61,168 research outputs found
Cohesion of BaReH and BaMnH: Density Functional Calculations and Prediction of (MnH Salts
Density functional calculations are used to calculate the structural and
electronic properties of BaReH and to analyze the bonding in this compound.
The high coordination in BaReH is due to bonding between Re 5 states and
states of -like symmetry formed from combinations of H orbitals in the
H cage. This explains the structure of the material, its short bond lengths
and other physical properties, such as the high band gap. We compare with
results for hypothetical BaMnH, which we find to have similar bonding and
cohesion to the Re compound. This suggests that it may be possible to
synthesize (MnH salts. Depending on the particular cation, such salts
may have exceptionally high hydrogen contents, in excess of 10 weight
Weighted Density Approximation Description of Insulating YH and LaH
Density functional calculations within the weighted density approximation
(WDA) are presented for YH and LaH. We investigate some commonly used
pair-distribution functions G. These calculations show that within a consistent
density functional framework a substantial insulating gap can be obtained while
at the same time retaining structural properties in accord with experimental
data. Our WDA band structures agree with those of approximation very well,
but the calculated band gaps are still 1.0-2.0 eV smaller than experimental
findings.Comment: 6 Pages, 3 figure
Broadband optical radiation detector
A method and apparatus for detecting optical radiation by optically monitoring temperature changes in a microvolume caused by absorption of the optical radiation to be detected is described. More specifically, a thermal lens forming material is provided which has first and second opposite, substantially parallel surfaces. A reflective coating is formed on the first surface, and a radiation absorbing coating is formed on the reflective coating. Chopped, incoming optical radiation to be detected is directed to irradiate a small portion of the radiation absorbing coating. Heat generated in this small area is conducted to the lens forming material through the reflective coating, thereby raising the temperature of a small portion of the lens forming material and causing a thermal lens to be formed therein
Double-beam optical method and apparatus for measuring thermal diffusivity and other molecular dynamic processes in utilizing the transient thermal lens effect
A sample material was irradiated by relatively high power, short pulses from a dye laser. Energy from the pulses was absorbed by the sample material, thereby forming a thermal lens in the area of absorption. The pulse repetition rate was chosen so that the thermal lens is substantially dissipated by the time the next pulse reaches the sample material. A probe light beam, which in a specific embodiment is a relatively low power, continuous wave (cw) laser beam, irradiated the thermal lens formed in the sample material. The intensity characteristics of the probe light beam subsequent to irradiation of the thermal lens is related to changes in the refractive index of the sample material as the thermal lens is formed and dissipated
HI gas in rejuvenated radio galaxies: GMRT observations of the DDRG J1247+6723
We report the detection of HI absorption towards the inner double of the
double-double radio galaxy (DDRG) J1247+6723 with the Giant Metrewave Radio
Telescope (GMRT). The inner double is a Giga-hertz peaked spectrum (GPS) source
with a linear size of 14 pc while the overall size defined by the outer double
is 1195 kpc, making it a giant radio source. The absorption profile is well
resolved and consists of a number of components on either side of the optical
systemic velocity. The neutral hydrogen column density is estimated to be
N(HI)=6.73*10^{20}(T_s/100)(f_c/1.0) cm^{-2}, where T_s and f_c are the spin
temperature and covering factor of the background source respectively. We
explore any correlation between the occurrence of HI absorption and
rejuvenation of radio activity and suggest that there could be a strong
relationship between them.Comment: 5 pages, 2 figures, accepted for publication in MNRAS Letter
Formation of iron nitride thin films with Al and Ti additives
In this work we investigate the process of iron nitride (Fe-N) phase
formation using 2 at.% Al or 2 at.% Ti as additives. The samples were prepared
with a magnetron sputtering technique using different amount of nitrogen during
the deposition process. The nitrogen partial pressure (\pn) was varied between
0-50% (rest Argon) and the targets of pure Fe, [Fe+Ti] and [Fe+Al] were
sputtered. The addition of small amount of Ti or Al results in improved
soft-magnetic properties when sputtered using \pn 10\p. When \pn is
increased to 50\p non-magnetic Fe-N phases are formed. We found that iron
mononitride (FeN) phases (N at% 50) are formed with Al or Ti addition at
\pn =50% whereas in absence of such addition \eFeN phases (N\pat30) are
formed. It was found that the overall nitrogen content can be increased
significantly with Al or Ti additions. On the basis of obtained result we
propose a mechanism describing formation of Fe-N phases Al and Ti additives.Comment: 9 Pages, 7 Figure
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