Constructing Heterostructure through Bidentate Coordination toward Operationally Stable Inverted Perovskite Solar Cells

It has been reported that one of the influencing factors leading to stability issues in iodine-containing perovskite solar cells is the iodine loss from the perovskite layer. Herein, bidentate coordination is used with undercoordinated I− of the perovskite surface to construct the stable perovskite-based heterostructure. This strong halogen bonding effectively inhibits interfacial migration of I− into functional layers such as C60 and Ag. Moreover, passivation of the undercoordinated I− suppresses the release of I2 and further delays the formation of voids at the perovskite surface. The resulting inverted perovskite solar cell exhibits a power conversion efficiency of 22.59% and the unencapsulated device maintains 96.15% of its initial value after continuous operation for 500 h under illumination.journal articl

Microcystic/reticular schwannoma of the adrenal gland: a case report and literature review

Microcystic/reticular schwannoma is a recently described, rare, distinctive histological variant of schwannoma with a predilection for the gastrointestinal tract [1]. Unlike classic Schwannoma, most microcystic/reticular Schwannoma had an incomplete fibrous capsule, two distinctly different areas - hypercellular areas and myxoid areas, Microcystic/reticular schwannoma occurs in the internal organs, especially in the digestive tract and a rare case occurs in the adrenal glands [1–3]. Herein, we report a case of microcystic/reticular schwannoma of the adrenal gland, in a 60-year-old male with 7.0 cm × 6.0 cm × 5 cm mass in the left adrenal gland. The tumor showed a vague multinodular appearance with a pushing border and arranged in a microcystic and reticular growth pattern with anastomosing and intersecting strands of spindle cells in a myxoid or collagenous/hyalinized stroma. Tumor cells showed diffuse nuclear and cytoplasmic positivity for S-100. Keywords: Microcystic/reticular schwannonma, Adrenal gland, Pathological features, Differential diagnosi

Rhenium-Catalyzed [4 + 1] Annulation of Azobenzenes and Aldehydes via Isolable Cyclic Rhenium(I) Complexes

The first Re-catalyzed [4 + 1] annulation of azobenzenes with aldehydes was developed to furnish 2<i>H</i>-indazoles via isolable and characterized cyclic Re^I-complexes. For the first time, the acetate-acceleration effect is showcased in Re-catalyzed C–H activation reactions. Remarkably, mechanistic studies revealed an irreversible aldehyde-insertion step, which is in sharp contrast to those of previous Rh- and Co-systems

Mechanical Properties and Thermal Conductivity of Thermal Insulation Board Containing Recycled Thermosetting Polyurethane and Thermoplastic

This study used a mechanochemical method to analyze the recycling mechanism of polyurethane foam and optimize the recycling process. The use of mechanochemical methods to regenerate the polyurethane foam powder breaks the C–O bond of the polyurethane foam and greatly enhances the activity of the powder. Based on orthogonal test design, the mesh, proportion, temperature, and time were selected to produce nine recycled boards by heat pressing. Then, the influence of four factors on the thermal conductivity and tensile strength of the recycled board was analyzed. The results show that 120 mesh polyurethane foam powder has strong activity, and the tensile strength can reach 9.913 Mpa when it is formed at 205 °C and 40 min with 50% PP powder. With the help of the low thermal conductivity of the polyurethane foam, the thermal conductivity of the recycled board can reach 0.037 W/m·K at the parameter of 40 mesh, 80%, 185 °C, 30 min. This research provides an effective method for the recycling of polyurethane foam

Study on Supermode Control of External Cavity VCSEL Array with Parallel-Coupled Model

A vertical-cavity surface-emitting laser (VCSEL) is easily made into a two-dimensional array to improve its output power. However, if the near-field complex amplitude output cannot be stabilized in the lowest supermode generated by the fundamental transverse mode, the spot cannot converge on the center normal of the far-field array geometry, and the energy will be diverged. The external cavity is prepared for the VCSEL array, and the output of the array can be stabilized in the lowest order supermode generated by the fundamental transverse mode by supermode control through diffraction coupling. In this study, the parallel-coupled model for the 2-dimensional VCSEL array based on Fresnel diffraction integration was established and used to numerically calculate and analyze the influence on the supermodes’ thresholds of different array distributions, array elements’ transverse modes and duty ratios versus the length of the external cavity. The simulation results show that the square array provides a wider range of external cavity control length (0.2d2/λ and approximately 0.9 to 1.0d2/λ). The lowest supermode of the fundamental transverse mode can be outputted. For the regular hexagonal array with the length of the external cavity of 0.15d2/λ and 0.6d2/λ. The results have important reference significance for the design of an external cavity VCSEL array, which can control the supermode and obtain VCSEL coherent array beams with high power and near diffraction limits

Mn-Catalyzed Aromatic C–H Alkenylation with Terminal Alkynes

The first <i>manganese-catalyzed</i> aromatic C–H alkenylation with terminal alkynes is described. The procedure features an operationally simple catalyst system containing commercially available MnBr­(CO)₅ and dicyclohexylamine (Cy₂NH). The reaction occurs readily in a highly chemo-, regio-, and stereoselective manner delivering <i>anti</i>-Markovnikov <i>E</i>-configured olefins in high yields. Experimental study and DFT calculations reveal that (1) the reaction is initiated by a C–H activation step via the cooperation of manganese and base; (2) manganacycle and alkynylmanganese species are the key reaction intermediates; and (3) the ligand-to-ligand H-transfer and alkynyl-assisted C–H activation are the key steps rendering the reaction catalytic in manganese

Multi-Omics Profiling Identifies Candidate Genes Controlling Seed Size in Peanut

Seed size is the major yield component and a key target trait that is selected during peanut breeding. However, the mechanisms that regulate peanut seed size are unknown. Two peanut mutants with bigger seed size were isolated in this study by 60Co treatment of a common peanut landrace, Huayu 22, and were designated as the “big seed” mutant lines (hybs). The length and weight of the seed in hybs were about 118% and 170% of those in wild-type (WT), respectively. We adopted a multi-omics approach to identify the genomic locus underlying the hybs mutants. We performed whole genome sequencing (WGS) of WT and hybs mutants and identified thousands of large-effect variants (SNPs and indels) that occurred in about four hundred genes in hybs mutants. Seeds from both WT and hybs lines were sampled 20 days after flowering (DAF) and were used for RNA-Seq analysis; the results revealed about one thousand highly differentially expressed genes (DEGs) in hybs compared to WT. Using a method that combined large-effect variants with DEGs, we identified 45 potential candidate genes that shared gene product mutations and expression level changes in hybs compared to WT. Among the genes, two candidate genes encoding cytochrome P450 superfamily protein and NAC transcription factors may be associated with the increased seed size in hybs. The present findings provide new information on the identification and functional research into candidate genes responsible for the seed size phenotype in peanut