CFD analysis of the complex japanese pufferfish nest

Existing research on the pufferfish species (Torquigener Albomaculosus) has shown that its nest structure has a certain impact on flow velocity. This study aims to investigate the nest-building behavior by using different materials. A 3D model will be created based on nest geometry, and 2D simulations will be conducted by using computational fluid dynamics (CFD). Furthermore, the study examines the nest’s fluid dynamics characteristics in its original state, with varied materials and heights. Results demonstrate that the nest reduces flow velocity, adapts to external flow conditions, and enhances shear strength with rough materials. Additionally, nest height affects internal circulation area and pressure. This unique structure protects the spawning area, improves oxygen transport, and strengthens the nest. The study further expands biomimetic engineering applications and suggests future interdisciplinary research directions

Synthesis and characterization of thiourea

Herein, a simple and effective method for the preparation of thiourea using a nucleophilic substitution reaction is reported. Urea and Lawesson’s reagent were used as the raw materials to prepare thiourea via a one-step method involving the sulfuration reaction, and the reaction mechanism was analyzed. The effect of the reaction time, reaction temperature, and mass ratio of the raw materials on the yield of thiourea were investigated.The most beneficial conditions used for the reaction were determined to be: Reaction time = 3.5 h, reaction temperature = 75°C, and mass ratio of urea to Lawesson’s reagent = 2:1. Under these optimal conditions, the average yield of thiourea over five replicate experiments was 62.37%. Characterization using Fourier transform infrared (FTIR) spectroscopy, X-ray diffraction (XRD) and thermogravimetric analysis (TGA) showed that the as-synthesized substance was thiourea. Our synthetic method has the advantages of high yield, mild reaction conditions and simplicity

Calculation of Nonlinear Stiffness of Rubber Pad under Different Temperatures and Prepressures

The static stiffness of rubber springs is affected by temperature and prepressure. In this thesis, the relationship between Young’s modulus and temperature of rubber was studied, and the quantitative relationship between them was determined. The approximate formula for calculating the static stiffness of rubber pads was further modified, and the ellipse approximation method and convexity coefficient correction method were proposed. In addition, the influence of temperature on geometric nonlinearity was considered. The formula for calculating nonlinear stiffness includes two variables: temperature and prepressure. The results of tests and theoretical calculations demonstrate that the nonlinear formula can be a good approximation and that it can meet the requirements of engineering applications

Synthesis and characterization of thiourea

Herein, a simple and effective method for the preparation of thiourea using a nucleophilic substitution reaction is reported. Urea and Lawesson’s reagent were used as the raw materials to prepare thiourea via a one-step method involving the sulfuration reaction, and the reaction mechanism was analyzed. The effect of the reaction time, reaction temperature, and mass ratio of the raw materials on the yield of thiourea were investigated.The most beneficial conditions used for the reaction were determined to be: Reaction time = 3.5 h, reaction temperature = 75°C, and mass ratio of urea to Lawesson’s reagent = 2:1. Under these optimal conditions, the average yield of thiourea over five replicate experiments was 62.37%. Characterization using Fourier transform infrared (FTIR) spectroscopy, X-ray diffraction (XRD) and thermogravimetric analysis (TGA) showed that the as-synthesized substance was thiourea. Our synthetic method has the advantages of high yield, mild reaction conditions and simplicity

Synthesis and Characterization of 1-(1-chlorocyclopropyl)-2-(1,2,4-triazol-1-yl)ethan-1-one

A simple and efficient method to prepare 1-(1-chlorocyclopropyl)-2-(1,2,4-triazol-1-yl)ethan-1-one via nucleophilic substitution of 2-chloro-1-(1-chlorocyclopropyl)ethanone and 1,2,4-triazole is described. The title compound is the key intermediate required for the synthesis of prothioconazole, a promising agricultural fungicide. By exploring changes in the reaction time, temperature, ratio of starting reagents, acid binding agent, and the nature of phase transfer catalyst, the reaction conditions could be optimized to afford the desired N-alkylated material in near-quantitative yield. The ultimate yield of the product after recrystallization was 93%, with a purity of 99% based on its characterization by Gas Chromatography-Mass Spectrometer (GC-MS), Fourier Transform infrared spectroscopy (IR), Proton Magnetic Resonance (1H NMR), and Carbon-13 Nuclear Magnetic Resonance (13C NMR). The synthetic process is suitable for industrial application, with the advantages of high yield and facile preparation under mild operating conditions

Study of Vertical Characteristics with Changes in Prepressure of Rubber Pad Used by High-Speed EMU

Rubber spring plays an important role in improving train performance, so the study of rubber spring is one of the focuses of train dynamics. The vertical characteristic parameters of rubber spring are affected by prepressure significantly, as a result of varying parameters of static stiffness, dynamic stiffness, periodic energy consumption, damping coefficient, and so on. In order to use the theoretical method to calculate the precise static stiffness and predict the dynamic characteristics and to reduce the workload of the rubber spring performance test, this paper takes the annular rubber pad as an example to study with different prepressures. In this paper, the convexity coefficient correction formula (simply called the CCCF) for static stiffness calculation and the dynamic fiducial conversion coefficient (simply called the DFCC) method based on different prepressures are proposed. Through further analysis, the accuracy of CCCF and DFCC is proved both theoretically and experimentally. The results have shown precise prediction of the variation of prepressure on rubber spring parameters by using CCCF and DFCC and can be used as the reference of accurate vertical dynamic-static characteristics of the rubber spring