1 research outputs found
Effects of Anodic Potential and Chloride Ion on Overall Reactivity in Electrochemical Reactors Designed for Solar-Powered Wastewater Treatment
We
have investigated electrochemical treatment of real domestic
wastewater coupled with simultaneous production of molecular H<sub>2</sub> as useful byproduct. The electrolysis cells employ multilayer
semiconductor anodes with electroactive bismuth-doped TiO<sub>2</sub> functionalities and stainless steel cathodes. DC-powered laboratory-scale
electrolysis experiments were performed under static anodic potentials
(+2.2 or +3.0 V NHE) using domestic wastewater samples, with added
chloride ion in variable concentrations. Greater than 95% reductions
in chemical oxygen demand (COD) and ammonium ion were achieved within
6 h. In addition, we experimentally determined a decreasing overall
reactivity of reactive chlorine species toward COD with an increasing
chloride ion concentration under chlorine radicals (ClĀ·, Cl<sub>2</sub><sup>ā</sup>Ā·) generation at +3.0 V NHE. The current
efficiency for COD removal was 12% with the lowest specific energy
consumption of 96 kWh kgCOD<sup>ā1</sup> at the cell voltage
of near 4 V in 50 mM chloride. The current efficiency and energy efficiency
for H<sub>2</sub> generation were calculated to range from 34 to 84%
and 14 to 26%, respectively. The hydrogen comprised 35 to 60% by volume
of evolved gases. The efficacy of our electrolysis cell was further
demonstrated by a 20 L prototype reactor totally powered by a photovoltaic
(PV) panel, which was shown to eliminate COD and total coliform bacteria
in less than 4 h of treatment