2,708 research outputs found

    On classification of Poisson vertex algebras

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    We describe a conjectural classification of Poisson vertex algebras of CFT type and of Poisson vertex algebras in one differential variable (= scalar Hamiltonian operators)

    Dynamical excitonic effects in metals and semiconductors

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    The dynamics of an electron--hole pair induced by the time--dependent screened Coulomb interaction is discussed. In contrast to the case where the static electron--hole interaction is considered we demonstrate the occurrence of important dynamical excitonic effects in the solution of the Bethe--Salpeter equation.This is illustrated in the calculated absorption spectra of noble metals (copper and silver) and silicon. Dynamical corrections strongly affect the spectra, partially canceling dynamical self--energy effects and leading to good agreement with experiment.Comment: Accepted for publication on Phys. Rev. Let

    Quantitative analysis of Clausius inequality

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    In the context of driven diffusive systems, for thermodynamic transformations over a large but finite time window, we derive an expansion of the energy balance. In particular, we characterize the transformations which minimize the energy dissipation and describe the optimal correction to the quasi-static limit. Surprisingly, in the case of transformations between homogeneous equilibrium states of an ideal gas, the optimal transformation is a sequence of inhomogeneous equilibrium states.Comment: arXiv admin note: text overlap with arXiv:1404.646

    Minimum dissipation principle in stationary non equilibrium states

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    We generalize to non equilibrium states Onsager's minimum dissipation principle. We also interpret this principle and some previous results in terms of optimal control theory. Entropy production plays the role of the cost necessary to drive the system to a prescribed macroscopic configuration

    Large deviation approach to non equilibrium processes in stochastic lattice gases

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    We present a review of recent work on the statistical mechanics of non equilibrium processes based on the analysis of large deviations properties of microscopic systems. Stochastic lattice gases are non trivial models of such phenomena and can be studied rigorously providing a source of challenging mathematical problems. In this way, some principles of wide validity have been obtained leading to interesting physical consequences.Comment: Extended version of the lectures given by G. Jona-Lasinio at the 9th Brazilian school of Probability, August 200

    On the long range correlations of thermodynamic systems out of equilibrium

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    Experiments show that macroscopic systems in a stationary nonequilibrium state exhibit long range correlations of the local thermodynamic variables. In previous papers we proposed a Hamilton-Jacobi equation for the nonequilibrium free energy as a basic principle of nonequilibrium thermodynamics. We show here how an equation for the two point correlations can be derived from the Hamilton-Jacobi equation for arbitrary transport coefficients for dynamics with both external fields and boundary reservoirs. In contrast with fluctuating hydrodynamics, this approach can be used to derive equations for correlations of any order. Generically, the solutions of the equation for the correlation functions are non-trivial and show that long range correlations are indeed a common feature of nonequilibrium systems. Finally, we establish a criterion to determine whether the local thermodynamic variables are positively or negatively correlated in terms of properties of the transport coefficients.Comment: 4 page

    Macroscopic current fluctuations in stochastic lattice gases

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    We study current fluctuations in lattice gases in the macroscopic limit extending the dynamic approach to density fluctuations developed in previous articles. More precisely, we derive large deviation estimates for the space--time fluctuations of the empirical current which include the previous results. Large time asymptotic estimates for the fluctuations of the time average of the current, recently established by Bodineau and Derrida, can be derived in a more general setting. There are models where we have to modify their estimates and some explicit examples are introduced.Comment: 4 pages, LaTeX, Changed conten

    Large deviations of the empirical current in interacting particle systems

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    We study current fluctuations in lattice gases in the hydrodynamic scaling limit. More precisely, we prove a large deviation principle for the empirical current in the symmetric simple exclusion process with rate functional I. We then estimate the asymptotic probability of a fluctuation of the average current over a large time interval and show that the corresponding rate function can be obtained by solving a variational problem for the functional I. For the symmetric simple exclusion process the minimizer is time independent so that this variational problem can be reduced to a time independent one. On the other hand, for other models the minimizer is time dependent. This phenomenon is naturally interpreted as a dynamical phase transition.Comment: 26 page

    Bound excitons in time-dependent density-functional-theory: optical and energy-loss spectra

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    A robust and efficient frequency dependent and non-local exchange-correlation fxc(r,r;ω)f_{xc}(r,r';\omega) is derived by imposing time-dependent density-functional theory (TDDFT) to reproduce the many-body diagrammatic expansion of the Bethe-Salpeter polarization function. As an illustration, we compute the optical spectra of LiF, \sio and diamond and the finite momentum transfer energy-loss spectrum of LiF. The TDDFT results reproduce extremely well the excitonic effects embodied in the Bethe-Salpeter approach, both for strongly bound and resonant excitons. We provide a working expression for fxcf_{xc} that is fast to evaluate and easy to implement.Comment: 4 pages, 2 figures. To appear in Phys. Rev. Let
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