Coherently Embedded Ag Nanostructures in Si: 3D Imaging and their application to SERS

Surface enhanced Raman spectroscopy (SERS) has been established as a powerful tool to detect very low-concentration bio-molecules. One of the challenging problems is to have reliable and robust SERS substrate. Here, we report on a simple method to grow coherently embedded (endotaxial) silver nanostructures in silicon substrates, analyze their three-dimensional shape by scanning transmission electron microscopy tomography and demonstrate their use as a highly reproducible and stable substrate for SERS measurements. Bi-layers consisting of Ag and GeOx thin films were grown on native oxide covered silicon substrate using a physical vapor deposition method. Followed by annealing at 800°C under ambient conditions, this resulted in the formation of endotaxial Ag nanostructures of specific shape depending upon the substrate orientation. These structures are utilized for detection of Crystal Violet molecules of 5 × 10−10 M concentrations. These are expected to be one of the highly robust, reusable and novel substrates for single molecule detection

Direct Imaging of Chiral Domain Walls and Neel Type Skyrmionium in Ferrimagnetic Alloys

The evolution of chiral spin structures is studied in ferrimagnetic Ta Ir Fe GdFeCo Pt multilayers as a function of temperature using scanning electron microscopy with polarization analysis SEMPA . The GdFeCo ferrimagnet exhibits pure right handed N el type domain wall DW spin textures over a large temperature range. This indicates the presence of a negative Dzyaloshinskii Moriya interaction that can originate from both the top Fe Pt and the Co Pt interfaces. From measurements of the DW width, as well as complementary magnetic characterization, the exchange stiffness as a function of temperature is ascertained. The exchange stiffness is surprisingly more or less constant, which is explained by theoretical predictions. Beyond single skyrmions, it is identified by direct imaging a pure N el type skyrmionium, which due to the expected vanishing skyrmion Hall angle, is a promising topological spin structure to enable applications by next generation of spintronic device