5,184 research outputs found
Hopping and clustering of oxygen vacancies in SrTiO3 by anelastic relaxation
The complex elastic compliance s11(w,T) of SrTiO3-d has been measured as a
function of the O deficiency d < 0.01. The two main relaxation peaks in the
absorption are identified with hopping of isolated O vacancies over a barrier
of 0.60 eV and reorientation of pairs of vacancies involving a barrier of 1 eV.
The pair binding energy is ~0.2 eV and indications for additional clustering,
possibly into chains, is found already at d ~0.004. The anistropic component of
the elastic dipole of an O vacancy is Deltalambda = 0.026.Comment: 4 pages, 4 figures, submitted to Phys. Rev. Let
Algebraic treatment of the confluent Natanzon potentials
Using the so(2,1) Lie algebra and the Baker, Campbell and Hausdorff formulas,
the Green's function for the class of the confluent Natanzon potentials is
constructed straightforwardly. The bound-state energy spectrum is then
determined. Eventually, the three-dimensional harmonic potential, the
three-dimensional Coulomb potential and the Morse potential may all be
considered as particular cases.Comment: 9 page
An Analytical Study of Ozone Feedbacks on Kelvin and Rossby–Gravity Waves: Effects on the QBO
An equatorial beta-plane model of the middle atmosphere is used to analytically examine the effects of radiative cooling and ozone heating on the spatial and temporal evolution of the quasi-biennial oscillation (QBO). Under the assumption that the diabatic heating is weak and the background fields of wind, temperature, and ozone are slowly varying, a perturbation analysis yields expressions describing the vertical spatial modulation of Kelvin and Rossby–gravity waves in the presence of ozone. These expressions show that wave-induced changes in the diabatic heating arising from the advection of basic-state ozone reduce the local radiative damping rate by up to 15% below 35 km. In a one-dimensional model of the QBO, eddy ozone heating increases the amplitude of the zonal wind QBO by 1–2 m s−1 and increases the oscillation period by about two months. The significance of these results to the observed QBO is discussed
Effect of doping and oxygen vacancies on the octahedral tilt transitions in the BaCeO3 perovskite
We present a systematic study of the effect of Y doping and hydration level
on the structural transformations of BaCeO3 based on anelastic spectroscopy
experiments. The temperature of the intermediate transformation between
rhombohedral and orthorhombic Imma phases rises with increasing the molar
fraction x of Y roughly as (500 K)x in the hydrated state, and is depressed of
more than twice that amount after complete dehydration. This is explained in
terms of the effect of doping on the average (Ce/Y)-O and Ba-O bond lengths,
and of lattice relaxation from O vacancies. The different behavior of the
transition to the lower temperature Pnma orthorhombic phase is tentatively
explained in terms of progressive flattening of the effective shape of the OH
ion and ordering of the O vacancies during cooling.Comment: 8 pages, 5 figure
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