Characterization and assessment of potential environmental risk of tailings stored in seven impoundments in the Aries river basin, Western Romania

BACKGROUND: The objective of this study was to examine the potential environmental risk of tailings resulted after precious and base metal ores processing, stored in seven impoundments located in the Aries river basin, Romania. The tailings were characterized by mineralogical and elemental composition, contamination indices, acid rock drainage generation potential and water leachability of hazardous/priority hazardous metals and ions. Multivariate statistical methods were used for data interpretation. RESULTS: Tailings were found to be highly contaminated with several hazardous/priority hazardous metals (As, Cu, Cd, Pb), and pose potential contamination risk for soil, sediments, surface and groundwater. Two out of the seven studied impoundments does not satisfy the criteria required for inert wastes, shows acid rock drainage potential and thus can contaminate the surface and groundwater. Three impoundments were found to be highly contaminated with As, Pb and Cd, two with As and other two with Cu. The tailings impoundments were grouped based on the enrichment factor, geoaccumulation index, contamination factor and contamination degree of 7 hazardous/priority hazardous metals (As, Cd, Cr, Cu, Ni, Pb, Zn) considered typical for the studied tailings. Principal component analysis showed that 47% of the elemental variability was attributable to alkaline silicate rocks, 31% to acidic S-containing minerals, 12% to carbonate minerals and 5% to biogenic elements. Leachability of metals and ions was ascribed in proportion of 61% to silicates, 11% to acidic minerals and 6% to the organic matter. A variability of 18% was attributed to leachability of biogenic elements (Na, K, Cl(-), NO(3)(-)) with no potential environmental risk. Pattern recognition by agglomerative hierarchical clustering emphasized the grouping of impoundments in agreement with their contamination degree and acid rock drainage generation potential. CONCLUSIONS: Tailings stored in the studied impoundments were found to be contaminated with some hazardous/ priority hazardous metals, fluoride and sulphate and thus presents different contamination risk for the environment. A long term monitoring program of these tailings impoundments and the expansion of the ecologization measures in the area is required

Determination of Quality Indicators of Prut River Water

This study presents an assessment of water quality of Prut River using the Water Quality Index (WQI), calculated according to the weighted arithmetic water quality index method. The obtained results show that the water of Prut River may be classified according to WQI as good water quality of grade B for sampling points Sculeni and Cislita-Prut villages, and very poor water quality of grade D collected in the sampling point Criva village

Determination of Major-to-Trace Minerals and Polyphenols in Different Apple Cultivars

The aim of this study was to investigate the concentration level of some major-to-trace elements and toxic minerals and polyphenols (catechin, epicatechin and quercetin) in fruits belonging to different apple cultivars (‘Auriu de Cluj’, ‘Florina’, ‘Generos’, ‘Golden Delicious’, ‘Prima’, ‘Productiv de Cluj’ and ‘Starkrimson’), under specific climate conditions to northwestern Romania. The apple minerals were determined by the inductively coupled plasma mass spectrometry (ICP-MS) and inductively coupled plasma optical emission spectrometry (ICP-OES) after a preliminary, microwave-assisted, acid digestion. The polyphenols were determined by high performance liquid chromatography (HPLC) with MS/MS detection. According to the obtained results, the edible part of the apple contains many minerals with high relative nutritional value (RNV). The major minerals (Na, K, Ca, Mg and P), minor elements (Cu, Fe, Mn, Sr and Zn) and toxic trace elements (Cd, Cr and Pb) were comparatively identified and quantified. It was found that K (31976 mg/kg) was predominant among the major elements, while Fe (3.68 mg/kg) and Cu (3.57 mg/kg) were comparable. The toxic trace metals (Cd, Cr and Pb) were below the limits of detection (0.01, 0.10 and 0.01 mg/kg, respectively) and did not determine any health risk to consumers. The main polyphenols composition (catechin, epicathechin, quercetin) differs slightly among different cultivars. In ‘Idared’ and ‘Jonathan’ cultivars, the investigated polyphenols are in higher quantities comparing to the others. In all investigated apple cultivars, quercetin was proved to be the major polyphenol, followed by epicathechin and catechin. These results suggest that, regarding only the investigated polyphenols, ‘Idared’ and ‘Jonathan’ cultivars have the highest antioxidant character in all investigated genotypes

Vassalak leletek a római limes erdélyi, Maros megyei szakaszáról (Marosvécs, Mikháza, Felsőrépa). FTIR és XRF spektroszkópiai jellemzés

Marosvécsen (Brâncoveneşti), Mikházán (Călugăreni) és Felsőrépán (Vătava) feltárt vassalak leleteket vizsgáltunk spektroszkópiai módszerekkel (FTIR, XRF). Az FTIR spektrumok 2000–400 cm-1 hullámszám tartományában jellemző módon jelentkező nagy intenzitású, viszonylag széles absorpciós sávok alapján a minták kisebb mennyiségű aluminát és karbonát mellett alapvetően szilikátokból állnak. Mint a röntgen-fluoreszcens analízis adatai mutatják, a fő ásványfázis minden esetben nagy valószínűséggel a fayalit (Fe2SiO4). Az egyes minták elemi összetételére vonatkozó, kézi XRF spektrométerrel több felületi ponton nyert adatok ugyanakkor arra utalnak, hogy mind a kémiai, mind az ásványtani következtetések levonásánál tekintettel kell lenni a salakok erősen heterogén jellegére

Characterization and assessment of potential environmental risk of tailings stored in seven impoundments in the Aries river basin, Western Romania

Abstract Background The objective of this study was to examine the potential environmental risk of tailings resulted after precious and base metal ores processing, stored in seven impoundments located in the Aries river basin, Romania. The tailings were characterized by mineralogical and elemental composition, contamination indices, acid rock drainage generation potential and water leachability of hazardous/priority hazardous metals and ions. Multivariate statistical methods were used for data interpretation. Results Tailings were found to be highly contaminated with several hazardous/priority hazardous metals (As, Cu, Cd, Pb), and pose potential contamination risk for soil, sediments, surface and groundwater. Two out of the seven studied impoundments does not satisfy the criteria required for inert wastes, shows acid rock drainage potential and thus can contaminate the surface and groundwater. Three impoundments were found to be highly contaminated with As, Pb and Cd, two with As and other two with Cu. The tailings impoundments were grouped based on the enrichment factor, geoaccumulation index, contamination factor and contamination degree of 7 hazardous/priority hazardous metals (As, Cd, Cr, Cu, Ni, Pb, Zn) considered typical for the studied tailings. Principal component analysis showed that 47% of the elemental variability was attributable to alkaline silicate rocks, 31% to acidic S-containing minerals, 12% to carbonate minerals and 5% to biogenic elements. Leachability of metals and ions was ascribed in proportion of 61% to silicates, 11% to acidic minerals and 6% to the organic matter. A variability of 18% was attributed to leachability of biogenic elements (Na, K, Cl-, NO3-) with no potential environmental risk. Pattern recognition by agglomerative hierarchical clustering emphasized the grouping of impoundments in agreement with their contamination degree and acid rock drainage generation potential. Conclusions Tailings stored in the studied impoundments were found to be contaminated with some hazardous/ priority hazardous metals, fluoride and sulphate and thus presents different contamination risk for the environment. A long term monitoring program of these tailings impoundments and the expansion of the ecologization measures in the area is required.</p

ASSESSING OF WATER QUALITY POLLUTION INDICES FOR HEAVY METAL CONTAMINATION. A STUDY CASE FROM MEDIAS CITY GROUNDWATERS

Three documented methods: Contamination index (Cd), the Heavy metal potential index (HPI) and the Heavy metal evaluation index (HEI) were evaluated for their suitability for contamination monitoring of underground water (water wells) from Medias. In addition, ions and physico-chemical analysis were elaborated. Results show that the concentrations of heavy metals found in the wells from Medias are below the permissible levels of drinking water quality standards. The data have been used for the calculation of Cd, HPI and HEI. All seven samples were classified as low using the Cd, HPI and HEI, whereas nitrogen compounds (nitrate, nitrite and ammonia) exceed the maximum admissible concentration, salinity as well (0.7‰ for F2, F3, F4, F5 and F7, while the MAC is established at 0.1‰, EPA). As a short conclusion, water samples do not present heavy metal pollution, furthermore there is an organic pollution, regarding nitrogen compounds and salinity

Determination of Major-to-Trace Minerals and Polyphenols in Different Apple Cultivars

The aim of this study was to investigate the concentration level of some major-to-trace elements and toxic minerals and polyphenols (catechin, epicatechin and quercetin) in fruits belonging to different apple cultivars (‘Auriu de Cluj’, ‘Florina’, ‘Generos’, ‘Golden Delicious’, ‘Prima’, ‘Productiv de Cluj’ and ‘Starkrimson’), under specific climate conditions to northwestern Romania. The apple minerals were determined by the inductively coupled plasma mass spectrometry (ICP-MS) and inductively coupled plasma optical emission spectrometry (ICP-OES) after a preliminary, microwave-assisted, acid digestion. The polyphenols were determined by high performance liquid chromatography (HPLC) with MS/MS detection. According to the obtained results, the edible part of the apple contains many minerals with high relative nutritional value (RNV). The major minerals (Na, K, Ca, Mg and P), minor elements (Cu, Fe, Mn, Sr and Zn) and toxic trace elements (Cd, Cr and Pb) were comparatively identified and quantified. It was found that K (31976 mg/kg) was predominant among the major elements, while Fe (3.68 mg/kg) and Cu (3.57 mg/kg) were comparable. The toxic trace metals (Cd, Cr and Pb) were below the limits of detection (0.01, 0.10 and 0.01 mg/kg, respectively) and did not determine any health risk to consumers. The main polyphenols composition (catechin, epicathechin, quercetin) differs slightly among different cultivars. In ‘Idared’ and ‘Jonathan’ cultivars, the investigated polyphenols are in higher quantities comparing to the others. In all investigated apple cultivars, quercetin was proved to be the major polyphenol, followed by epicathechin and catechin. These results suggest that, regarding only the investigated polyphenols, ‘Idared’ and ‘Jonathan’ cultivars have the highest antioxidant character in all investigated genotypes.</p

Application of Inductively Coupled Plasma Spectrometric Techniques and Multivariate Statistical Analysis in the Hydrogeochemical Profiling of Caves—Case Study Cloșani, Romania

The aim of the study was to develop the hydrogeochemical profiling of caves based on the elemental composition of water and silty soil samples and a multivariate statistical analysis. Major and trace elements, including rare earths, were determined in the water and soil samples. The general characteristics of water, anions content, inorganic and organic carbon fractions and nitrogen species (NO3− and NH4+) were also considered. The ANOVA—principal component analysis (PCA) and two-way joining analysis were applied on samples collected from Cloșani Cave, Romania. The ANOVA-PCA revealed that the hydrogeochemical characteristics of Ca2+-HCO3− water facies were described by five factors, the strongest being associated with water-carbonate rock interactions and the occurrence of Ca, Mg and HCO3− (43.4%). Although organic carbon fractions have a lower influence (20.1%) than inorganic ones on water characteristics, they are involved in the chemical processes of nitrogen and of the elements involved in redox processes (Fe, Mn, Cr and Sn). The seasonal variability of water characteristics, especially during the spring, was observed. The variability of silty soil samples was described by four principal components, the strongest influence being attributed to rare earth elements (52.2%). The ANOVA-PCA provided deeper information compared to Gibbs and Piper diagrams and the correlation analysis