Activated recombinative desorption: A potential component in mechanisms of spacecraft glow

The concept of activated recombination of atomic species on surfaces can explain the production of vibrationally and translationally excited desorbed molecular species. Equilibrium statistical mechanics predicts that the molecular quantum state distributions of desorbing molecules is a function of surface temperature only when the adsorption probability is unity and independent of initial collision conditions. In most cases, the adsorption probability is dependent upon initial conditions such as collision energy or internal quantum state distribution of impinging molecules. From detailed balance, such dynamical behavior is reflected in the internal quantum state distribution of the desorbing molecule. This concept, activated recombinative desorption, may offer a common thread in proposed mechanisms of spacecraft glow. Using molecular beam techniques and equipment available at Los Alamos, which includes a high translational energy 0-atom beam source, mass spectrometric detection of desorbed species, chemiluminescence/laser induced fluorescence detection of electronic and vibrationally excited reaction products, and Auger detection of surface adsorbed reaction products, a fundamental study of the gas surface chemistry underlying the glow process is proposed

Ultrasonic detection of flaws in fusion butt welds

Reliable and accurate Delta technique, a nondestructive ultrasonics method, uses redirection of energy to detect randomly oriented imperfections in fusion butt welds. Data on flaws can be read from either an oscilloscope or a printout

Domain Coarsening in Systems Far from Equilibrium

The growth of domains of stripes evolving from random initial conditions is studied in numerical simulations of models of systems far from equilibrium such as Rayleigh-Benard convection. The scaling of the size of the domains deduced from the inverse width of the Fourier spectrum is studied for both potential and nonpotential models. The morphology of the domains and the defect structures are however quite different in the two cases, and evidence is presented for a second length scale in the nonpotential case.Comment: 11 pages, RevTeX; 3 uufiles encoded postscript figures appende

Pupil participation in Scottish schools: final report

This research was commissioned by Learning and Teaching Scotland (LTS) to evaluate the nature of pupil participation in primary and secondary schools across Scotland. The specific objectives of the research were: <p>· To describe what school staff and pupils understand by the term ‘pupil participation’.</p> <p>· To describe the range and usage of pupil participation mechanisms employed in schools.</p> <p>· To describe how school staff respect and respond to pupils’ views and ideas, and those of the wider community.</p> <p>· To identify the characteristics of schools and classrooms that facilitate effective pupil participation.</p> <p>· To identify possible barriers to the development of pupil participation in schools and to make suggestions about how these can be overcome.</p> <p>· To capture examples of effective practice of pupil participation.</p> <p>· To make suggestions about how pupil participation can help support the implementation of the Curriculum for Excellence.</p&gt

Editor’s Introduction

In this issue of the Engineering Management Journal (EMJ), we are delighted to present eight new articles that address several key areas across the engineering management discipline. The scope of the research studies highlights the application as well as the range of approaches adopted in engineering management [...

Editor’s Introduction

In this issue of the journal we are delighted to present eight articles that cover several key areas across engineering management. The discipline of engineering management [...

High intensity 5 eV O-atom exposure facility for material degradation studies

An atomic oxygen exposure facility was developed for studies of material degradation. The goal of these studies is to provide design criteria and information for the manufacture of long life (20 to 30 years) construction materials for use in low Earth orbit. The studies that are being undertaken will provide: (1) absolute reaction cross sections for the engineering design problems, (2) formulations of reaction mechanisms for use in the selection of suitable existing materials and the design of new more resistant ones, and (3) the calibration of flight hardware (mass spectrometers, etc.) in order to directly relate experiments performed in low Earth orbit to ground based investigations. The facility consists of a CW laser sustained discharge source of O-atoms, an atomic beam formation and diagnostics system, a spinning rotor viscometer, and provision for using the system for calibration of actual flight instruments

Atomic oxygen effects on candidate coatings for long-term spacecraft in low earth orbit

Candidate atomic oxygen protective coatings for long-term low Earth orbit (LEO) spacecraft were evaluated using the Los Alamos National Laboratory O-atom exposure facility. The coatings studied include Teflon, Al2O3, SiO2, and SWS-V-10, a silicon material. Preliminary results indicate that sputtered PTFE Teflon (0.1 micrometers) has a fluence lifetime of 10 to the 19th power O-atoms/cm (2), and sputtered silicon dioxide (0.1 micrometers), aluminum oxide (0.1 micrometers), and SWS-V-10, a silicone, (4 micrometers) have fluence lifetimes of 10 to the 20th power to 10 to the 21st power O-atoms/cm (2). There are large variations in fluence lifetime data for these coatings

Editor’s Introduction

In this issue of the Engineering Management Journal (EMJ), we are delighted to present seven new articles that address key areas across the field of engineering management. EMJ seeks to provide readers with timely access to the tools, techniques and underpinning knowledge to operate in the increasingly technology-driven world and manage arising complexities [...

Atomic oxygen effects on boron nitride and silicon nitride: A comparison of ground based and space flight data

The effects of atomic oxygen on boron nitride (BN) and silicon nitride (Si3N4) were evaluated in a low Earth orbit (LEO) flight experiment and in a ground based simulation facility. In both the inflight and ground based experiments, these materials were coated on thin (approx. 250A) silver films, and the electrical resistance of the silver was measured in situ to detect any penetration of atomic oxygen through the BN and Si3N4 materials. In the presence of atomic oxygen, silver oxidizes to form silver oxide, which has a much higher electrical resistance than pure silver. Permeation of atomic oxygen through BN, as indicated by an increase in the electrical resistance of the silver underneath, was observed in both the inflight and ground based experiments. In contrast, no permeation of atomic oxygen through Si3N4 was observed in either the inflight or ground based experiments. The ground based results show good qualitative correlation with the LEO flight results, indicating that ground based facilities such as the one at Los Alamos National Lab can reproduce space flight data from LEO