Self-Powered, High-Speed and Visible–Near Infrared Response of MoO_3–<i>x</i>/n-Si Heterojunction Photodetector with Enhanced Performance by Interfacial Engineering

Photodetectors with a wide spectrum response are important components for sensing, imaging, and other optoelectronic applications. A molybdenum oxide (MoO_3–<i>x</i>)/Si heterojunction has been applied as solar cells with great success, but its potential in photodetectors has not been explored yet. Herein, a self-powered, high-speed heterojunction photodetector fabricated by coating an n-type Si hierarchical structure with an ultrathin hole-selective layer of molybdenum oxide (MoO_3–<i>x</i>) is first investigated. Excellent and stable photoresponse performance is obtained by using a methyl group passivated interface. The heterojunction photodetector demonstrated high sensitivity to a wide spectrum from 300 to 1100 nm. The self-powered photodetector shows a high detectivity of (∼6.29 × 10¹² cmHz^1/2 W^–1) and fast response time (1.0 μs). The excellent photodetecting performance is attributed to the enhanced interfacial barrier height and three-dimensional geometry of Si nanostructures, which is beneficial for efficient photocarrier collection and transportation. Finally, our devices show excellent long-term stability in air for 6 months with negligible performance degradation. The thermal evaporation method for large-scale fabrication of MoO_3–<i>x</i>/n-Si photodetectors makes it suitable for self-powered, multispectral, and high-speed response photodetecting applications

Interface Engineering To Boost Photoresponse Performance of Self-Powered, Broad-Bandwidth PEDOT:PSS/Si Heterojunction Photodetector

Organic–inorganic hybrid heterojunctions are poised to push toward novel optoelectronics applications, such as photodetectors, but significant challenges complicating practical use remain. Although all organic based photodetectors have been reported with great success, their potential in high-speed, broadband, self-powered photodetectors have not been fully explored. Herein, a self-powered, broad bandwidth of photodetector based on PEDOT:PSS/Si heterojunction is built by a facial low temperature spin-coating method. By interface engineering of heterojunction with optimal band alignment and heteromicrostructures, enhanced photoresponse performances are obtained. The bandwidth of the hybrid photodetector could be broadened by 10 kHz after interfacial passivation by a methyl group. Further manipulating the geometrical structure of the hybrid heterojunction with silicon nanowire, a broad spectrum response from 300 to 1100 nm, with bandwidth as high as 40.6 kHz, fast response speed of 2.03 μs and high detection of 4.1 × 10¹¹ Jones under zero bias was achieved. Meanwhile, the close dependence between the photoresponse performance of heterojunctions and Si nanowire length is observed in the top-coverage configuration. Finally, a coverage effects model is proposed based on the competition of Si bulk and surface recombination, which is also confirmed by the designed bottom-coverage experiment. The mechanisms behind the enhanced photoresponse of the hybrid photodetector is attributed to the optimum band alignment, as well as the optimum balance of carrier dissociation and recombination of heterojunction. The scalable and low temperature method would be of great convenience for large-scale fabrication of the PEDOT:PSS/Si hybrid photodetector

Electrochromic Asymmetric Supercapacitor Windows Enable Direct Determination of Energy Status by the Naked Eye

Because of the popularity of smart electronics, multifunctional energy storage devices, especially electrochromic supercapacitors (SCs), have attracted tremendous research interest. Herein, a solid-state electrochromic asymmetric SC (ASC) window is designed and fabricated by introducing WO₃ and polyaniline as the negative and positive electrodes, respectively. The two complementary materials contribute to the outstanding electrochemical and electrochromic performances of the fabricated device. With an operating voltage window of 1.4 V and an areal capacitance of 28.3 mF cm^–2, the electrochromic devices show a high energy density of 7.7 × 10^–3 mW h cm^–2. Meanwhile, they exhibit an obvious and reversible color transition between light green (uncharged state) and dark blue (charged state), with an optical transmittance change between 55 and 12% at a wavelength of 633 nm. Hence, the energy storage level of the ASC is directly related to its color and can be determined by the naked eye, which means it can be incorporated with other energy cells to visual display their energy status. Particularly, a self-powered and color-indicated system is achieved by combining the smart windows with commercial solar cell panels. We believe that the novel electrochromic ASC windows will have great potential application for both smart electronics and smart buildings

Tailorable and Wearable Textile Devices for Solar Energy Harvesting and Simultaneous Storage

The pursuit of harmonic combination of technology and fashion intrinsically points to the development of smart garments. Herein, we present an all-solid tailorable energy textile possessing integrated function of simultaneous solar energy harvesting and storage, and we call it tailorable textile device. Our technique makes it possible to tailor the multifunctional textile into any designed shape without impairing its performance and produce stylish smart energy garments for wearable self-powering system with enhanced user experience and more room for fashion design. The “threads” (fiber electrodes) featuring tailorability and knittability can be large-scale fabricated and then woven into energy textiles. The fiber supercapacitor with merits of tailorability, ultrafast charging capability, and ultrahigh bending-resistance is used as the energy storage module, while an all-solid dye-sensitized solar cell textile is used as the solar energy harvesting module. Our textile sample can be fully charged to 1.2 V in 17 s by self-harvesting solar energy and fully discharged in 78 s at a discharge current density of 0.1 mA

DataSheet1_Asymmetries and relationships between muscle strength, proprioception, biomechanics, and postural stability in patients with unilateral knee osteoarthritis.docx

Background: The pathological mechanism of knee osteoarthritis (KOA) is unknown. KOA degeneration may be associated with changes in muscle strength, proprioception, biomechanics, and postural stability.Objective: This study aimed to assess asymmetries in muscle strength, proprioception, biomechanics, and postural stability of bilateral lower limbs in patients with unilateral KOA and healthy controls and analyze correlations between KOA and these parameters.Methods: A total of 50 patients with unilateral KOA (age range: 50-70) and 50 healthy subjects were recruited as study participants (age range: 50-70). Muscle strength, proprioception, femorotibial angle (FTA), femoral condylar–tibial plateau angle (FCTP), average trajectory error (ATE), and center of pressure (COP) sways areas were accessed in study participants, and the correlation between these variables was investigated.Results: In patients with unilateral KOA, lower limb muscle strength was significantly lower on the symptomatic side than on the asymptomatic side (p 0.05). Patients with unilateral KOA had lower muscle strength than healthy controls (p 0.05).Conclusion: In patients with unilateral KOA, muscle strength, proprioception, biomechanics, and postural stability of bilateral limbs are asymmetrical in unilateral KOA patients. Muscle strength, proprioception, and postural stability are significantly associated variables, and changes in these variables should be considered in KOA prevention and rehabilitation.</p