Recent progress in research on tungsten materials for nuclear fusion applications in Europe

The current magnetic confinement nuclear fusion power reactor concepts going beyond ITER are based on assumptions about the availability of materials with extreme mechanical, heat, and neutron load capacity. In Europe, the development of such structural and armour materials together with the necessary production, machining, and fabrication technologies is pursued within the EFDA long-term fusion materials programme. This paper reviews the progress of work within the programme in the area of tungsten and tungsten alloys. Results, conclusions, and future projections are summarized for each of the programme’s main subtopics, which are: (1) fabrication, (2) structural W materials, (3) W armour materials, and (4) materials science and modelling. It gives a detailed overview of the latest results on materials research, fabrication processes, joining options, high heat flux testing, plasticity studies, modelling, and validation experiments

A numerical study of the effect of single overloads on plasticity induced crack closure

In this work, the effect of single overloads on plasticity induced crack closure is studied. An elastic-plastic finite element model was developed and the crack opening level was calculated from the contact forces along the crack flank. The effects of the loading parameters and stress state are analysed, and the mechanisms behind crack closure variations are identified. An overload is a traumatic event that eliminates material’s memory relative to the load history. Crack tip blunting is the mechanism behind this memory loss, since it eliminates crack closure. Material hardening has a major relevance on the evolution of plastic blunting, which was evident in the variation of the CTOD parameter. On the other hand, the overload produces strong plastic deformation ahead of the crack tip, giving rise to conditions for the rapid generation of crack closure higher than before the event. The peak of crack closure was found to increase linearly with the load increase above the maximum baseline value. The crack is totally closed for overload ratios of about 2.5. Empirical models were developed for the peak of crack closure, for the delay of this peak and for the stabilization distance after the overload. Finally, the stress state was found to have a major effect on crack closure level after an overload.info:eu-repo/semantics/publishedVersio

Synthesis of FeTi hydrogen storage material via ball milling: effect of milling energy and atmosphere.

Attempts were made earlier to synthesize and activate the FeTi intermetallic during ball milling (BM), for H2 storage using sodium boron tetra-hydride (NaBH4) additive as a process controlling agent. Simple reactive milling starting from Fe and Ti powders resulted in heavy agglomeration of powders, due to the self sustaining nature of the reaction following an incubation period. When NaBH4 was used as the process control agent to avoid agglomeration, this resulted in the production of titanium hydride besides FeTi, and as a consequence unfavorable irreversibility in the subsequent hydrogen charging/discharging cycles [1,2,12]. The present work reports on modifications introduced in the synthesis process by changing two processing parameters, namely the milling energy and atmosphere compositio

Hybrid molecular dynamic Monte Carlo simulation and experimental production of a multi-component Cu-Fe-Ni-Mo-W alloy

ABSTRACT: High-entropy alloys are a class of materials intensely studied in the last years due to their innovative properties. Their unconventional compositions and chemical structures hold promise for achieving unprecedented combinations of mechanical properties. The Cu-Fe-Ni-Mo-W multicomponent alloy was studied using a combination of simulation and experimental production to test the possibility of formation of a simple solid solution. Therefore, Molecular Dynamics and hybrid Molecular Dynamic/Monte Carlo simulations from 10K up to the melting point of the alloy were analyzed together with the experimental production by arc furnace and powder milling. The Molecular Dynamics simulations starting with a bcc type-structure show the formation of a singlephase bcc solid solution type-structure, whereas using Monte Carlo one, generally produced a two-phase mixture. Moreover, the lowest potential energy was obtained when starting from a fcc type-structure and using Monte Carlo simulation giving rise to the formation of a bcc Fe-Mo-W phase and a Cu-Ni fcc type-structure. Dendritic and interdendritic phases were observed in the sample produced by arc furnace while the milled powder evidence an separation of two phases Cu-Fe-Ni phase and W-Mo type-structures. Samples produced by both methods show the formation of bcc and a fcc type-structures. Therefore, the Monte Carlo simulation seems to be closer with the experimental results, which points to a two-phase mixture formation for the Cu-Fe-Ni-Mo-W multicomponent system.info:eu-repo/semantics/publishedVersio

Structural and optical characterization of mechanochemically synthesized CuSbS2 compounds

ABSTRACT: One of the areas of research on materials for thin-film solar cells focuses on replacing In and Ga with more earth-abundant elements. In that respect, chalcostibite (CuSbS2) is being considered as a promising environmentally friendly and cost-effective photovoltaic absorber material. In the present work, single CuSbS2 phase was synthesized directly by a short-duration (2 h) mechanochemical-synthesis step starting from mixtures of elemental powders. X-ray diffraction analysis of the synthesized CuSbS2 powders revealed a good agreement with the orthorhombic chalcostibite phase, space group Pnma, and a crystallite size of 26 nm. Particle-size characterization revealed a multimodal distribution with a median diameter ranging from of 2.93 mu m to 3.10 mu m. The thermal stability of the synthesized CuSbS2 powders was evaluated by thermogravimetry and differential thermal analysis. No phase change was observed by heat-treating the mechanochemically synthesized powders at 350 degrees C for 24 h. By UV-VIS-NIR spectroscopy the optical band gap was determined to be 1.41 eV, suggesting that the mechanochemically synthesized CuSbS2 can be considered suitable to be used as absorber materials. Overall, the results show that the mechanochemical process is a viable route for the synthesis of materials for photovoltaic applications.info:eu-repo/semantics/publishedVersio

Irradiation damage on CrNbTaVWx high entropy alloys

ABSTRACT: CrNbTaVWx high-entropy alloys have been developed for plasma facing components to be applied in nuclear fusion reactors. The CrNbTaVWx (x = 1 and 1.7) compositions were prepared by ball milling and consolidated at 1600 degrees C under 90 MPa. To study the irradiation resistance of these materials, deuterium plasmas were used to irradiate the samples in the PF-1000U facility with 1 and 3 discharges. Structural changes before and after irradiation were analyzed by scanning electron microscopy coupled with energy dispersive X-ray spectroscopy. Nuclear reaction analysis was carried out with 1000 and 2300 keV 3He+ ion beams to evaluate the profile and amount of retained deuterium on the irradiated samples. After irradiation, the sample with higher W content revealed swelling and melting for all discharges, while in the case of CrNbTaVW only blisters were observed. The deuterium retention was higher for CrNbTaVW1.7 when compared with CrNbTaVW for 3 discharges applied.info:eu-repo/semantics/publishedVersio

Structural and Optical Characterization of Mechanochemically Synthesized CuSbS2† [Abstract]

ABSTRACT: The present work describes experimental studies related to the characterization of CuSbS2 directly synthesized after 2 h of mechanochemical synthesis (MCS) at 340 rpm, starting from mixtures of elemental powders. X-ray diffraction (XRD) and UV-VIS-NIR spectroscopy were carried out to analyze the crystal structure, degree of crystallinity, crystallite size and optical properties of the mechanochemically synthesized CuSbS2 powders. Rietveld refinement was carried out using Diffrac. TOPAS (Bruker AXS). Thermal stability of the synthesized materials was evaluated by the vacuum thermal heat treatment of the mechanochemically synthesized CuSbS2 powders at 350 °C for 24 h. Furthermore, the CuSbS2 powders were also analyzed by field-emission scanning electron microscopy (FE-SEM), laser diffraction, and differential thermal analysis.info:eu-repo/semantics/publishedVersio

Effects of NaBH4 additions on hydrogen absorption by nanostuctured FeTi powders

Hydrogen is nowadays considered as one of the most promising fuels for the future transportation market, since it is highly energetic and its combustion products are non-toxic. There are however some inherent problems related to its handling and storage that makes its implementation difficult in the energy market [1]. One way of storing hydrogen is in form of intermetallic hydrides. Some intermetallics can store large amounts of hydrogen in their interstitial sites and, in some cases, reversible equilibrium absorption/desorption cycles might be realized near ambient temperature and normal pressure. FeTi is an intermetallic compound that is being widely studied for hydrogen storage purposes. This system has one of the highest volumetric storage capacities and can be produced at low cost [2,3]. However, the FeTi alloy prepared through conventional metallurgical process requires activation treatments at elevated temperature. It has been shown previously that the nanostructured FeTi can be activated at room temperature with the mechanical alloying of pure metallic constituents, Fe and Ti, with NaBH4 [4]. In this work nanostructured FeTi based powders were produced by mechanical alloying, and the effects of adding different amounts of NaBH4 on the hydrogen absorption capacity and on the agglomeration of the powders were studied. The effect of handling powders in a glovebox with oxygen free atmosphere or in atmospheric ambient condition was also examined. Several parameters of the as-milled powders were controlled. Among the characterization performed are phase identification and crystallite size determinations by X-ray diffraction, micro hardness measurements, scanning electron microscopy and absorption isotherms determinations

On a class of 4D Kahler bases and AdS_5 supersymmetric Black Holes

We construct a class of toric Kahler manifolds, M_4, of real dimension four, a subset of which corresponds to the Kahler bases of all known 5D asymptotically AdS_5 supersymmetric black-holes. In a certain limit, these Kahler spaces take the form of cones over Sasaki spaces, which, in turn, are fibrations over toric manifolds of real dimension two. The metric on M_4 is completely determined by a single function H(x), which is the conformal factor of the two dimensional space. We study the solutions of minimal five dimensional gauged supergravity having this class of Kahler spaces as base and show that in order to generate a five dimensional solution H(x) must obey a simple sixth order differential equation. We discuss the solutions in detail, which include all known asymptotically AdS_5 black holes as well as other spacetimes with non-compact horizons. Moreover we find an infinite number of supersymmetric deformations of these spacetimes with less spatial isometries than the base space. These deformations vanish at the horizon, but become relevant asymptotically.Comment: 34 pages, 3 figures. v2: formula (8.35) and other minor typos corrected; references added; accepted for publication in JHE