26,694 research outputs found
Pressure-Temperature Phase Diagram of Multiferroic
The pressure-temperature phase diagram of multiferroic is
investigated for hydrostatic pressures up to 2 GPa. The stability range of the
ferroelectric phase associated with the incommensurate helical spin order is
reduced by pressure and ferroelectricity is completely suppressed at the
critical pressure of 1.64 GPa at 6.2 K. Thermal expansion measurements at
ambient pressure show strong step-like anomalies of the lattice parameters
associated with the lock-in transition into the commensurate paraelectric
phase. The expansion anomalies are highly anisotropic, the related volume
change is consistent with the high-pressure phase diagram
The Suppression and Recovery of the Ferroelectric Phase in Multiferroic
We report the discovery of a complete suppression of ferroelectricity in
by 10 % iron substitution and its restoration in external magnetic
fields. The spontaneous polarization in arises below 12
K in external fields above 4 T. The magnetic/ferroelectric phase diagram is
constructed from the anomalies of the dielectric constant, polarization,
magnetization, and heat capacity. The observations are qualitatively described
by a mean field model with competing interactions and strong anisotropy. We
propose that the magnetic field induces a non-collinear inversion symmetry
breaking magnetic structure in
A sputtering derived atomic oxygen source for studying fast atom reactions
A technique for the generation of fast atomic oxygen was developed. These atoms are created by ion beam sputtering from metal oxide surfaces. Mass resolved ion beams at energies up to 60 KeV are produced for this purpose using a 150 cm isotope separator. Studies have shown that particles sputtered with 40 KeV Ar(+) on Ta2O5 were dominantly neutral and exclusively atomic. The atomic oxygen also resided exclusively in its 3P ground state. The translational energy distribution for these atoms peaked at ca 7 eV (the metal-oxygen bond energy). Additional measurements on V2O5 yielded a bimodal distribution with the lower energy peak at ca 5 eV coinciding reasonably well with the metal-oxygen bond energy. The 7 eV source was used to investigate fast oxygen atom reactions with the 2-butene stereoisomers. Relative excitation functions for H-abstraction and pi-bond reaction were measured with trans-2-butene. The abstraction channel, although of minor relative importance at thermal energy, becomes comparable to the addition channel at 0.9 eV and dominates the high-energy regime. Structural effects on the specific channels were also found to be important at high energy
Magnetoelectricity and Magnetostriction due to the Rare Earth Moment in TmAl(BO)
The magnetic properties, the magnetostriction, and the magnetoelectric effect
in the d-electron free rare-earth aluminum borate TmAl(BO) are
investigated between room temperature and 2 K. The magnetic susceptibility
reveals a strong anisotropy with the hexagonal c-axis as the hard magnetic
axis. Magnetostriction measurements show a large effect of an in-plane field
reducing both, the a- and c-axis lattice parameters. The magnetoelectric
polarization change in a- and c-directions reaches up to 300 C/m at 70
kOe with the field applied along the a-axis. The magnetoelectric polarization
is proportional to the lattice contraction in magnetic field. The results of
this investigation prove the existence of a significant coupling between the
rare earth magnetic moment and the lattice in Al(BO) compounds
( = rare earth). They further show that the rare earth moment itself will
generate a large magnetoelectric effect which makes it easier to study and to
understand the origin of the magnetoelectric interaction in this class of
materials.Comment: 4 pages, 5 figure
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