1,293 research outputs found

    Ultracold homonuclear and heteronuclear collisions in metastable helium

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    Scattering and ionizing cross sections and rates are calculated for ultracold collisions between metastable helium atoms using a fully quantum-mechanical close-coupled formalism. Homonuclear collisions of the bosonic 4{}^{4}He∗+4^{*} +{}^{4}He∗^{*} and fermionic 3{}^{3}He∗+3^{*} + {}^{3}He∗^{*} systems, and heteronuclear collisions of the mixed 3{}^{3}He∗+4^{*} +{}^{4}He∗^{*} system, are investigated over a temperature range 1 μ\muK to 1 K. Carefully constructed Born-Oppenheimer molecular potentials are used to describe the electrostatic interaction between the colliding atoms, and complex optical potentials used to represent loss through ionization from the 1,3Σ{}^{1,3}\Sigma states. Magnetic spin-dipole mediated transitions from the 5Σ{}^{5}\Sigma state are included and results reported for spin-polarized and unpolarized systems. Comparisons are made with experimental results, previous semi-classical models, and a perturbed single channel model.Comment: 14 pages, 9 figure

    Electron scattering and transport in liquid argon

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    The transport of excess electrons in liquid argon driven out of equilibrium by an applied electric field is revisited using a multi-term solution of Boltzmann's equation together with ab initio liquid phase cross-sections calculated using the Dirac-Fock scattering equations. The calculation of liquid phase cross-sections extends previous treatments to consider multipole polarisabilities and a non-local treatment of exchange while the accuracy of the electron-argon potential is validated through comparison of the calculated gas phase cross-section with experiment. The results presented highlight the inadequacy of local treatments of exchange that are commonly used in liquid and cluster phase cross-section calculations. The multi-term Boltzmann equation framework accounting for coherent scattering enables the inclusion of the full anisotropy in the differential cross-section arising from the interaction and the structure factor, without an a priori assumption of quasi-isotropy in the velocity distribution function. The model, which contains no free parameters and accounts for both coherent scattering and liquid phase screening effects, was found to reproduce well the experimental drift velocities and characteristic energies.Comment: 32 pages, 16 figures; minor corrections, added 1 figur

    Photoassociation spectra and the validity of the dipole approximation for weakly bound dimers

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    Photoassociation (PA) of ultracold metastable helium to the 2s2p manifold is theoretically investigated using a non-perturbative close-coupled treatment in which the laser coupling is evaluated without assuming the dipole approximation. The results are compared with our previous study [Cocks and Whittingham, Phys. Rev. A 80, 023417 (2009)] that makes use of the dipole approximation. The approximation is found to strongly affect the PA spectra because the photoassociated levels are weakly bound, and a similar impact is predicted to occur in other systems of a weakly bound nature. The inclusion or not of the approximation does not affect the resonance positions or widths, however significant differences are observed in the background of the spectra and the maximum laser intensity at which resonances are discernable. Couplings not satisfying the dipole selection rule |J-1| <= J' <= |J+1| do not lead to observable resonances.Comment: 5 pages, 2 figures; Minor textual revision
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