5 research outputs found
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Influence of oxygen pressure on the fs laserinduced oxidation of molybdenum thin films
We present a study of femtosecond (1028 nm, 230 fs, 54.7 MHz) laser processing on molybdenum (Mo) thin films. Irradiations were done under ambient air as well as pure oxygen (O2) at various gauge pressures (4, 8, 12 and 16 psi). Our results indicate that the high heating rates associated with laser processing allow the production of different molybdenum oxides. Raman spectroscopy and scanning electron microscopy are used to characterize the molybdenum oxidation for the different irradiation and oxygen pressures parameters chosen showing a high correlation between well-defined oxidation zones and the oxygen pressure surrounding the samples during the irradiation of the Mo thin films
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High repetition rate femtosecond laser heat accumulation and ablation thresholds in cobalt-binder and binderless tungsten carbides
Femtosecond (fs) laser ablation has been studied for the potential of fast, high precision machining of difficult-to-machine materials like binderless tungsten carbide. Obstacles that have limited its efficiency include melting from heat accumulation (HA), particle shielding, and plasma shielding. To address HA without shielding effects, high repetition rate (57.4 MHz), ultra-low fluence fs laser irradiation is performed to study the incubation effect and subsequent HA-ablation threshold of fine-grained tungsten carbides. Exposure times on the order of 100 ms were conducted in air with fluences (1.82 to 9.09 mJ/cm2) two orders of magnitude below the single fs pulse ablation thresholds reported in literature (0.4 J/cm2). Heat accumulation at high repetition rate explains the ultra-low fluence melt threshold behavior resulting in melt crowns around ablated holes and grooves. The results of this study aid in predicting heat buildup in high repetition rate laser irradiation for applications that wish to achieve high ablation rates of difficult-to-machine, ultrahard materials and help enable shaping of binderless tungsten carbide for use in applications too extreme for bindered tungsten carbide
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Ultrafast laser welding of ceramics.
Welding of ceramics is a key missing component in modern manufacturing. Current methods cannot join ceramics in proximity to temperature-sensitive materials like polymers and electronic components. We introduce an ultrafast pulsed laser welding approach that relies on focusing light on interfaces to ensure an optical interaction volume in ceramics to stimulate nonlinear absorption processes, causing localized melting rather than ablation. The key is the interplay between linear and nonlinear optical properties and laser energy-material coupling. The welded ceramic assemblies hold high vacuum and have shear strengths comparable to metal-to-ceramic diffusion bonds. Laser welding can make ceramics integral components in devices for harsh environments as well as in optoelectronic and/or electronic packages needing visible-radio frequency transparency
Recommended from our members
Influence of oxygen pressure on the fs laserinduced oxidation of molybdenum thin films
We present a study of femtosecond (1028 nm, 230 fs, 54.7 MHz) laser processing on molybdenum (Mo) thin films. Irradiations were done under ambient air as well as pure oxygen (O2) at various gauge pressures (4, 8, 12 and 16 psi). Our results indicate that the high heating rates associated with laser processing allow the production of different molybdenum oxides. Raman spectroscopy and scanning electron microscopy are used to characterize the molybdenum oxidation for the different irradiation and oxygen pressures parameters chosen showing a high correlation between well-defined oxidation zones and the oxygen pressure surrounding the samples during the irradiation of the Mo thin films
Recommended from our members
Ultrafast laser welding of ceramics.
Welding of ceramics is a key missing component in modern manufacturing. Current methods cannot join ceramics in proximity to temperature-sensitive materials like polymers and electronic components. We introduce an ultrafast pulsed laser welding approach that relies on focusing light on interfaces to ensure an optical interaction volume in ceramics to stimulate nonlinear absorption processes, causing localized melting rather than ablation. The key is the interplay between linear and nonlinear optical properties and laser energy-material coupling. The welded ceramic assemblies hold high vacuum and have shear strengths comparable to metal-to-ceramic diffusion bonds. Laser welding can make ceramics integral components in devices for harsh environments as well as in optoelectronic and/or electronic packages needing visible-radio frequency transparency