Enhancing Multiphoton Upconversion from NaYF₄:Yb/Tm@NaYF₄ Core–Shell Nanoparticles <i>via</i> the Use of Laser Cavity

We discover that emission efficiency of Tm³⁺-doped upconversion nanoparticles can be enhanced through the use of a laser cavity. With suitable control of the lasing conditions, the population of the intermediate excited states of the Tm³⁺ can be clamped at a required value above the excitation threshold. As a result, upconversion efficiency for the 300–620 nm emission band of the Tm³⁺-doped nanoparticles under 976 nm excitation can be enhanced by an order of magnitude over the case without a laser cavity. This is because the intrinsic recombination process of the intermediate excited states is suppressed and the surplus of excitation power directly contributes to the enhancement of multiphoton upconversion. Furthermore, our theoretical investigation has shown that the improvement of upconversion emission efficiency is mainly dependent on the cavity loss, so that this strategy can also be extended to other lanthanide-doped systems

White-Light Whispering-Gallery-Mode Lasing from Lanthanide-Doped Upconversion NaYF₄ Hexagonal Microrods

We demonstrate simultaneous red, green, and blue emission from a Yb³⁺–Er³⁺–Tm³⁺ tridoped hexagonal β-NaYF₄ microrod, which supports whispering-gallery-mode (WGM) resonance, to realize white-light lasing under near-infrared excitation at room temperature. This can be done by optimizing the upconversion efficiency and emission intensity balance of the blue, green, and red peaks through the proper tuning of sensitizer (Yb³⁺) and activator (Er³⁺, Tm³⁺) concentration in the host matrix. In addition, we minimize the difference of lasing threshold and maintain stable single-mode operation to achieve simultaneous red, green, and blue lasing by optimizing the radius of the hexagonal microrods