Theory of adiabatic Hexaamminecobalt-Self-Exchange

We have reexamined the thermally induced Co(NH_3)_6^{2+/3+} [Co(II/III)] redox reaction using the first principles density-functional-theory method, semiclassical Marcus theory, and known charge transfer parameters. We confirm a previously suggested mechanism involving excited state (^2E_g) of Co(II) which becomes lower than the ground state (^4T_1g) in the transition state region. This lowers the transition state barrier considerably by about 6.9 kcal/mol and leads to a spin-allowed and adiabatic electron exchange process. Our calculations are consistent with previous experimental results regarding the spin-excitation energy (^3T_1g) of Co(III), and the fact that an optical absorption peak (^2E_g) of the Co(II) species could not be found experimentally. Our rate is of order 6 10^{-3} 1/Ms and hence 2 orders of magnitude faster than determined previously by experiments.Comment: 10 pages, 5 figures, 4 tables; submitted to J.Chem.Phy

Small Energy Scale for Mixed-Valent Uranium Materials

We investigate a two-channel Anderson impurity model with a $5f^1$ magnetic and a $5f^2$ quadrupolar ground doublet, and a $5f^2$ excited triplet. Using the numerical renormalization group method, we find a crossover to a non-Fermi liquid state below a temperature $T^*$ varying as the $5f^2$ triplet-doublet splitting to the 7/2 power. To within numerical accuracy, the non-linear magnetic susceptibility and the $5f^1$ contribution to the linear susceptibility are given by universal one-parameter scaling functions. These results may explain UBe$_{13}$ as mixed valent with a small crossover scale $T^*$.Comment: 4 pages, 3 figures, REVTeX, to appear in Phys. Rev. Let

Staggered Superconductivity in UPt3_3: A New Phenomenological Approach

We present a new Ginzburg-Landau theory for superconductivity in UPt$_3$, based upon a multicomponent order parameter transforming under an irreducible space group representation; the phase is staggered in real space. Our model can explain the $H-T-P$ phase diagram including the tetracritical point for all field directions. We motivate this unconventional superconducting state in terms of odd-in-time-reversal pairing that may arise in one- or two-channel Kondo models, and suggest experimental tests.Comment: 12 pages, 3 postscript figures are appended as a uuencoded file, RevTeX 3.

Nonparametric measures of the impact of public research expenditures on Australian broadacre agriculture

Nonparametric methods are used to measure the impact of public research expenditures on Australian broadacre agriculture over the 1953–94 period. Results using both unrestricted and 30‐year lagged specifications of the research impacts on productivity suggest that while certain aspects of the nonparametric multi‐input/output technologies are quite robust to alternative specifications (in particular, the associated Malmquist total factor productivity indexes), other aspects are less stable (in particular, the indexes on input and, to a lesser extent, output biased technical change). Internal rates of return to research expenditures on Australian broadacre agriculture are estimated to be in the 12 per cent to 20 per cent range.Crop Production/Industries, Research and Development/Tech Change/Emerging Technologies,

Cosmic X-ray physics

The soft X-ray sky survey data are combined with the results from the UXT sounding rocket payload. Very strong constraints can then be placed on models of the origin of the soft diffuse background. Additional observational constraints force more complicated and realistic models. Significant progress was made in the extraction of more detailed spectral information from the UXT data set. Work was begun on a second generation proportional counter response model. The first flight of the sounding rocket will have a collimator to study the diffuse background