2,292 research outputs found
Quantitative localized proton-promoted dissolution kinetics of calcite using scanning electrochemical microscopy (SECM)
Scanning electrochemical microscopy (SECM) has been used to determine quantitatively the kinetics of proton-promoted dissolution of the calcite (101Ì
4) cleavage surface (from natural âIceland Sparâ) at the microscopic scale. By working under conditions where the probe size is much less than the characteristic dislocation spacing (as revealed from etching), it has been possible to measure kinetics mainly in regions of the surface which are free from dislocations, for the first time. To clearly reveal the locations of measurements, studies focused on cleaved âmirrorâ surfaces, where one of the two faces produced by cleavage was etched freely to reveal defects intersecting the surface, while the other (mirror) face was etched locally (and quantitatively) using SECM to generate high proton fluxes with a 25 ÎŒm diameter Pt disk ultramicroelectrode (UME) positioned at a defined (known) distance from a crystal surface. The etch pits formed at various etch times were measured using white light interferometry to ascertain pit dimensions. To determine quantitative dissolution kinetics, a moving boundary finite element model was formulated in which experimental time-dependent pit expansion data formed the input for simulations, from which solution and interfacial concentrations of key chemical species, and interfacial fluxes, could then be determined and visualized. This novel analysis allowed the rate constant for proton attack on calcite, and the order of the reaction with respect to the interfacial proton concentration, to be determined unambiguously. The process was found to be first order in terms of interfacial proton concentration with a rate constant k = 6.3 (± 1.3) Ă 10â4 m sâ1. Significantly, this value is similar to previous macroscopic rate measurements of calcite dissolution which averaged over large areas and many dislocation sites, and where such sites provided a continuous source of steps for dissolution. Since the local measurements reported herein are mainly made in regions without dislocations, this study demonstrates that dislocations and steps that arise from such sites are not needed for fast proton-promoted calcite dissolution. Other sites, such as point defects, which are naturally abundant in calcite, are likely to be key reaction sites
Literacy practices of primary education children in Andalusia (Spain): a family-based perspective
Primary school children develop literacy practices in various domains and situations in everyday life.
This study focused on the analysis of literacy practices of children aged 8â12 years from the perspec-
tive of their families. 1,843 families participated in the non-experimental explanatory study. The
children in these families speak Spanish as a first language and are schooled in this language. The
instrument used was a self-report questionnaire about childrenâs home-literacy practices. The data
obtained were analysed using categorical principal components analysis (CATPCA) and analysis of
variance (ANOVA). The results show the complex relationship between literacy practices developed
by children in the domains of home and school and the limited development of a literacy-promoting
âthird spaceâ. In conclusion, the families in our study had limited awareness of their role as literacy-
promoting agents and thought of literacy learning as restricted to formal or academic spaces
Group cognitive analytic music therapy: a quasi-experimental feasibility study conducted in a high secure hospital
This study conducted a feasibility patient preference quasi-experimental study of group cognitive analytic music therapy (G-CAMT) for mentally disordered offenders. Participants either chose or were randomised to 16 sessions of manualised G-CAMT (N = 10) plus treatment as usual (TAU) or TAU alone (N = 10). Self-rated and staff-rated outcomes were assessed at baseline, post-intervention and 8-weeks post-intervention. Residency was assessed at 2-year follow-up. Results indicate that G-CAMT was easily implemented; 9/10 participants completed G-CAMT and attendees had high satisfaction with the approach. Session attendance was high; 4/10 participants attended all sessions. At the 8-week follow-up, 3/9 G-CAMT participants had reliable reductions (i.e. statistically reliable pre to 8-week follow-up change results) in intrusive/possessive behaviours and fear of separation/abandonment. On the staff-rated outcome measure G-CAMT participants as a group were statistically significantly friendlier compared to TAU at 8-week follow-up (U = 0.50, p = 0.009, d = 1.92, CI 0.44 to 3.11). There were no differences between the arms in terms of residency outcomes at 2-year follow-up. The study is discussed in terms of G-CAMTâs theoretical grounding and high acceptability. The study is limited by its small sample size, but indicates the possibility of progressing onto a full trial
Deeply Virtual Compton Scattering
We study in QCD the physics of deeply-virtual Compton scattering (DVCS)---the
virtual Compton process in the large s and small t kinematic region. We show
that DVCS can probe a new type of off-forward parton distributions. We derive
an Altarelli-Parisi type of evolution equations for these distributions. We
also derive their sum rules in terms of nucleon form-factors of the twist-two
quark and gluon operators. In particular, we find that the second sum rule is
related to fractions of the nucleon spin carried separately by quarks and
gluons. We estimate the cross section for DVCS and compare it with the
accompanying Bethe-Heitler process at CEBAF and HERMES kinematics.Comment: 20 pages, 2 figures, replaced with the version to appear in Phys.
Rev.
The Implications of the Microwave Background Anisotropies for Laser-Interferometer-Tested Gravitational Waves
The observed microwave background anisotropies in combination with the theory
of quantum mechanically generated cosmological perturbations predict a well
measurable amount of relic gravitational waves in the frequency intervals
tested by LISA and ground-based laser interferometers.Comment: revised, corrected, and slightly expanded version to be published in
Classical and Quantum Gravity; 22 pages, 1 Postscript figure, Latex; Based on
a talk presented at the First Internationsl LISA Symposium, 9 - 12 July 1996,
RAL, U
Versatile transporter apparatus for experiments with optically trapped Bose-Einstein condensates
We describe a versatile and simple scheme for producing magnetically and
optically-trapped Rb-87 Bose-Einstein condensates, based on a moving-coil
transporter apparatus. The apparatus features a TOP trap that incorporates the
movable quadrupole coils used for magneto-optical trapping and long-distance
magnetic transport of atomic clouds. As a stand-alone device, this trap allows
for the stable production of condensates containing up to one million atoms. In
combination with an optical dipole trap, the TOP trap acts as a funnel for
efficient loading, after which the quadrupole coils can be retracted, thereby
maximizing optical access. The robustness of this scheme is illustrated by
realizing the superfluid-to-Mott insulator transition in a three-dimensional
optical lattice
Magnetic vortex oscillator driven by dc spin-polarized current
Transfer of angular momentum from a spin-polarized current to a ferromagnet
provides an efficient means to control the dynamics of nanomagnets. A peculiar
consequence of this spin-torque, the ability to induce persistent oscillations
of a nanomagnet by applying a dc current, has previously been reported only for
spatially uniform nanomagnets. Here we demonstrate that a quintessentially
nonuniform magnetic structure, a magnetic vortex, isolated within a nanoscale
spin valve structure, can be excited into persistent microwave-frequency
oscillations by a spin-polarized dc current. Comparison to micromagnetic
simulations leads to identification of the oscillations with a precession of
the vortex core. The oscillations, which can be obtained in essentially zero
magnetic field, exhibit linewidths that can be narrower than 300 kHz, making
these highly compact spin-torque vortex oscillator devices potential candidates
for microwave signal-processing applications, and a powerful new tool for
fundamental studies of vortex dynamics in magnetic nanostructures.Comment: 14 pages, 4 figure
Photodetachment study of the 1s3s4s ^4S resonance in He^-
A Feshbach resonance associated with the 1s3s4s ^{4}S state of He^{-} has
been observed in the He(1s2s ^{3}S) + e^- (\epsilon s) partial photodetachment
cross section. The residual He(1s2s ^{3}S) atoms were resonantly ionized and
the resulting He^+ ions were detected in the presence of a small background. A
collinear laser-ion beam apparatus was used to attain both high resolution and
sensitivity. We measured a resonance energy E_r = 2.959 255(7) eV and a width
\Gamma = 0.19(3) meV, in agreement with a recent calculation.Comment: LaTeX article, 4 pages, 3 figures, 21 reference
Quantitative plane-resolved crystal growth and dissolution kinetics by coupling in situ optical microscopy and diffusion models : the case of salicylic acid in aqueous solution
The growth and dissolution kinetics of salicylic acid crystals are investigated in situ by focusing on individual microscale crystals. From a combination of optical microscopy and finite element method (FEM) modeling, it was possible to obtain a detailed quantitative picture of dissolution and growth dynamics for individual crystal faces. The approach uses real-time in situ growth and dissolution data (crystal size and shape as a function of time) to parametrize a FEM model incorporating surface kinetics and bulk to surface diffusion, from which concentration distributions and fluxes are obtained directly. It was found that the (001) face showed strong mass transport (diffusion) controlled behavior with an average surface concentration close to the solubility value during growth and dissolution over a wide range of bulk saturation levels. The (1Ì
10) and (110) faces exhibited mixed mass transport/surface controlled behavior, but with a strong diffusive component. As crystals became relatively large, they tended to exhibit peculiar hollow structures in the end (001) face, observed by interferometry and optical microscopy. Such features have been reported in a number of crystals, but there has not been a satisfactory explanation for their origin. The mass transport simulations indicate that there is a large difference in flux across the crystal surface, with high values at the edge of the (001) face compared to the center, and this flux has to be redistributed across the (001) surface. As the crystal grows, the redistribution process evidently can not be maintained so that the edges grow at the expense of the center, ultimately creating high index internal structures. At later times, we postulate that these high energy faces, starved of material from solution, dissolve and the extra flux of salicylic acid causes the voids to close
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