Epitaxial strain and the magnetic properties of canted antiferromagnetic perovskite NaNiF3 thin films

The perovskite crystal structure is known to exhibit a multitude of interesting physical phenomena owing to the intricate coupling of the electronic and magnetic properties to the structure. Fluoroperovskites offer an alternative chemistry to the much more widely studied oxide materials, which may prove advantageous for applications. It is demonstrated here for the first time that the antiferromagnetic perovskite fluoride, NaNiF3, can be synthesized in thin film form. The films were grown via molecular beam epitaxy on SrTiO3 (100) substrates to produce high quality epitaxial films in the thickness range of 5-50 nm. The Pnma structure of the films was confirmed by x-ray diffraction. There was a decrease in the out-of-plane lattice spacing from the bulk value corresponding to a maximum strain of 1.7% in the thinnest film. Canted antiferromagnetism was measured in all films using magnetometry and a negative change in the antiferromagnetic ordering temperature of ΔTN = - 9.1 ± 0.7 K was observed with increasing strain

Hexagonal Tilings: Tutte Uniqueness

We develop the necessary machinery in order to prove that hexagonal tilings are uniquely determined by their Tutte polynomial, showing as an example how to apply this technique to the toroidal hexagonal tiling.Comment: 12 figure

Rotation curves and metallicity gradients from HII regions in spiral galaxies

In this paper we study long slit spectra in the region of H$\alpha$ emission line of a sample of 111 spiral galaxies with recognizable and well defined spiral morphology and with a well determined environmental status, ranging from isolation to non-disruptive interaction with satellites or companions. The form and properties of the rotation curves are considered as a function of the isolation degree, morphological type and luminosity. The line ratios are used to estimate the metallicity of all the detected HII regions, thus producing a composite metallicity profile for different types of spirals. We have found that isolated galaxies tend to be of later types and lower luminosity than the interacting galaxies. The outer parts of the rotation curves of isolated galaxies tend to be flatter than in interacting galaxies, but they show similar relations between global parameters. The scatter of the Tully-Fisher relation defined by isolated galaxies is significantly lower than that of interacting galaxies. The [NII]/H$\alpha$ ratios, used as metallicity indicator, show a clear trend between Z and morphological type, t, with earlier spirals showing larger ratios; this trend is tighter when instead of t the gradient of the inner rotation curve, G, is used; no trend is found with the interaction status. The Z-gradient of the disks depends on the type, being almost flat for early spirals, and increasing for later types. The [NII]/H$\alpha$ ratios measured for disk HII regions of interacting galaxies are higher than for normal/isolated objects, even if all the galaxy families present similar distributions of H$\alpha$ Equivalent Width.Comment: accepted for publication in A&A (tables for HII region parameters incomplete, contact [email protected] for the whole set of tables

Tunable BODIPY derivatives amenable to "click" and peptide chemistry

Novel azido- and amino- functionalised fluorescent probes based on the BODIPY framework have been developed. The probes can be easily and cheaply synthesised, exhibit the highly desirable BODIPY fluorescent properties, and are amenable to “click” and peptide chemistry methodologies. These probes provide a stable and readily available tool amenable for the visualisation of both solution and solid supported events

Development and evaluation of a prototype global volcano surveillance system utilizing the ERTS-1 satellite data collection system

There are no author-identified significant results in this report