Electron Transfer Reaction Through an Adsorbed Layer

We consider electron transfer from a redox to an electrode through and adsorbed intermediate. The formalism is developed to cover all regimes of coverage factor, from lone adsorbate to monolayer regime. The randomness in the distribution of adsorbates is handled using coherent potential approximation. We give current-overpotential profile for all coverage regimes. We explictly analyse the low and high coverage regimes by supplementing with DOS profile for adsorbate in both weakly coupled and strongly coupled sector. The prominence of bonding and anti-bonding states in the strongly coupled adsorbates at low coverage gives rise to saddle point behaviour in current-overpotential profile. We were able to recover the marcus inverted region at low coverage and the traditional direct electron transfer behaviour at high coverage

Warehouse Storing and Collecting of Parts

This report deals with reducing the high costs resulting from the wear and tear of the fork-lifts used to store or collect items in a warehouse. Two problems were identified and addressed separately. One concerns the way items should be stored or collected at storage locations on the shelves of one corridor. The other problem seeks for an efficient way to define which fork-lift should operate on each corridor, and the order by which the fork-lifts should visit the corridors. We give to both problems formulations that fit in the framework of combinatorial optimization