Electrically modulated photoluminescence in ferroelectric liquid crystal

Electrical modulation and switching of photoluminescence (PL) have been demonstrated in pure deformed helix ferroelectric liquid crystal (DHFLC) material. The PL intensity increases and peak position shifts towards lower wavelength above a threshold voltage which continues up to a saturation voltage. This is attributed to the helix unwinding phenomenon in the DHFLC on the application of an electric field. Moreover, the PL intensity could be switched between high intensity (field-on) and low intensity (field-off) positions. These studies would add a new dimension to ferroelectric liquid crystal's application in the area of optical devices.Comment: 4 figure

Au9+ swift heavy ion irradiation of Zn[CS(NH2)2]3SO4 crystal: Crystalline perfection and optical properties

The single crystal of tris(thiourea)zinc sulphate (Zn[CS(NH2)2]3SO4) was irradiated by 150 MeV Au9+ swift heavy ions and analyzed in comparison with pure crystal for crystalline perfection and optical properties. The Fourier transform infrared and x-ray powder diffraction inferred that swift ions lead the disordering and breaking of molecular bonds in lattice without formation of new structural phases. High resolution X-ray diffraction (HRXRD) revealed the abundance of point defects, and formation of mosaics and low angle grain boundaries in the irradiated region of crystal. The swift ion irradiation found to affect the lattice vibrational modes and functional groups significantly. The defects induced by heavy ions act as the color centers and resulted in enhance of photoluminescence emission intensity. The optical transparency and band gap found to be decreased.Comment: 7 page

Coexistence of Band Jahn Teller Distortion and superconductivity in correlated systems

The co-existence of band Jahn-Teller (BJT) effect with superconductivity (SC) is studied for correlated systems, with orbitally degenerate bands using a simple model. The Hubbard model for a doubly degenerate orbital with the on-site intraorbital Coulomb repulsion treated in the slave boson formalism and the interorbital Coulomb repulsion treated in the Hartree-Fock mean field approximation, describes the correlated system. The model further incorporates the BJT interaction and a pairing term to account for the lattice distortion and superconductivity respectively. It is found that structural distortion tends to suppress superconductivity and when SC sets in at low temperatures, the growth of the lattice distortion is arrested. The phase diagram comprising of the SC and structural transition temperatures $T_c$ and $T_s$ versus the dopant concentration $\delta$ reveals that the highest obtainable $T_c$ for an optimum doping is limited by structural transition. The dependence of the occupation probabilities of the different bands as well as the density of states (DOS) in the distorted-superconducting phase, on electron correlation has been discussed.Comment: RevTex, 4 pages, 4 figuers (postscript files attached) Journal Reference : Phys. Rev. B (accepted for publication

Time reversal symmetry breaking superconductivity

We study time reversal symmetry breaking superconductivity with $\Delta_k = \Delta_{x^2-y^2} (k) +e^{i\theta} \Delta_{\alpha}$ ($\alpha = s$ or $d_{xy}$) symmetries. It is shown that the behavior of such superconductors could be {\em qualitatively} different depending on the minor components ($\alpha$) and its phase at lower temperatures. It is argued that such {\em qualitatively different} behaviors in thermal as well as in angular dependencies could be a {\em source} of consequences in transport and Josephson physics. Orthorhombicity is found to be a strong mechanism for mixed phase (in case of $\alpha = s$). We show that due to electron correlation the order parameter is more like a pure $d_{x^2-y^2}$ symmetry near optimum doping.Comment: 5 pages, 5 figures (attached), to be published in Physical Review

Stability of the doped antiferromagnetic state of the t-t'-Hubbard model

The next-nearest-neighbour hopping term t' is shown to stabilize the AF state of the doped Hubbard model with respect to transverse perturbations in the order- parameter by strongly suppressing the intraband particle-hole processes. For a fixed sign of t', this stabilization is found to be significantly different for electron and hole doping, which qualitatively explains the observed difference in the degree of robustness of the AF state in the electron-doped (Nd_{2-x}Ce_{x}CuO_{4}) and hole-doped (La_{2-x}Sr_{x}CuO_{4}) cuprates. The t'-U phase diagram is obtained for both signs of the t' term, showing the different regions of stability and instability of the doped antiferromagnet. Doping is shown to suppress the t'-induced frustration due to the competing interaction J'. A study of transverse spin fluctuations in the metallic AF state reveals that the decay of magnons into particle-hole excitations yields an interesting low-energy result \Gamma \sim \omega for magnon damping.Comment: 10 pages, 8 figure

Theory of excited state absorptions in phenylene-based π\pi-conjugated polymers

Within a rigid-band correlated electron model for oligomers of poly-(paraphenylene) (PPP) and poly-(paraphenylenevinylene) (PPV), we show that there exist two fundamentally different classes of two-photon A$_g$ states in these systems to which photoinduced absorption (PA) can occur. At relatively lower energies there occur A$_g$ states which are superpositions of one electron - one hole (1e--1h) and two electron -- two hole (2e--2h) excitations, that are both comprised of the highest delocalized valence band and the lowest delocalized conduction band states only. The dominant PA is to one specific member of this class of states (the mA$_g$). In addition to the above class of A$_g$ states, PA can also occur to a higher energy kA$_g$ state whose 2e--2h component is {\em different} and has significant contributions from excitations involving both delocalized and localized bands. Our calculated scaled energies of the mA$_g$ and the kA$_g$ agree reasonably well to the experimentally observed low and high energy PAs in PPV. The calculated relative intensities of the two PAs are also in qualitative agreement with experiment. In the case of ladder-type PPP and its oligomers, we predict from our theoretical work a new intense PA at an energy considerably lower than the region where PA have been observed currently. Based on earlier work that showed that efficient charge--carrier generation occurs upon excitation to odd--parity states that involve both delocalized and localized bands, we speculate that it is the characteristic electronic nature of the kA$_g$ that leads to charge generation subsequent to excitation to this state, as found experimentally.Comment: Revtex4 style, 2 figures inserted in the text, three tables, 10 page

Facile route to produce spherical and highly luminescent Tb3+doped Y2O3nanophosphors

Terbium doped yttrium oxide (Y2O3:Tb3+) nanophosphor has been synthesized via a facial yet modified co-precipitation method. To get maximum luminescence output from Y2O3:Tb3+nanophosphors, surfactants namely, Cetyl trimethylammonium bromide (CTAB) and Trioctylphosphine oxide (TOPO) were added during synthesis. Further, it has been observed that combined addition of surfactant (CTAB�+�TOPO) at the time of synthesis has resulted in nearly spherical morphology of the nanophosphor. Furthermore, these optimized material are observed to have enhanced integrated photoluminescence (PL) intensity of ∼23% as compared to the one synthesized without the addition of any surfactant. The results are further supported by detailed structural and optical studies. Optimum use of surfactants during synthesis shows for the first time that both nano-sized distribution and high crystallinity can be achieved simultaneously which has resulted in bright green emission in Tb3+doped Y2O3nanophosphors. � 201