTiSe2

TiSe2 has received much attention among the transition metals chalcogenides because of its thrilling physical properties concerning atypical resistivity behavior, emerging of charge density wave (CDW) state, induced superconductivity etc. Here, we report discovery of new feature of TiSe2, namely, observation of resistive switching in voltage biased point contacts (PCs) based on TiSe2 and its derivatives doped by S and Cu (TiSeS, CuxTiSe2). The switching is taking place between a low resistive mainly metallic-type state and a high resistive semiconducting-type state by applying bias voltage (usually below 0.5V), while reverse switching takes place by applying voltage of opposite polarity (usually below 0.5V). The difference in resistance between these two states can reach up to two orders of magnitude at the room temperature. The origin of the effect can be attributed to the variation of stoichiometry in PC core due to drift/displacement of Se/Ti vacancies under high electric field. Additionally, we demonstrated, that heating takes place in PC core, which can facilitate the electric field induced effect. At the same time, we did not found any evidence for CDW spectral features in our PC spectra for TiSe2. The observed resistive switching allows to propose TiSe2 and their derivatives as the promising materials, e.g., for non-volatile resistive random access memory (ReRAM) engineering.Comment: 11 pages, 6 figure

Distribution of the superconducting gap in an YNi2B2C film studied by point contact spectroscopy

The differential resistances $R_d=dV/dI(V)$ of point contacts between a normal metal and a c axis oriented YNi2B2C film ($T_c$ = 15.2K) in the superconducting (SC) state have been investigated. $R_d(V)$ contains clear "gap" features connected with processes of Andreev reflection at the boundary between normal metal and superconductor that allow the determination of the SC gap $\Delta$ and its temperature and magnetic field dependence. A distribution of $\Delta$ from $\Delta_min\approx$ 1.5 meV to $\Delta_max\approx$ 2.4 meV is revealed; however the critical temperature $T_c$ in all cases corresponded to that of the film. The value 2$\Delta_max/k_BT_c\approx$3.66 is close to the BCS value of 3.52, and the temperature dependence $\Delta(T)$ is BCS-like, irrespective of the actual $\Delta$ value. It is supposed that the distribution of $\Delta$ can be attributed to a gap anisotropy or to a multiband nature of the SC state in YNi2B2C, rather than to the presence of nodes in the gap.Comment: 6 two-column pages, 7 figs; V2: as published, Fig.4 is modifie