Models for designing pipe-grade polyethylenes to resist rapid crack propagation

Plastic pipeline systems have now become dominant for fuel-gas and water distribution networks. Although they have an impressive service record failures do occur, with Rapid Crack Propagation being characterised as the least probable but most potentially catastrophic one. This study investigates the effect of structural morphology and bulk residual strains on the RCP performance of polyethylene pipes, and proposes a new methodology for predicting a safe service envelope. During crack propagation in PE pipes, the fracture surface has two distinct regions; plane strain and plane stress. In addition to the Instrumented Charpy, Reversed Charpy, High Speed Double Torsion, Dynamic Mechanical Analysis and uniaxial tensile testing, S4 tests of extruded pipe specimens were employed in order to evaluate the structural and fracture parameters of pipe grade resins in these two fracture modes on pipe. A new experimental technique, which modified the pipe bore crystallinity without altering the residual strain field (as evaluated from slit ring tests) showed that the bore surface layer properties had much less influence on RCP than previously thought. Parallel with the experimental work, modeling of the fracture mechanisms was also undertaken. Using previous models in the field, such as the adiabatic decohesion model, the plane strain fracture toughness was evaluated while the plane stress fracture toughness was evaluated either from the Reversed Charpy or from the stability of adiabatic drawing in a tensile test. A mixed mode, temperature sensitive toughness was finally evaluated, leading to an overall fracture properties assessment for polyethylene pipes which could be compared directly to the crack driving force during RCP in pipe. By employing a new mathematical approach, which incorporated both the effects of residual strains and pipe stiffness behind the pressure decay length, a previous basic analytical RCP model was further developed and compared to more elaborate finite element and finite volume solutions. The new results were also compared to S4 experiments using high-speed photography and showed that the new methodology could be employed by the end user even when testing facilities are not directly availabl

On the Effect of Nb on the Microstructure and Properties of Next Generation Polycrystalline Powder Metallurgy Ni-Based Superalloys

Abstract The effect of Nb on the properties and microstructure of two novel powder metallurgy (P/M) Ni-based superalloys was evaluated, and the results critically compared with the Rolls-Royce alloy RR1000. The Nb-containing alloy was found to exhibit improved tensile and creep properties as well as superior oxidation resistance compared with both RR1000 and the Nb-free variant tested. The beneficial effect of Nb on the tensile and creep properties was due to the microstructures obtained following the post-solution heat treatments, which led to a higher γ′ volume fraction and a finer tertiary γ′ distribution. In addition, an increase in the anti-phase-boundary energy of the γ′ phase is also expected with the addition of Nb, further contributing to the strength of the material. However, these modifications in the γ′ distribution detrimentally affect the dwell fatigue crack-growth behavior of the material, although this behavior can be improved through modified heat treatments. The oxidation resistance of the Nb-containing alloy was also enhanced as Nb is believed to accelerate the formation of a defect-free Cr2O3 scale. Overall, both developmental alloys, with and without the addition of Nb, were found to exhibit superior properties than RR1000.This work was supported by the Rolls-Royce/EPSRC Strategic Partnership under EP/H022309/1, EP/H500375/1 and EP/ M005607/1

Models for designing pipe-grade polyethylenes to resist rapid crack propagation

Plastic pipeline systems have now become dominant for fuel-gas and water distribution networks. Although they have an impressive service record failures do occur, with Rapid Crack Propagation being characterised as the least probable but most potentially catastrophic one. This study investigates the effect of structural morphology and bulk residual strains on the RCP performance of polyethylene pipes, and proposes a new methodology for predicting a safe service envelope. During crack propagation in PE pipes, the fracture surface has two distinct regions; plane strain and plane stress. In addition to the Instrumented Charpy, Reversed Charpy, High Speed Double Torsion, Dynamic Mechanical Analysis and uniaxial tensile testing, S4 tests of extruded pipe specimens were employed in order to evaluate the structural and fracture parameters of pipe grade resins in these two fracture modes on pipe. A new experimental technique, which modified the pipe bore crystallinity without altering the residual strain field (as evaluated from slit ring tests) showed that the bore surface layer properties had much less influence on RCP than previously thought. Parallel with the experimental work, modeling of the fracture mechanisms was also undertaken. Using previous models in the field, such as the adiabatic decohesion model, the plane strain fracture toughness was evaluated while the plane stress fracture toughness was evaluated either from the Reversed Charpy or from the stability of adiabatic drawing in a tensile test. A mixed mode, temperature sensitive toughness was finally evaluated, leading to an overall fracture properties assessment for polyethylene pipes which could be compared directly to the crack driving force during RCP in pipe. By employing a new mathematical approach, which incorporated both the effects of residual strains and pipe stiffness behind the pressure decay length, a previous basic analytical RCP model was further developed and compared to more elaborate finite element and finite volume solutions. The new results were also compared to S4 experiments using high-speed photography and showed that the new methodology could be employed by the end user even when testing facilities are not directly availableEThOS - Electronic Theses Online ServiceRepsol YPFGBUnited Kingdo

Accompanying data for "On the effect of Nb on the microstructure and properties of next generation polycrystalline powder metallurgy Ni-based superalloys"

The data has been labelled with the same designations as used in the corresponding paper. Raw data is provided from differential scanning calorimetry and scanning electron microscopy following the various heat treatments and oxidation analyses. In addition, data is provided from the tensile, creep and dwell tests performed and the outcomes of the mechanical property modelling are also given.This work was supported by the Rolls-Royce/EPSRC Strategic Partnership under EP/H022309/1, EP/H500375/1 and EP/ M005607/1