21 research outputs found
Catalytic dehalogenation of aryl chlorides mediated by ruthenium(II) phosphine complexes
Get PDFThe catalytic dechlorination of aryl chlorides performed by RuHCl(H_2)_2(PCy_3)_2 and RuH_2(H_2)_2(PCy_3)_2 in alcohols is rapid and complete within 1 h. The mechanism involves a transfer hydrogenation step with participation of the alcohol. The system exhibits significant functional group tolerance. The catalyst can be generated in situ from [RuCl_2(COD)]_x (COD = cyclooctadiene) and 2 equiv of phosphine (PCy_3 or P^iPr_3). Catalytic conversions are similar to those observed when an isolated precatalyst is used. Mechanistic considerations and the scope of the process are discussed
Hipsters End: Queer Time, and Imitation versus Authenticity, in Matthew Lopezâs the Inheritance
No full textComposition of Rice, Influence of Variety and Environment on Physical and Chemical Composition
No full textHydrogenolysis of a Ruthenium Carbene Complex to Yield DihydrideâDihydrogen Tautomers: Mechanistic Implications for Tandem ROMPâHydrogenation Catalysis
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Solution Thermochemistry of Ligand Substitution Reactions Involving Organoruthenium Complexes
No full textProductive Chloroarene CâCl Bond Activation: Palladium/Phosphine-Catalyzed Methods for Oxidation of Alcohols and Hydrodechlorination of Chloroarenes
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