94 research outputs found
\u3ci\u3eIn-Situ\u3c/i\u3e Raman Scattering Studies of Alkali-Doped Single Wall Carbon Nanotubes
Electrochemical doping and in-situ Raman scattering were used to study charge transfer in K- and Li-doped single wall carbon nanotubes (SWNT) as a function of alkali concentration. An 8 cm-1 downshift was observed for the tangential phonon mode of SWNT doped to stoichiometries of KC24 and Li1.25C6. The shift in both systems is reversible upon de-doping despite an irreversible loss of crystallinity. These results indicate that the tangential mode shifts result from electron transfer from alkali dopants to the SWNT, and that these modes are only weakly affected by long-range order within the ropes
Oscillator Strength of Metallic Carbon Nanotubes
Based on the tight binding method with hopping integral between the
nearest-neighbor atoms, an oscillator strength \int_0^{\infty} \d \omega {\rm
Re} \sigma (\omega) is discussed for armchair and metallic zigzag carbon
nanotubes. The formulae of the oscillator strength are derived for both types
of nanotubes and are compared with the result obtained by a linear chain model.
In addition, the doping dependence is investigated in the absence of Coulomb
interaction. It is shown that the oscillator strength of each carbon nanotube
shows qualitatively the same doping dependence, but the fine structure is
different due to it's own peculiar band structure. Some relations independent
of the radius of the tube are derived, and a useful formula for determining the
amount of doping is proposed.Comment: 4 pages, 4 figures, submitted to J. Phys. Soc. Jpn. at June 30, 200
Enhancement of the Electron Spin Resonance of Single-Walled Carbon Nanotubes by Oxygen Removal
We have observed a nearly fourfold increase in the electron spin resonance
(ESR) signal from an ensemble of single-walled carbon nanotubes (SWCNTs) due to
oxygen desorption. By performing temperature-dependent ESR spectroscopy both
before and after thermal annealing, we found that the ESR in SWCNTs can be
reversibly altered via the molecular oxygen content in the samples. Independent
of the presence of adsorbed oxygen, a Curie-law (spin susceptibility ) is seen from 4 K to 300 K, indicating that the probed spins are
finite-level species. For both the pre-annealed and post-annealed sample
conditions, the ESR linewidth decreased as the temperature was increased, a
phenomenon we identify as motional narrowing. From the temperature dependence
of the linewidth, we extracted an estimate of the intertube hopping frequency;
for both sample conditions, we found this hopping frequency to be 100
GHz. Since the spin hopping frequency changes only slightly when oxygen is
desorbed, we conclude that only the spin susceptibility, not spin transport, is
affected by the presence of physisorbed molecular oxygen in SWCNT ensembles.
Surprisingly, no linewidth change is observed when the amount of oxygen in the
SWCNT sample is altered, contrary to other carbonaceous systems and certain 1D
conducting polymers. We hypothesize that physisorbed molecular oxygen acts as
an acceptor (-type), compensating the donor-like (-type) defects that are
responsible for the ESR signal in bulk SWCNTs.Comment: 14 pages, 7 figure
Recommended from our members
Non-structural carbohydrates in woody plants compared among laboratories
Non-structural carbohydrates (NSC) in plant tissue are frequently quantified to make inferences about plant responses to environmental conditions. Laboratories publishing estimates of NSC of woody plants use many different methods to evaluate NSC. We asked whether NSC estimates in the recent literature could be quantitatively compared among studies. We also asked whether any differences among laboratories were related to the extraction and quantification methods used to determine starch and sugar concentrations. These questions were addressed by sending sub-samples collected from five woody plant tissues, which varied in NSC content and chemical composition, to 29 laboratories. Each laboratory analyzed the samples with their laboratory-specific protocols, based on recent publications, to determine concentrations of soluble sugars, starch and their sum, total NSC. Laboratory estimates differed substantially for all samples. For example, estimates for Eucalyptus globulus leaves (EGL) varied from 23 to 116 (mean = 56) mg g⁻¹ for soluble sugars, 6–533 (mean = 94) mg g⁻¹ for starch and 53–649 (mean = 153) mg g⁻¹ for total NSC. Mixed model analysis of variance showed that much of the variability among laboratories was unrelated to the categories we used for extraction and quantification methods (method category R² = 0.05–0.12 for soluble sugars, 0.10–0.33 for starch and 0.01–0.09 for total NSC). For EGL, the difference between the highest and lowest least squares means for categories in the mixed model analysis was 33 mg g⁻¹ for total NSC, compared with the range of laboratory estimates of 596 mg g⁻¹. Laboratories were reasonably consistent in their ranks of estimates among tissues for starch (r = 0.41–0.91), but less so for total NSC (r = 0.45–0.84) and soluble sugars (r = 0.11–0.83). Our results show that NSC estimates for woody plant tissues cannot be compared among laboratories. The relative changes in NSC between treatments measured within a laboratory may be comparable within and between laboratories, especially for starch. To obtain comparable NSC estimates, we suggest that users can either adopt the reference method given in this publication, or report estimates for a portion of samples using the reference method, and report estimates for a standard reference material. Researchers interested in NSC estimates should work to identify and adopt standard methods.This is the publisher’s final pdf. The published article is copyrighted by the author(s) and published by Oxford University Press. The published article can be found at: http://treephys.oxfordjournals.org/Keywords: soluble sugars, starch, particle size, reference method, standardization, non-structural carbohydrate chemical analysis, extraction and quantification consistenc
Thermal Imagery to Count Cattle with UAV Technology in an Industrialized Beef Operation
In the beef cattle industry, managers track daily inventory of animals by enumerating cattle in individual paddocks within an expansive feedlot, which is a very time and labor intensive task. Today’s agriculture routinely uses sophisticated technologies such as robots, temperature and moisture sensors, aerial images, and unmanned aerial vehicles (UAVs). More specifically, the use of UAVs in agriculture is a new and expanding technology that has the potential to be a key part of the cattle enumeration system. Having the ability to take a picture of a pen at a fixed height with thermal imagery while using UAV technology, would cut down on the time it takes to perform this task. It would also potentially increase enumeration accuracy and ultimately improve the management of the cattle in an intensive setting. In this study, I investigated the potential of UAVs for use in agriculture. Specifically, I sought to develop an automated cattle enumeration system and looked to find a response to how we can decrease the time it takes to count cattle in an industrialized beef operation. In doing so, I investigated the ability to count cattle in an individual paddock using thermal imagery, using image processing software and a UAV. We developed a method in which we could fly the UAV on an automated path to take a picture at a fixed height using an infrared camera. In addition to taking the thermal pictures, we used image counting software to automatically enumerate individual cattle within a given area
- …