Energetics and crystal chemistry of Ruddlesden-Popper type structures in high T(sub c) ceramic superconductors

The formation of Ruddlesden-Popper type layers (alternating slabs of rocksalt and perovskite structures) is seen in these oxides which is similar in many respects to what is seen in the system Sr-Ti-O. However, it was observed that there are some significant differences, for example the rocksalt and perovskite blocks in new superconducting compounds are not necessarily electrically, unlike in Sr-Ti-O systems. This will certainly render an additional coulombic bonding energy between two different types of blocks and may well lead to significant differences in their structural chemistry. In the higher order members of the various homologous series, additional Cu-O planes are inserted in the perovskite blocks. In order for the unit cell to electrically neutral the net positive charge on rocksalt block (which remains constant throughout the homologous series) should be balanced by an equal negative charge on perovskite block. It, thus becomes necessary to create oxygen vacancies in the basic perovskite structure, when width of the perovskite slab changes on addition of extra Cu-O planes. Results of atomistic simulations suggest that these missing oxygen ions allow the Cu-O planes to buckle in these compounds. This is also supported by the absence of buckling in the first member of Bi-containing compounds in which there are no missing oxygen ions and the Sr-Ti-O series of compounds. Additional results are presented on the phase stability of polytypoid structures in these crystal chemically complex systems. The studies will focus on the determination of the location of Cu(3+) in the structures of higher order members of the La-Cu-O system and whether Cu(3+) ions or oxygen vacancies are energetically more favorable charge compensating mechanism

David Sherrington commemorative issue

This themed issue of Polymer Chemistry was commissioned following the passing, in October 2014, of Professor David Colin Sherrington, FRS. It was commissioned as a dedication to the memory of a world-class polymer chemist of international renown, as well as a celebration of a subject area that was very close to Dave's heart and upon which he founded his career and made his name. It is entirely appropriate that this collection of papers is published in a leading international journal that bears the name of the subject field with which Dave's name is synonymous and to which he contributed so much – Polymer Chemistry – and that this collection be published in the UK by his own professional chemical society, the Royal Society of Chemistry

Integrated Power/Attitude Control System (IPACS) study. Volume 2: Conceptual designs

For abstract, see N74-22706

Natural History of the Peregrine Falcon in the Keewatin District of the Northwest Territories

A dense, productive population of peregrine falcons (Falco peregrinus) was studied for five years on a 450 sq km study area located along the northwest coast of Hudson Bay. The mean internest distance of 3.3 km represents the highest nesting density on record for the species in the Arctic. Morphometric and plumage characteristics of adults in the population suggest they are intermediate between F.p. tundrius from farther north and F.p. anatum from boreal regions to the south and west. The migratory pathway used by this population of birds is similar to that used by peregrines from Alaska, northern Canada, and Greenland. Both timing of arrival on the breeding grounds and clutch initiation are influenced strongly by spring weather patterns. Nineteen species of birds and three species of mammals were used as prey; however, in most years the bulk of the diet consisted of six species of birds and one mammal. A dramatic increase in the density of territorial peregrines in a year of high microtine rodent abundance, coupled with changes in various measures of reproductive performance, suggested that use of lemmings by falcons can be significant in some years. Suggestions that peregrines lay fewer eggs in the arctic part of their range were not supported. Broods hatched asynchronously, with the last-hatched young dying in about one-half of all broods of four. Surviving last-hatched young in broods of four grew at rates similar to older nest mates. Brood size was as high as that for any tundra nesting peregrine population on record.Key words: peregrine falcon, Falco peregrinus tundrius, morphology, migration, food, growth, productivityMots clés: faucon pèlerin, Falco peregrinus tundrius, morphologie, migration, alimentation, croissance, productivit&eacute

Continuous macroscopic limit of a discrete stochastic model for interaction of living cells

In the development of multiscale biological models it is crucial to establish a connection between discrete microscopic or mesoscopic stochastic models and macroscopic continuous descriptions based on cellular density. In this paper a continuous limit of a two-dimensional Cellular Potts Model (CPM) with excluded volume is derived, describing cells moving in a medium and reacting to each other through both direct contact and long range chemotaxis. The continuous macroscopic model is obtained as a Fokker-Planck equation describing evolution of the cell probability density function. All coefficients of the general macroscopic model are derived from parameters of the CPM and a very good agreement is demonstrated between CPM Monte Carlo simulations and numerical solution of the macroscopic model. It is also shown that in the absence of contact cell-cell interactions, the obtained model reduces to the classical macroscopic Keller-Segel model. General multiscale approach is demonstrated by simulating spongy bone formation from loosely packed mesenchyme via the intramembranous route suggesting that self-organizing physical mechanisms can account for this developmental process.Comment: 4 pages, 3 figure

Hypercrosslinked materials

This chapter describes the chemistry of hypercrosslinked materials, and presents a description of their synthesis, defining physico-chemical features and their most important applications. The synthesis section will examine the different monomers, precursor polymers, reagents and synthetic strategies used to prepare hypercrosslinked materials. Each synthesis section also details the chemical and morphological properties of the hypercrosslinked materials and the main field of application

Hypercrosslinked materials : preparation, characterisation and applications

This review article provides an overview of hypercrosslinking technology. In particular, it covers the preparation and characterisation of hypercrosslinked materials and their applications. The synthesis section examines the different monomers, precursor polymers and reagents used to prepare hypercrosslinked materials, but also the different synthetic approaches disclosed in the literature. The various chemical modification reactions relevant to this area are also reviewed. Several examples of applications for hypercrosslinked materials are described; these applications are grouped into thematic areas such as chromatography, gas storage and the trapping of organic contaminants