Microwave synthesis, characterization and perspectives of wood pencil-derived carbon

More than 14 billion pencils are manufactured and used globally every year. On average, a pencil is discarded after 60% of its original length has been depleted. In the present work we propose a simple and affordable way of converting this non-neglectable amount of waste into added value carbon product. In particular, we demonstrate the microwave synthesis of carbon from the wood pencil with and without chemical activation. This could be a process stage before the final recycling of the expensive graphite core. In the latter case, irradiation of the wood pencil in a domestic microwave oven heats up the pencil's graphite core, thus inducing carbonization of its wood casing. The carbonized product consists of amorphous carbon nanosheets having relatively low surface area. However, if the wood pencil is soaked in 50% KOH aqueous solution prior to microwave irradiation, a significantly higher surface area of carbon is obtained, consisting of irregular-shaped porous particles. Consequently, the obtained carbon can easily decolorize a methylene blue aqueous solution, can be used to make pocket warmers or gunpowder, and lastly, serves as an excellent adsorbent towards Cr(VI) removal from water, showing a maximum adsorption capacity of 70-75 mg/g within 24 h at 23 degrees C, pH = 3.Web of Science121art. no. 41

Kiwi Fruits Preservation Using Novel Edible Active Coatings Based on Rich Thymol Halloysite Nanostructures and Chitosan/Polyvinyl Alcohol Gels

The concept of this study is the replacement of previous fossil-based techniques for food packaging and food shelf-life extension, with novel more green processes and materials following the spirit of circular economy and the global trend for environmentally positive fingerprints. A novel adsorption process to produce thymol-halloysite nanohybrids is presented in this work. The high dispersion of this thymol-halloysite nanostructure in chitosan biopolymer is one of the goals of this study. The incorporation of this biodegradable matrix with poly-vinyl-alcohol produced a very promising food-packaging film. Mechanical, water-oxygen barrier, antimicrobial, and antioxidant properties were measured. Transparency levels were also tested using a UV-vis instrument. Moreover, the developed films were tested in-vivo for the preservation and the extension of the shelf-life of kiwi fruits. In all cases, results indicated that the increased fraction of thymol from thyme oil significantly enhances the antimicrobial and antioxidant activity of the prepared chitosan-poly-vinyl- alcohol gel. The use of the halloysite increases the mechanical and water-oxygen barrier properties and leads to a control release process of thymol which extends the preservation and the shelf-life of kiwi fruits. Finally, the results indicated that the halloysite improves the properties of the chitosan/poly-vinyl-alcohol films, and the thymol makes them further advantageous

Development of Poly(L-Lactic Acid)/Chitosan/Basil Oil Active Packaging Films via a Melt-Extrusion Process Using Novel Chitosan/Basil Oil Blends

Following the global trend toward a cyclic economy, the development of a fully biodegradable active packaging film is the target of this work. An innovative process to improve the mechanical, antioxidant, and barrier properties of Poly(L-Lactic Acid)/Chitosan films is presented using essential basil oil extract. A Chitosan/Basil oil blend was prepared via a green evaporation/adsorption method as a precursor for the development of the Poly(L-Lactic Acid)/Chitosan/Basil Oil active packaging film. This Chitosan/Basil Oil blend was incorporated directly in the Poly(L-Lactic Acid) matrix with various concentrations. Modification of the chitosan with the Basil Oil improves the blending with the Poly(L-Lactic Acid) matrix via a melt-extrusion process. The obtained Poly(L-Lactic Acid)/Chitosan/Basil Oil composite films exhibited advanced food packaging properties compared to those of the Poly(L-Lactic Acid)/Chitosan films without Basil Oil addition. The films with 5%wt and 10%wt Chitosan/Basil Oil loadings exhibited better thermal, mechanical, and barrier behavior and significant antioxidant activity. Thus, PLLA/CS/BO5 and PLLA/CS/BO10 are the most promising films to potentially be used for active packaging applications

Geographical Origin Authentication of Agri-Food Products: A Review

This study is a systematic literature review of geographical origin authentication by elemental analytical techniques. Authentication and certification of geographic origin of agri-food products is a useful tool toward the protection of the quality for products. The aim of this work was to map the current state of research in the area of agricultural products and food, identifying emerging fields to the geographical origin of products. The article is divided in three parts. The first part of the article deals with the analytical techniques applied in the food authentication. Special mention is made to elemental analysis and multiple isotope ratio. The second section focuses on statistically published data concerning published research for geographical origin authentication for the period 2015–2019. Specific results are presented inter alia: number of articles according to the type of product, articles according to the type of the analytical techniques, and others. The third part contains characteristic results from articles that were published in the period 2015–2019, on certification of geographical origin on specific agricultural products

Effect of Copper and Titanium-Exchanged Montmorillonite Nanostructures on the Packaging Performance of Chitosan/Poly-Vinyl-Alcohol-Based Active Packaging Nanocomposite Films

In this study, CuMt and TiMt montmorillonites were produced via an ion-exchange process with Cu+ and Ti4+ ions. These nanostructured materials were characterized with X-ray diffraction (XRD) and fourier transform infrared spectroscopy (FTIR) measurements and added as nanoreinforcements and active agents in chitosan (CS)/poly-vinyl-alcohol (PVOH)-based packaging films. The developed films were characterized by XRD and FTIR measurements. The antimicrobial, tensile, and oxygen/water-barrier measurements for the evaluation of the packaging performance were carried out to the obtained CS/PVOH/CuMt and CS/PVOH/TiMt films. The results of this study indicated that CS/PVOH/CuMt film is a stronger intercalated nanocomposite structure compared to the CS/PVOH/TiMt film. This fact reflected higher tensile strength and water/oxygen-barrier properties. The antibacterial activity of these films was tested against four food pathogenic bacteria: Escherichia coli, Staphylococcus aureus, Salmonella enterica and Listeria monocytogenes. Results showed that in most cases, the antibacterial activity was generated by the CuMt and TiMt nanostructures. Thus, both CS/PVOH/CuMt and CS/PVOH/TiMt films are nanocomposite candidates with very good perspectives for future applications on food edible active packaging

Effect of Na- and Organo-Modified Montmorillonite/Essential Oil Nanohybrids on the Kinetics of the In Situ Radical Polymerization of Styrene

The great concern about the use of hazardous additives in food packaging materials has shown the way to new bio-based materials, such as nanoclays incorporating bioactive essential oils (EO). One of the still unresolved issues is the proper incorporation of these materials into a polymeric matrix. The in situ polymerization seems to be a promising technique, not requiring high temperatures or toxic solvents. Therefore, in this study, the bulk radical polymerization of styrene was investigated in the presence of sodium montmorillonite (NaMMT) and organo-modified montmorillonite (orgMMT) including thyme (TO), oregano (OO), and basil (BO) essential oil. It was found that the hydroxyl groups present in the main ingredients of TO and OO may participate in side retardation reactions leading to lower polymerization rates (measured gravimetrically by the variation of monomer conversion with time) accompanied by higher polymer average molecular weight (measured via GPC). The use of BO did not seem to affect significantly the polymerization kinetics and polymer MWD. These results were verified from independent experiments using model compounds, thymol, carvacrol and estragol instead of the clays. Partially intercalated structures were revealed from XRD scans. The glass transition temperature (from DSC) and the thermal stability (from TGA) of the nanocomposites formed were slightly increased from 95 to 98 °C and from 435 to 445 °C, respectively. Finally, better dispersion was observed when orgMMT was added instead of NaMMT

Synthesis of a Novel Chitosan/Basil Oil Blend and Development of Novel Low Density Poly Ethylene/Chitosan/Basil Oil Active Packaging Films Following a Melt-Extrusion Process for Enhancing Chicken Breast Fillets Shelf-Life

An innovative process for the adsorption of the hydrophobic Basil-Oil (BO) into the hydrophilic food byproduct chitosan (CS) and the development of an advanced low-density polyethylene/chitosan/basil-oil (LDPE/CS_BO) active packaging film was investigated in this work. The idea of this study was the use of the BO as both a bioactive agent and a compatibilizer. The CS was modified to a CS_BO hydrophobic blend via a green evaporation/adsorption process. This blend was incorporated directly in the LDPE to produce films with advanced properties. All the obtained composite films exhibited improved packaging properties. The film with 10% CS_BO content exhibited the best packaging properties, i.e., 33.0% higher tensile stress, 31.0% higher water barrier, 54.3% higher oxygen barrier, and 12.3% higher antioxidant activity values compared to the corresponding values of the LDPE films. The lipid oxidation values of chicken breast fillets which were packaged under vacuum using this film were measured after seven and after fourteen days of storage. These values were found to be lower by around 41% and 45%, respectively, compared with the corresponding lipid oxidation values of pure LDPE film

The use of activated bio-carbon derived from “Posidonia oceanica” sea-waste for Lithium-Sulfur batteries development

Lithium-Sulfur Batteries is promising energy storage systems due to their superior capacity and energy density. A promising solution for drawbacks such as low sulfur utilization and cycling stability is the use of porous carbon as sulfur carrier. On the other hand, cyclic economy and green ideas is of great importance nowadays. Carbon-sulfur cathodes from waste valorization, abundant, and low-cost precursors is an attractive approach. Herein, an activated carbon (AC-Poc) derived from "Posidonia oceanica" sea-waste, was studied as a matrix for the development of a novel carbon-sulfur composite cathode (AC-Poc/S) for the first time. AC-Poc can be used as an effective sulfur host, due to its high specific BET surface area (1264 m(2).g(-1)) hierarchical porous structure, and total pore volume 0.81 cm(3).g(-1). AC-Poc/S reveals an outstanding initial capacity of 1539 mAh.g(-1) as cathode material, combined with high reversible capacity at 0.2 C. Furthermore, the discharge capacity of 390 mAh/g at 2 C reveals good rate capability, even at increased C-rate. AC-Poc/S composite exhibits excellent sulfur utilization (92 %) alongside with sufficiently well electrochemical performance. These results combined with the easy synthesis method of the activated carbon from an abundant and low-cost precursor make AC-Poc/S a very promising material for LSBs applications.Web of Science53art. no. 10274