35 research outputs found
Study of Zircaloy-4 fuel cladding corrosion using ion beams - Application to long term disposal of nuclear wastes
AC
Role of proton irradiation and relative air humidity on iron corrosion
This paper presents a study of the effects of proton irradiation on iron
corrosion. Since it is known that in humid atmospheres, iron corrosion is
enhanced by the double influence of air and humidity, we studied the iron
corrosion under irradiation with a 45% relative humidity. Three proton beam
intensities (5, 10 and 20 nA) were used. To characterise the corrosion layer,
we used ion beam methods (Rutherford Backscattering Spectrometry (RBS), Elastic
Recoil Detection Analysis (ERDA)) and X-ray Diffraction (XRD) analysis. The
corrosion kinetics are plotted for each proton flux. A diffusion model of the
oxidant species is proposed, taking into account the fact that the flux through
the surface is dependent on the kinetic factor K. This model provides evidence
for the dependence of the diffusion coefficient, D, and the kinetic factor, K,
on the proton beam intensity. Comparison of the values for D with the diffusion
coefficients for thermal oxygen diffusion in iron at 300 K suggests an
enhancement due to irradiation of 6 orders of magnitude
Use of the point defect model to interpret the iron oxidation kinetics under proton irradiation
This article concerns the study of iron corrosion in wet air under mega-electron-volt proton irradiation for different fluxes at room temperature and with a relative humidity fixed to 45%. Oxidized iron sample surfaces are characterized by ion beam analysis (Rutherford backscattering spectrometry and elastic recoil detection analysis), for the elemental analysis. The structural and physicochemical characterization is performed using the x-ray photoelectron spectroscopy and transmission electron microscopy techniques. We have also measured the iron oxidation kinetics. Radiation enhanced diffusion and transport processes have been evidenced. The modeling of the experimental data shows that the apparent oxygen diffusion coefficient increases whereas the oxygen transport velocity decreases as function of flux. Finally, the point defect model has been used to determine the electric field value in the samples. Results have shown that the transport process can be attributed to the presence of an electrical potential gradient
Microbial induced corrosion in French concept of nuclear waste underground disposal
International audienc
Apport des analogues archéologiques à la prédiction de l’altération des matériaux sur le très long terme
Stress corrosion cracking in the context of deep geological nuclear storage
International audienc